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个人简介

1999.09-2003.06 浙江大学,制药工程,本科 2003.09-2008.12 浙江大学,化学工程,硕博连读 2009.01-2009.10 浙江大学,环境科学与工程学科流动站,学科博士后 2009.11-2010.10 美国New Mexico State University,博士后 2015.03-2016.03 美国The University of Texas at San Antonio,访问学者 2011.03-2011.12 浙江大学化工学院,讲师 2011.12-2018.12 浙江大学化工学院,副教授 2018.05至今 浙江大学制药工程研究所,副所长 2018.12至今 浙江大学化工学院,教授 2020.10至今 浙江大学生物质化工教育部重点实验室副主任

研究领域

金属有机框架材料、多孔炭材料设计制备与应用 吸附分离工程(变压吸附、模拟移动床色谱等) 天然产物、低碳烃、电子特气、湿电子化学品的分离纯化 超临界流体、离子液体等绿色分离技术

近期论文

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Li, L.; Guo, L.; Olson, D. H.; Xian, S.; Zhang, Z.; Yang, Q.; Wu, K.; Yang, Y.; Bao, Z.; Ren, Q.; Li, J. Discrimination of Xylene Isomers in a Stacked Coordination Polymer. Science 2022, 377 (6603), 335–339. https://doi.org/10.1126/science.abj7659. Zheng, F.; Guo, L.; Chen, R.; Chen, L.; Zhang, Z.; Yang, Q.; Yang, Y.; Su, B.; Ren, Q.; Bao, Z. Shell‐like Xenon Nano‐Traps within Angular Anion‐Pillared Layered Porous Materials for Boosting Xe/Kr Separation. Angewandte Chemie 2022. https://doi.org/10.1002/ange.202116686. Liu, Y.; Wu, H.; Guo, L.; Zhou, W.; Zhang, Z.; Yang, Q.; Yang, Y.; Ren, Q.; Bao, Z. Cover Picture: Hydrogen‐Bonded Metal–Nucleobase Frameworks for Efficient Separation of Xenon and Krypton (Angew. Chem. Int. Ed. 11/2022). Angew Chem Int Ed 2022, 61 (11). https://doi.org/10.1002/anie.202202166. Liu, Y.; Dai, J.; Guo, L.; Zhang, Z.; Yang, Y.; Yang, Q.; Ren, Q.; Bao, Z. Porous Hydrogen-Bonded Frameworks Assembled from Metal-Nucleobase Entities for Xe/Kr Separation. CCS Chem 2022, 4 (1), 381–388. https://doi.org/10.31635/ccschem.021.202100824. Liu, C.; Li, W.; Liu, Y.; Wang, H.; Yu, B.; Bao, Z.; Jiang, J. Porous Organic Cages for Efficient Gas Selective Separation and Iodine Capture. Chemical Engineering Journal 2022, 428, 131129. https://doi.org/10.1016/j.cej.2021.131129. Zheng, F.; Chen, L.; Chen, R.; Zhang, Z.; Yang, Q.; Yang, Y.; Su, B.; Ren, Q.; Bao, Z. A Robust Two–Dimensional Layered Metal–Organic Framework for Efficient Separation of Methane from Nitrogen. Separation and Purification Technology 2022, 281, 119911. https://doi.org/10.1016/j.seppur.2021.119911. Jiang, S.; Guo, L.; Chen, L.; Song, C.; Liu, B.; Yang, Q.; Zhang, Z.; Yang, Y.; Ren, Q.; Bao, Z. A Strongly Hydrophobic Ethane-Selective Metal-Organic Framework for Efficient Ethane/Ethylene Separation. Chemical Engineering Journal 2022, 136152. https://doi.org/10.1016/j.cej.2022.136152. Yu, Q.; Guo, L.; Lai, D.; Zhang, Z.; Yang, Q.; Yang, Y.; Ren, Q.; Bao, Z. A Pore-Engineered Metal-Organic Framework with Mixed Ligands Enabling Highly Efficient Separation of Hexane Isomers for Gasoline Upgrading. Separation and Purification Technology 2021, 268, 118646. https://doi.org/10.1016/j.seppur.2021.118646. Wu, K.; Guo, L.; Zhang, Z.; Yang, Q.; Yang, Y.; Ren, Q.; Bao, Z. Shaping of Gallate-Based Metal-Organic Frameworks for Adsorption Separation of Ethylene from Acetylene and Ethane. Journal of Colloid and Interface Science 2021, 581, 177–184. https://doi.org/10.1016/j.jcis.2020.07.111. Liu, Y.; Dai, J.; Zhang, Z.; Yang, Y.; Yang, Q.; Ren, Q.; Bao, Z. Crystal Structure Transformation in Hydrogen‐bonded Organic Frameworks via Ion Exchange. Chem. Asian J. 2021, 16 (23), 3978–3984. https://doi.org/10.1002/asia.202101151. Jiang, S.; Li, L.; Guo, L.; Song, C.; Yang, Q.; Zhang, Z.; Yang, Y.; Ren, Q.; Bao, Z. A Robust Ethane-Trapping Metal-Organic Framework for Efficient Purification of Ethylene. Sci. China Chem. 2021, 64 (4), 666–672. https://doi.org/10.1007/s11426-020-9929-8. Chen, F.; Lai, D.; Guo, L.; Wang, J.; Zhang, P.; Wu, K.; Zhang, Z.; Yang, Q.; Yang, Y.; Chen, B.; Ren, Q.; Bao, Z. Deep Desulfurization with Record SO2 Adsorption on the Metal–Organic Frameworks. J. Am. Chem. Soc. 2021, 143 (24), 9040–9047. https://doi.org/10.1021/jacs.1c02176. Chen, F.; Ding, J.; Guo, K.; Yang, L.; Zhang, Z.; Yang, Q.; Yang, Y.; Bao, Z.; He, Y.; Ren, Q. CoNi Alloy Nanoparticles Embedded in Metal–Organic Framework‐Derived Carbon for the Highly Efficient Separation of Xenon and Krypton via a Charge‐Transfer Effect. Angew. Chem. Int. Ed. 2021, 60 (5), 2431–2438. https://doi.org/10.1002/anie.202011778. Yu, X.; Wang, Y.; Yang, Q.; Zhang, Z.; Ren, Q.; Bao, Z.; Yang, Y. De Novo Synthesis of Microspheical Cellulose 3,5-Dichlorophenylcarbamates: An Organic-Inorganic Hybrid Chiral Stationary Phase for Enantiospearation. Separation and Purification Technology 2020, 238, 116480. https://doi.org/10.1016/j.seppur.2019.116480. Wang, Q.; Ke, T.; Yang, L.; Zhang, Z.; Cui, X.; Bao, Z.; Ren, Q.; Yang, Q.; Xing, H. Titelbild: Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving (Angew. Chem. 9/2020). Angew. Chem. 2020, 132 (9), 3365–3365. https://doi.org/10.1002/ange.202000349. Shen, J.; He, X.; Ke, T.; Krishna, R.; van Baten, J. M.; Chen, R.; Bao, Z.; Xing, H.; Dincǎ, M.; Zhang, Z.; Yang, Q.; Ren, Q. Simultaneous Interlayer and Intralayer Space Control in Two-Dimensional Metal−organic Frameworks for Acetylene/Ethylene Separation. Nat Commun 2020, 11 (1), 6259. https://doi.org/10.1038/s41467-020-20101-7. Qi, L.; Chen, J.; Zhang, B.; Nie, R.; Qi, Z.; Kobayashi, T.; Bao, Z.; Yang, Q.; Ren, Q.; Sun, Q.; Zhang, Z.; Huang, W. Deciphering a Reaction Network for the Switchable Production of Tetrahydroquinoline or Quinoline with MOF-Supported Pd Tandem Catalysts. ACS Catal. 2020, 10 (10), 5707–5714. https://doi.org/10.1021/acscatal.0c00899. Li, Z.; Li, L.; Guo, L.; Wang, J.; Yang, Q.; Zhang, Z.; Yang, Y.; Bao, Z.; Ren, Q. Gallate-Based Metal–Organic Frameworks for Highly Efficient Removal of Trace Propyne from Propylene. Ind. Eng. Chem. Res. 2020, 59 (30), 13716–13723. https://doi.org/10.1021/acs.iecr.0c01726. Li, L.; Guo, L.; Zheng, F.; Zhang, Z.; Yang, Q.; Yang, Y.; Ren, Q.; Bao, Z. Calcium-Based Metal–Organic Framework for Simultaneous Capture of Trace Propyne and Propadiene from Propylene. ACS Appl. Mater. Interfaces 2020, 12 (14), 17147–17154. https://doi.org/10.1021/acsami.0c03139. Ke, T.; Wang, Q.; Shen, J.; Zhou, J.; Bao, Z.; Yang, Q.; Ren, Q. Molecular Sieving of C 2 ‐C 3 Alkene from Alkyne with Tuned Threshold Pressure in Robust Layered Metal–Organic Frameworks. Angew. Chem. 2020, 132 (31), 12825–12830. https://doi.org/10.1002/ange.202003421. Dai, J.; Xie, D.; Liu, Y.; Zhang, Z.; Yang, Y.; Yang, Q.; Ren, Q.; Bao, Z. Supramolecular Metal–Organic Framework for CO 2 /CH 4 and CO 2 /N 2 Separation. Ind. Eng. Chem. Res. 2020, 59 (16), 7866–7874. https://doi.org/10.1021/acs.iecr.0c00447. Chen, J.; Wang, J.; Guo, L.; Li, L.; Yang, Q.; Zhang, Z.; Yang, Y.; Bao, Z.; Ren, Q. Adsorptive Separation of Geometric Isomers of 2-Butene on Gallate-Based Metal–Organic Frameworks. ACS Appl. Mater. Interfaces 2020, 12 (8), 9609–9616. https://doi.org/10.1021/acsami.9b20092. Chen, F.; Zhang, Z.; Yang, Q.; Yang, Y.; Bao, Z.; Ren, Q. Microporous Carbon Adsorbents Prepared by Activating Reagent-Free Pyrolysis for Upgrading Low-Quality Natural Gas. ACS Sustainable Chem. Eng. 2020, 8 (2), 977–985. https://doi.org/10.1021/acssuschemeng.9b05627. Zhu, J.; Chen, F.; Zhang, Z.; Li, M.; Yang, Q.; Yang, Y.; Bao, Z.; Ren, Q. M-Gallate (M = Ni, Co) Metal–Organic Framework-Derived Ni/C and Bimetallic Ni–Co/C Catalysts for Lignin Conversion into Monophenols. ACS Sustainable Chem. Eng. 2019, 7 (15), 12955–12963. https://doi.org/10.1021/acssuschemeng.9b02005. Zheng, F.; Guo, L.; Gao, B.; Li, L.; Zhang, Z.; Yang, Q.; Yang, Y.; Su, B.; Ren, Q.; Bao, Z. Engineering the Pore Size of Pillared-Layer Coordination Polymers Enables Highly Efficient Adsorption Separation of Acetylene from Ethylene. ACS Appl. Mater. Interfaces 2019, 11 (31), 28197–28204. https://doi.org/10.1021/acsami.9b09231. Wang, J.; Li, L.; Guo, L.; Zhao, Y.; Xie, D.; Zhang, Z.; Yang, Q.; Yang, Y.; Bao, Z.; Ren, Q. Adsorptive Separation of Acetylene from Ethylene in Isostructural Gallate‐Based Metal–Organic Frameworks. Chem. Eur. J. 2019, 25 (68), 15516–15524. https://doi.org/10.1002/chem.201903952. Li, L.; Wang, J.; Zhang, Z.; Yang, Q.; Yang, Y.; Su, B.; Bao, Z.; Ren, Q. Inverse Adsorption Separation of CO 2 /C 2 H 2 Mixture in Cyclodextrin-Based Metal–Organic Frameworks. ACS Appl. Mater. Interfaces 2019, 11 (2), 2543–2550. https://doi.org/10.1021/acsami.8b19590. Li, L.; Guo, L.; Zhang, Z.; Yang, Q.; Yang, Y.; Bao, Z.; Ren, Q.; Li, J. A Robust Squarate-Based Metal–Organic Framework Demonstrates Record-High Affinity and Selectivity for Xenon over Krypton. J. Am. Chem. Soc. 2019, 141 (23), 9358–9364. https://doi.org/10.1021/jacs.9b03422. Li, L.; Guo, L.; Pu, S.; Wang, J.; Yang, Q.; Zhang, Z.; Yang, Y.; Ren, Q.; Alnemrat, S.; Bao, Z. A Calcium-Based Microporous Metal-Organic Framework for Efficient Adsorption Separation of Light Hydrocarbons. Chemical Engineering Journal 2019, 358, 446–455. https://doi.org/10.1016/j.cej.2018.10.034. Gao, B.; Huang, M.; Zhang, Z.; Yang, Q.; Su, B.; Yang, Y.; Ren, Q.; Bao, Z. Hybridization of Metal–Organic Framework and Monodisperse Spherical Silica for Chromatographic Separation of Xylene Isomers. Chinese Journal of Chemical Engineering 2019, 27 (4), 818–826. https://doi.org/10.1016/j.cjche.2018.06.016. Zhao, Y.; Wang, J.; Bao, Z.; Xing, H.; Zhang, Z.; Su, B.; Yang, Q.; Yang, Y.; Ren, Q. Adsorption Separation of Acetylene and Ethylene in a Highly Thermostable Microporous Metal-Organic Framework. Separation and Purification Technology 2018, 195, 238–243. https://doi.org/10.1016/j.seppur.2017.11.044. Yang, L.; Cui, X.; Zhang, Z.; Yang, Q.; Bao, Z.; Ren, Q.; Xing, H. An Asymmetric Anion‐Pillared Metal–Organic Framework as a Multisite Adsorbent Enables Simultaneous Removal of Propyne and Propadiene from Propylene. Angew. Chem. 2018, 130 (40), 13329–13333. https://doi.org/10.1002/ange.201807652. Yang, L.; Cui, X.; Yang, Q.; Qian, S.; Wu, H.; Bao, Z.; Zhang, Z.; Ren, Q.; Zhou, W.; Chen, B.; Xing, H. Gas Separation: A Single-Molecule Propyne Trap: Highly Efficient Removal of Propyne from Propylene with Anion-Pillared Ultramicroporous Materials (Adv. Mater. 10/2018). Adv. Mater. 2018, 30 (10), 1870068. https://doi.org/10.1002/adma.201870068. Pu, S.; Wang, J.; Li, L.; Zhang, Z.; Bao, Z.; Yang, Q.; Yang, Y.; Xing, H.; Ren, Q. Performance Comparison of Metal–Organic Framework Extrudates and Commercial Zeolite for Ethylene/Ethane Separation. Ind. Eng. Chem. Res. 2018, 57 (5), 1645–1654. https://doi.org/10.1021/acs.iecr.7b04391. Li, L.; Yang, L.; Wang, J.; Zhang, Z.; Yang, Q.; Yang, Y.; Ren, Q.; Bao, Z. Highly Efficient Separation of Methane from Nitrogen on a Squarate-Based Metal-Organic Framework. AIChE J 2018, 64 (10), 3681–3689. https://doi.org/10.1002/aic.16335. Bao, Z.; Xie, D.; Chang, G.; Wu, H.; Li, L.; Zhou, W.; Wang, H.; Zhang, Z.; Xing, H.; Yang, Q.; Zaworotko, M. J.; Ren, Q.; Chen, B. Fine Tuning and Specific Binding Sites with a Porous Hydrogen-Bonded Metal-Complex Framework for Gas Selective Separations. J. Am. Chem. Soc. 2018, 140 (13), 4596–4603. https://doi.org/10.1021/jacs.7b13706. Bao, Z.; Wang, J.; Zhang, Z.; Xing, H.; Yang, Q.; Yang, Y.; Wu, H.; Krishna, R.; Zhou, W.; Chen, B.; Ren, Q. Molecular Sieving of Ethane from Ethylene through the Molecular Cross‐Section Size Differentiation in Gallate‐based Metal–Organic Frameworks. Angew. Chem. 2018, 130 (49), 16252–16257. https://doi.org/10.1002/ange.201808716. Zhang, X.; Wang, J.; Chen, S.; Bao, Z.; Xing, H.; Zhang, Z.; Su, B.; Yang, Q.; Yang, Y.; Ren, Q. A Spherical N-Methyl-d-Glucamine-Based Hybrid Adsorbent for Highly Efficient Adsorption of Boric Acid from Water. Separation and Purification Technology 2017, 172, 43–50. https://doi.org/10.1016/j.seppur.2016.08.002. Yang, W.; Wang, J.; Wang, H.; Bao, Z.; Zhao, J. C.-G.; Chen, B. Highly Interpenetrated Robust Microporous Hydrogen-Bonded Organic Framework for Gas Separation. Crystal Growth & Design 2017, 17 (11), 6132–6137. https://doi.org/10.1021/acs.cgd.7b01322. Wang, J.; Xie, D.; Zhang, Z.; Yang, Q.; Xing, H.; Yang, Y.; Ren, Q.; Bao, Z. Efficient Adsorption Separation of Acetylene and Ethylene via Supported Ionic Liquid on Metal‐organic Framework. AIChE J. 2017, 63 (6), 2165–2175. https://doi.org/10.1002/aic.15561. Wang, H.; Bao, Z.; Wu, H.; Lin, R.-B.; Zhou, W.; Hu, T.-L.; Li, B.; Zhao, J. C.-G.; Chen, B. Two Solvent-Induced Porous Hydrogen-Bonded Organic Frameworks: Solvent Effects on Structures and Functionalities. Chem. Commun. 2017, 53 (81), 11150–11153. https://doi.org/10.1039/C7CC06187K. Wang, J.; Bao, Z.; Xing, H.; Su, B.; Zhang, Z.; Yang, Q.; Yang, Y.; Ren, Q.; Chen, B. Incorporation of N -Methyl- d -Glucamine Functionalized Oligomer into MIL-101(Cr) for Highly Efficient Removal of Boric Acid from Water. Chem. Eur. J. 2016, 22 (43), 15290–15297. https://doi.org/10.1002/chem.201602599. Su, Y.; Chang, G.; Zhang, Z.; Xing, H.; Su, B.; Yang, Q.; Ren, Q.; Yang, Y.; Bao, Z. Catalytic Dehydration of Glucose to 5-Hydroxymethylfurfural with a Bifunctional Metal-Organic Framework. AIChE J. 2016, 62 (12), 4403–4417. https://doi.org/10.1002/aic.15356. Jin, W.; Yang, Q.; Huang, B.; Bao, Z.; Su, B.; Ren, Q.; Yang, Y.; Xing, H. Enhanced Solubilization and Extraction of Hydrophobic Bioactive Compounds Using Water/Ionic Liquid Mixtures. Green Chem. 2016, 18 (12), 3549–3557. https://doi.org/10.1039/C6GC00584E. Cui, X.; Chen, K.; Xing, H.; Yang, Q.; Krishna, R.; Bao, Z.; Wu, H.; Zhou, W.; Dong, X.; Han, Y.; Li, B.; Ren, Q.; Zaworotko, M. J.; Chen, B. Pore Chemistry and Size Control in Hybrid Porous Materials for Acetylene Capture from Ethylene. Science 2016, 353 (6295), 141–144. https://doi.org/10.1126/science.aaf2458. Chang, G.; Li, B.; Wang, H.; Hu, T.; Bao, Z.; Chen, B. Control of Interpenetration in a Microporous Metal–Organic Framework for Significantly Enhanced C 2 H 2 /CO 2 Separation at Room Temperature. Chem. Commun. 2016, 52 (17), 3494–3496. https://doi.org/10.1039/C5CC10598F. Bao, Z.; Chang, G.; Xing, H.; Krishna, R.; Ren, Q.; Chen, B. Potential of Microporous Metal–Organic Frameworks for Separation of Hydrocarbon Mixtures. Energy Environ. Sci. 2016, 9 (12), 3612–3641. https://doi.org/10.1039/C6EE01886F.

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