个人简介
Prof. Bernskoetter received the B.Sc. in Chemisty from Benedictine College, Atchison, KS in 2002 and the Ph.D. in Chemistry from Cornell University in 2006. He came to Brown in 2009 after two years as a Postdoctoral Research Fellow at the University of North Carolina-Chapel Hill where he worked with Prof. Maurice Brookhart. Prof. Bernskoetter's previous research has focused on dinitrogen functionalization and carbon-hydrogen bond activation.
研究领域
Research in the Bernskoetter lab focuses on the use of inorganic and organometallic complexes to address challenges relevant to our planet's growing energy concerns. Our initiatives employ techniques from synthetic organic and inorganic chemistry to study highly reactive molecules capable of mediating difficult chemical transformations.
近期论文
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Leonard, N. G.; Parker, G. V.; Williard, P. G.; Bernkoetter, W. H.Coordination Chemistry of Iridium Phosphine-Sulfonate Complexes. (Invited contribution to Dwight Sweigart Memorial Issue) J. Inorg. Organomet. Poly. Mat. 2014, 24, 157-163.
Koehne, I.; Schmeier, T. J.; Bielinski, E. A.; Pan, C. J.; Bernskoetter, W.H.; Takase, M. K.; Wurtele, C.; Hazari, N.; Schneider, S. Synthesis and Structure of Six Coordinate Iron Borohydride Complexes Supported by PNP Ligands. Inorg. Chem. 2014 ASAP.
Dong, J.; Williard, P. G.; Hazari, N.; Bernskoetter, W. H. The Effect of Sodium Cation on Metallacycle β-Hydride Elimination in CO2-Ethylene Coupling to Acrylates. Chem. Eur. J. 2014, Early View DOI: 10.1002/chem.201304196.
Xu, H.; Williard, P.G.; Bernskoetter, W.H. Intermolecular Methyl Group Exchange and Reversible P-Me Bond Cleavage at Cobalt(III) Dimethyl Halide Species. Organometallics, 2013, 32, 798-806.
Dong, J.; Schmeier, T. J.; Williard, P. G.; Hazari, N.; Bernskoetter, W. H. Lewis Acid Induced β-Elimination from a Nickelalactone: Efforts toward Acrylate Production from CO2 and Ethylene. Organometallics, 2013, 32, 2152-2159.
Bernskoetter, W. H.; Hazari, N. Computational Investigation of the Insertion of Carbon Dioxide into Four and Five Coordinate Iridium Hydrides. (Invited contribution to special issue: Small Molecule Activation by Reactive Metal Complexes) Eur. J. Inorg. Chem. 2013, 4032-4041.
Zhang, Y.; Hanna, B. S.; Dineen, A.; Williard, P. G.; Bernskoetter, W. H. Functionalization of Carbon Dioxide with Ethylene at Molybdenum Hydride Complexes. Organometallics, 2013, 32, 3969-3979.
Xu, H.; Williard, P.G.; Bernskoetter, W.H. C-CN Bond Activation of Acetonitrile using Cobalt(I) Organometallics, 2012, 31, 1588-1590
Wolfe, J.M.; Bernskoetter, W.H. Reductive Functionalization of Carbon Dioxide to Methyl Acrylate at Zerovalent Tungsten. Dalton Trans. 2012, 41, 10763-10768.
Bernskoetter, W.H.; Tyler, B.T. Kinetics and Mechanism of Molybdenum Mediated Acrylate Formation from Carbon Dioxide and Ethylene. Organometallics, 2011, 30, 520-527.
Leonard, N.G.; Williard, P.G.; Bernskoetter, W.H. Synthesis and Coordination Chemistry of Organoiridium Complexes Supported by an Anionic Tridentate Ligand. Dalton Trans., 2011, 40, 4300-4306.
Xu, H. Bernskoetter, W.H. Mechanistic Considerations for C-C Bond Reductive Coupling at a Cobalt(III) Center J. Am. Chem. Soc. 2011, 133, 14956-14959.