孙哲 - 天津大学 - 分子增值研究所

个人简介

Career and Education 2018- Professor, institute of molecular plus, Tianjin University. 教授，天津大学分子+研究院 2016-2018 Project assistant professor, department of chemistry, the University of Tokyo. 特任助理教授，东京大学化学系 2015-2016 Assistant professor, WPI-AIMR, Tohoku University. 助理教授，日本东北大学材料科学高等研究所 2014-2015 Research associate, WPI-AIMR, Tohoku University. 博士后，日本东北大学材料科学高等研究所 2009-2014 PhD, department of chemistry, National University of Singapore. 博士，新加坡国立大学化学系 2005-2009 BSc, department of chemistry, Sichuan University. 本科，四川大学化学系 Grants and Awards 国家优秀青年基金 (2022) 天津大学"卓荦计划“ (2023) 天津大学北洋青年学者 (2019) 天津市杰出青年基金（2019）国家高层次人才项目（2018） NSFC面上项目（主持，2024-2027） NSFC面上项目（主持，2020-2023） NSFC青年基金（主持，2019-2021）中石油横向项目（主持，2022-2024）日本学术振兴会（JSPS）科研费基磐C（Kakenhi-KibanC）（主持，2017-2018） Singapore National Institute of Chemistry gold medal (2014) 国家优秀自费留学生奖学金（2014）

研究领域

Organic Chemistry • Material Science Structural Chemistry • Supramolecular Chemistry We design and synthesize new structures based on conjugated π systems, driven by their function or our pure curiosity. With our molecules, we investigate their structure-property relationships and their applications in material science. Furthermore, we study their interactions with other molecules and try to build supramolecular systems.

近期论文

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T. Weng, Z. Xu, K. Li, Y. Guo, X. Chen, Z. Li, Z. Sun* "1,1′-Biolympicenyl: A Stable Non-Kekulé Diradical with a Small Singlet and Triplet Energy Gap" J. Am. Chem. Soc. 2024, doi.org/10.1021/jacs.4c09627. J. Hu, Q. Xiang, X. Tian, L. Ye, Y. Wang, Y. Ni, X. Chen,Y. Liu, G. Chen,* Z. Sun*"S-Shaped Helical Singlet Diradicaloid and Its Transformation to Circumchrysene via a Two-Stage Cyclization"J. Am. Chem. Soc. 2024, 146, 10321-10330. G. Chen,* J. Yu, L. Wu, X. Ji, J. Xu, C. Wang, S.e Ma, Q. Miao,L. Wang, C. Wang, S. E Lewis, Y. Yue,* Z. Sun,* Y. Liu,* B. Tang,*T. D James*"Fluorescent small molecule donors"Chem. Soc. Rev. 2024, 10.1039/D3CS00124E. Q. Zhou, Z. Xu, K. Li, X. Tian,* L. Ye,* Z. Sun*"Synthesis and Properties of A Strained Triple Nanohoop"Chem. Asia. J 2024, e202301131. Q. Xiang, L. Ye, L. Ma,* Z. Sun* "The Olympicenyl Radical and Its Derivatives"ChemPlusChem 2024, 89, e202300571. X. Liu, Z. Jin, F. Qiu, Y. Guo, Y. Chen, Z. Sun, L. Zhang*"Hexabenzoheptacene: A Longitudinally Multihelicene Nanocarbon with Local Aromaticity and Enhanced Stability"Angew. Chem. Int. Ed. 2024, e202407547. T. Jiao, Y. Ni, T. Xu, X. Hou, S. Wu, L. Ren, Z. Sun*, J. Wu*, “Synthesis of monolayer and persistent bilayer graphene fragments via a radical-mediated coupling approach”, Nature Synthesis, 2023, https://doi.org/10.1038/s44160-023-00348-w. L. Ye, S. Jiang, J. Hu, M. Wang, T. Weng, F. Wu, L. Cai, Z. Sun,* L. Ma* "Induction of Metabolic Reprogramming in Kidney by Singlet Diradical Nanoparticles" Adv. Mater. 2023, 10.1002/adma.202301338. Q. Zhou, X. Hou, J. Wang, Y. Ni, W. Fan, Z. Li, X. Wei, K. Li, W. Yuan,Z. Xu, M. Zhu, Y. Zhao, Z. Sun*, J. Wu*, “A Fused [5]Helicene Dimer with a Figure-Eight Topology: Synthesis, Chiral Resolution, and Electronic Properties” Angew. Chem. Int. Ed. 2023, e202302266. T. Shen, D. Dijkstra, A. Farrando-Pérez, P. G. Boj, J. M. Villalvilla, J. A. Quintana, Y. Zou, X. Hou, H. Wei, Z. Li, Z. Sun,* M. A. Díaz-García*, J. Wu*,“Fused Triangulene Dimers: Facile Synthesis by Intramolecular Radical-Radical Coupling and Application for Near Infrared Lasers“, Angew. Chem. Int. Ed., 2023, e202304197. B. Hou+, K. Li+, H. He, J. Hu, Z. Xu, Q. Xiang, P. Wang, X. Chen,* Z. Sun,* "Stable Crystalline Nanohoop Radical and Its Self-Association Promoted by van der Waals Interactions" Angew. Chem. Int. Ed. 2023, 62, e202301046 Z. Sun, W. Fan, Y. Han, W. Yuan, Y. Ni, J. Wang, H. Wei, Y. Zhao, Z. Sun*, J. Wu* ,"Helical fused 1,2:8,9-dibenzozethrene oligomers with up to 201° end-to-end twist: “one-pot” synthesis and chiral resolution" Chem. Sci. 2023, 14, 7922-7927. Q. Xiang, Y. Guo, J. Hu, Z. Li,* Z. Sun* "Formation of slipped dimer in 6-pentafluorophenyl-substituted olympicenyl radical", Chin. J. Chem. 2023, https://doi.org/10.1002/cjoc.202300370 P. Wang, J. Hu, Z. Xu, Z. Pu, S. Sato, X. Zhang,* W. Hu,* Z. Sun,*"Synthesis and structure elucidation of triarylmethyl radicals withanthryl substitution"Chem. Comm, 2023, 59, 2015-2018. Y. Guo, X. Wu, B. Hou, Q. Xiang, Y. Ni,* J. Li,* Z. Sun,*"Synthesis and Characterization of a Persistent Benzoanthracenyl Radical Derivative" Chem. Res. Chin. Univ., 2023, 39, 208-212. K. Li, Z. Sun,*"Cyclocondensation Reaction for the Synthesis of N-Containing Macrocycles" Chem. Lett., 2023, 10.1246/cl.230131. G. Liu, L. Gao, Y. Han, Y. Xiao, B. Du, J. Gong, J. Hu, F. Zhang, H. Meng, X. Li, X. Shi, Z. Sun, J. Wang, G. Dai,* C. Chi,* Q. Wang*"Symmetry-Broken Intermolecular Charge Separation of Cationic Radicals"Angew. Chem. Int. Ed. 2023, 62, e202301348. . H. Deng+, Z. Guo+, Y. Wang, K. Li, Q. Zhou, C. Ge, Z. Xu, S. Sato, X. Ma*, Z. Sun* "Modular Synthesis, Host-Guest Complexation and Solvation-Controlled Relaxation of Nanohoops with Donor-Acceptor Structures" Chem. Sci. 2022, 13, 14080-14089. M. Zhu, Q. Zhou, H. Cheng, Y. Sha,* V. I Bregadze, H. Yan,* Z. Sun,* X. Li* "Boron-Cluster Embedded Necklace-Shaped Nanohoops" Angew. Chem. Int. Ed. 2022, 61, e202213470 . C. Zong+, S. Yang+, Y. Sun, L. Zhang, J. Hu, W. Hu, R. Li,* Z. Sun* "Isomeric dibenzooctazethrene diradicals for high-performance air-stable organic field-effect transistors" Chem. Sci. 2022, 13, 11442-11447. B. Zhang, S. Wu, X. Hou, G. Li, Y. Ni, Q. Zhang, J. Zhu, Y. Han, P. Wang, Z. Sun*, J. Wu* "A graphyne spoked wheel" Chem. 2022, 8, 2831-2842. Z. Gong, Q. Xiang, K. Li, Z. Xu, J. Hu, Y. Ni, S. Sato, Z. Sun* "Pentagon-Containing Doublet Graphene Fragments with Edge-Dependent Spin/Charge Distribution" Chin. J. Chem. 2022, 40, 2525-2530. Q. Xiang, Z. Sun* "Doublet Open-Shell Graphene Fragments" Chem Asian. J. 2022, e202200251 Y. Guo, S. Ding, N. Zhang, Z. Xu, S. Wu, J. Hu, Q. Xiang,* Z. Li, X. Chen, S. Sato, J. Wu, Z. Sun* "π-Extended Doublet Open-Shell Graphene Fragments Exhibiting One-Dimensional Chain Stacking" J. Am. Chem. Soc. 2022, 144, 2095-2100 K. Li, Z. Xu, J. Xu, T. Weng, X. Chen, S. Sato, J. Wu, Z. Sun* "Overcrowded Ethylene-Bridged Nanohoop Dimers: Regioselective Synthesis, Multiconfigurational Electronic States, and Global Hückel/Möbius Aromaticity" J. Am. Chem. Soc. 2021, 143, 20419–20430 J. Hu, Q. Xiang, J. Xu, Z. Xu,* G. Chen,* Z. Sun* "Stable and twisted 5,6:12,13-dinaphthozethrene from angular π-extension" Chem. Comm. 2021, 57, 9712-9715 K. Li, Z. Sun* "Recent Advances in Dimeric Cycloparaphenylenes as Nanotube Fragments" Synlett. 2021, DOI: 10.1055/a-1534-3103 C. Zong+, X. Zhu+, Z. Xu, L. Zhang, J. Xu, J. Guo, Q. Xiang, Z. Zeng, W. Hu, J. Wu, R. Li*, Z. Sun* "Isomeric Dibenzoheptazethrenes for Air‐stable Organic Field‐effect Transistors" Angew. Chem. Int. Ed. 2021, 60, 16230-16236 Q. Xiang, J. Xu, J. Guo, Y. Dang, Z. Xu, Z. Zeng, Z. Sun* "Unveiling the Hidden σ‐Dimerization of a Kinetically Protected Olympicenyl Radical" Chem. Eur. J. 2021, 27, 8203-8213 K. Li, Z. Xu, H. Deng, Z. Zhou, Y. Dang, Z. Sun* “Dimeric Cycloparaphenylenes with a Rigid Aromatic Linker” Angew. Chem. Int. Ed. 2021, 60, 7649–7653 J. Guo, C. Zhou, S. Xie, S. Luo, T. Y Gopalakrishna, Z. Sun, J. Jouha, J. Wu, Z. Zeng* “Large Aromatic Hydrocarbon Radical Cation with Global Aromaticity and State-Associated Magnetic Activity” Chem. Mater. 2020, 32, 5927–5936. Q. Xiang, J. Guo, J. Xu, S. Ding, Z. Li, G. Li, H. Phan, Y. Gu, Y. Dang, Z. Xu, Z. Gong, W. Hu, Z. Zeng, J. Wu, Z. Sun* "Stable Olympicenyl Radicals and Their π-Dimers" J. Am. Chem. Soc. 2020, 142, 11022–11031 Z. Sun, T. Mio, K. Ikemoto, S. Sato, H. Isobe "Synthesis, Structures, and Assembly of Geodesic Phenine Frameworks with Isoreticular Networks of [n]Cyclo-para-phenylenes" J. Org. Chem 2019, 84, 3500–3507. Z. Sun, K. Ikemoto, T. M Fukunaga, T. Koretsune, R. Arita, S. Sato, H. Isobe "Finite phenine nanotubes with periodic vacancy defects" Science 2019, 363, 151–155. Z. Sun, T. Mio, T. Okada, T. Matsuno, S. Sato, H. Kono, H. Isobe "Unbiased rotational motions of an ellipsoidal guest in a tight yet pliable host" Angew. Chem. Int. Ed. 2019, 58, 2040–2044.