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Catalyst-Controlled Divergent Generations and Transformations of α-Carbonyl Cations from Alkynes. Junrui Zhou,† Weilin Wang,†* Fenfang Zuo,† Shupeng Liu, Pathan Mosim Amin, Kangbao Zhong, Ruopeng Bai,* Youliang Wang.* Angew. Chem. Int. Ed., 2023, e202302545. († 共同一作) Gold-Catalyzed Divergent N/O-Vinylations of trans-2-Butene-1,4-amino Alcohols with Alkynes and the Cascade Rearrangements/Cyclizations to Dihydropyrroles and Dihydrofurans. Xiao-Qian Zhang, Congdi Zhang, Zhiyou Hu, Youliang Wang.* Org. Lett., 2023, 25, 5800–5805. Catalyst-Controlled Divergent Cycloisomerizations of N-Propargyl Indoles. Yu Nie, Junrui Zhou, Youliang Wang.* Org. Lett., 2023, 25, 4350–4354. Gold-catalyzed formal (3 + 2) and (4 + 2) cycloadditions of alkynes to highly functionalized dihydropyrroles and tetrahydropyridines. Xiao-Qian Zhang, Tianyi Xu, Congdi Zhang, Chao Wang, Youliang Wang.* Org. Chem. Front., 2022, 10, 680-685. Design, development and applications of copper-catalyzed regioselective (4 + 2) annulations between diaryliodonium salts and alkynes. Weilin Wang*, Junrui Zhou, Chao Wang, Congdi Zhang, Xiao-Qian Zhang, Youliang Wang.* Commun Chem, 2022, 5, 145. Gold-catalyzed formal (3 + 2) and (4 + 2) cycloaddition reactions using propiolates: assembly of 2,3-dihydrofurans and 3,4-dihydropyrans via a multistep cascade process. Congdi Zhang, Xiao-Qian Zhang, Yu Nie, Chao Wang, Tianyi Xu, Junjie Zhang, Lu Bai, Chao Feng, Youliang Wang.* Org. Chem. Front., 2022, 9, 5872-5878. Copper-Catalyzed Chemo-, Regio-, and Stereoselective Multicomponent 1,2,3-Trifunctionalization of Internal Alkynes. Weilin Wang, Youliang Wang.* Org. Lett., 2022, 24, 1871-1875. General, Straightforward, and Atom-Economical Synthesis of Vinyl Triflimides. Lei Hao,† Qianwen Pan,† Congdi Zhang, Sen Wang, Weilin Wang, Junjie Zhang, Lu Bai, Youliang Wang.* Chem. Eur. J. 2021, 27, 12272-12275. († 共同一作)（封面文章） A DFT study on gold-catalyzed domino cyclization for post-Ugi synthesis of spiroindolines: insights on the origin of remarkable diastereoselectivity. Yunhe Li, Yi Zhou, Jie Zhang, Ruiyu Liu, Xiang Zhao,* Youliang Wang.* Catal. Sci. Technol., 2022, 12, 1678-1684. Exploring the chemistry of E/Z configuration in gold-catalyzed domino cyclization: Insights on the stereoselectivity. Yunhe Li,† Jie Zhang,† Xiang Zhao,* Youliang Wang.* Molecular Catalysis, 2022, 519, 112154. Pd(0)-Catalyzed Diastereo- and Enantioselective Intermolecular Cycloaddition for Rapid Assembly of 2-Acyl-methylenecyclopentanes. Barry M. Trost,* Zhijun Zuo, Youliang Wang. Org. Lett., 2021, 23, 979-983. Non‐Diazo C−H Insertion Approach to Cyclobutanones through Oxidative Gold Catalysis. Zhitong Zheng,† Youliang Wang,† Xu Ma, Yuxue Li, Liming Zhang.* Angew. Chem. Int. Ed., 2020, 59, 17398-17402. († 共同一作) Pd(0)-Catalyzed Chemo-, Diastereo-, and Enantioselective α-Quaternary Alkylation of Branched Aldehydes. Barry M. Trost,* Zhijun Zuo,† Youliang Wang,† and Johnathan E. Schultz. ACS Catal., 2020, 10, 9496-9503. († 共同一作) Total synthesis of bryostatin 3. Barry M. Trost, Youliang Wang, Andreas K. Buckl, Zhongxing Huang, Minh H. Nguyen, Olesya Kuzmina, Science 2020, 368, 1007-1011, DOI: 10.1126/science.abb7271 Use of α-Trifluoromethyl Carbanions for Palladium-Catalysed Asymmetric Cycloadditions. Barry M. Trost,* Youliang Wang,† Chao-I (Joey) Hung.† Nature Chemistry 2020, 12, 294-301. († 共同一作) Palladium-Catalyzed Regio-, Enantio-, and Diastereoselective Asymmetric [3 + 2] Cycloaddition Reactions: Synthesis of Chiral Cyclopentyl Phosphonates. Barry M. Trost,* Anand H. Shinde,† Youliang Wang,† Zhijun Zuo, Chang Min. ACS Catal., 2020, 10, 1969-1975. († 共同一作) A Deprotonation Approach to the Unprecedented Amino-Trimethylenemethane Chemistry: Regio-, Diastereo-, and Enantioselective Synthesis of Complex Amino Cycles. Barry M. Trost,* Youliang Wang. Angew. Chem. Int. Ed., 2018, 57, 11025-11029. A C-H Insertion Approach to Functionalized Cyclopentenones. Youliang Wang, Maxence Zarca, Liu-Zhu Gong, Liming Zhang.* J. Am. Chem. Soc., 2016, 138, 7516-7519. Intramolecular Insertions into Unactivated C(sp3)-H Bonds by Oxidatively Generated β-Diketone-α-Gold Carbenes: Synthesis of Cyclopentanones. Youliang Wang, Zhitong Zheng, Liming Zhang.* J. Am. Chem. Soc., 2015, 137, 5316-5319. Ruthenium-Catalyzed Oxidative Transformations of Terminal Alkynes to Ketenes by Using Tethered Sulfoxides: Access to β-Lactams and Cyclobutanones. Youliang Wang, Zhitong Zheng, Liming Zhang.* Angew. Chem. Int. Ed., 2014, 53, 9572-9576. Gold-Catalyzed Cyclizations of cis-Enediynes: Insights into the Nature of Gold–Aryne Interactions. Youliang Wang, Akop Yepremyan, Subir Ghorai, Robert Todd, Donald H. Aue,* Liming Zhang.* Angew. Chem. Int. Ed., 2013, 52, 7795-7799. Direct Conversion of Internal Alkynes into α-Iodoenones: One-Step Collaborative Iodination and Oxidation. Youliang Wang, Alexandre Genoux, Subir Ghorai, Hongyi Chen, Robert Todd, Liming Zhang.* Adv. Synth. Catal., 2016, 358, 1417-1420. Recent Developments in the Chemistry of Heteroaromatic N-Oxides.Youliang Wang, Liming Zhang. Synthesis 2015, 47, 289. Au Catalyzed Oxidative Cyclisation. Zhitong Zheng, Zhixun Wang, Youliang Wang, Liming Zhang. Chem. Soc. Rev. DOI: 10.1039/C5CS00887E. Ruthenium-catalyzed rearrangement of propargyl sulfoxides: formation of α,β-unsaturated thioesters. Renhua Zheng, Youliang Wang, Liming Zhang. Tetrahedron Lett., 2015, 56, 3144-3146. [3,3]-Sigmatropic Rearrangement versus Carbene Formation in Gold-Catalyzed Transformations of Alkynyl Aryl Sulfoxides: Mechanistic Studies and Expanded Reaction Scope. Biao Lu, Yuxue Li, Youliang Wang, Donald H. Aue, Yingdong Luo, Liming Zhang. J. Am. Chem. Soc., 2013, 135, 8512-8524. Palladium-catalyzed heteroannulation of [60]fullerene with N-(2-arylethyl) sulfonamides via C–H bond activation. Yi-Tan Su, Youliang Wang, Guan-Wu Wang. Org. Chem. Front., 2014, 1, 689-693.