曹迁永 - 南昌大学

研究领域

1．荧光有机小分子的设计与合成：合成出了一系列新的含蒽、芘、丹酰绿及多联吡啶荧光团的荧光分子；研究不同推位电子对荧光分子发光能量与强度的影响；通过引入一些强电子给体二茂铁基及强电子给体如咪唑与三唑阳离子，研究其对荧光分子发光影响及电子转移机制。其中一些长寿命电荷分离荧光体有望用于太阳能电池光敏剂。 2.发光化合物离子检测与器件化：我们合成了一系列含阴离子氢键给体或金属离子配位点的荧光化合物，可用于有机溶剂及环境中阴/阳离子检测。同时，开展了将荧光小分子负载到无机基质如MCM-41及有机高分子材料上，拓展了化合物的应用。

近期论文

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Jin-Zhu Ge, Yang Zou, Yong-Hong Yan, Sen Lin, Xiao-Fang Zhao, Qian-Yong Cao*, A new ferrocene–anthracene dyad for dual-signaling sensing of Cu(II) and Hg(II), J. Photochem. & Photobio. A: Chem., 2016, 315, 67–75. Zhi-Cheng Wang, Zichen Wang, Qian-Yong Cao, Sen Lin and Zhong-Wei Wang, Amide-Triazolium-Appended Anthracenes for Turn-On Fluorescence Sensing of Anions in Noncompetitive and Competitive Solvents, ChemPlusChem, 2016, DOI: 10.1002/cplu.201500527 Jin-Zhu Ge, Zhanghua Liu, Qian-Yong Cao, Yong Chen and Jiang-Hua Zhu, A Pyrene-functionalized Polynorbornene for Ratiometric Fluorescence Sensing of Pyrophosphate, Chem. Asian J., 2016, 5，　687-690. Pei-Shui Yao, Zhanghua Liu, Jin-Zhu Ge, Yong Chen, Qian-Yong Cao*, “A novel polynorbornene-base chemosensor for fluorescence sensing of Zn2+ and Cd2+ and subsequent pyrophosphate in aqueous solution”, Dalton Trans., 2015, 44, 7470–7476. Li Zhou, Xiang-Tian Fan, Yu-Di Xu, Qian-Yong Cao*, Pyrenyl-functionalized ferrocenes for multisignaling recognition of anions, New J. Chem., 2015, 39, 8087–8092. Pei-Shui Yao, Qian-Yong Cao*, Rong-Peng Peng, Jing-Hua Liu, “Quinoline-functionalized norbornene for fluorescence recognition of metal ions”, J. Photochem. & Photobio. A: Chem., 2015, 305, 11–18 王智成, 戴博娜, 丘继芳, 曹迁永, 葛金柱, 一种二茂铁与联萘酚修饰环三唑的合成及其对Zn2＋双信号识别, Chin. J. Org. Chem. 2015, 35, 2383～2388. Bo-Na Dai, Qian-Yong Cao*, Ling Wang, Zi-Chen Wang, Zhenyu Yang, “A new naphthalene-containing triazolophane for fluorescence sensing of mercury(II) ion”, Inorg. Chim. Acta, 2014, 423, 163–167. Qian-Yong Cao*, Pei-Shui Yao, Xian-Fang Zhao, Jiang-Hua Liu, Zhong-Wei Wang, “A new dinuclear ferrocene with amide–thiourea binding sites for dual electrochemical sensing to Hg(II) and anions”, Inorg. Chim. Acta, 2014, 419, 147–151. Qian-Yong Cao*, Yuan-Ming Han, Pei-Shui Yao, Wen-Fu Fu, Yu Xie, Jing-Hua Liu, A new ferrocene–anthracene dyad bearing amide and triazolium donors for dual-signaling sensing to anions, Tetrahedron Lett. 2014, 55, 248–251. Qian-Yong Cao*, Ming Li, Li Zhou, and Zhong-Wei Wang, New 2,2':6,2''-terpyridines as Colorimetric and fluorescent Sensors for Fluoride ions, RSC Advances, 2014, 4, 4041–4046. Qian-Yong Cao*, Yuan-Ming Han, Hong-Ming Wang, Yu Xie, “A new pyrenyl-appended triazole for fluorescent recognition of Hg2+ ion in aqueous solution”, Dyes and Pigments, 2013, 99, 798–802. Zhong-Wei Wang, Qian-Yong Cao*, Sen Lin, Li Zhuo, Zhi-Hua Li, “2,6-Diphenylpyridine-based fluorophores: synthesis, photophysical properties and effects of protonation”, J. Photochem. & Photobio. A: Chem., 2013, 251, 106–122. Zhi-Ping Wu, Gui-Jun Liu, Cai-Cai Zhu, Zhi-Mei Li, Xi-Cun Gao*, Qian-Yong Cao*,“Violet-blue or pure-blue emitting triphenylamine derivatives: synthesis and properties”, Can. J. Chem, 2013, 91, 10436–1047. Qian-Yong Cao*, Zi-Chen Wang, Ming Li, Jing-Hua Liu, “A novel anthracene-appended triazolium for fluorescent sensing to H2PO4─”, Tetrahedron Lett. 2013, 54, 3933–3936. Yu Xie*, Xiao-Wei Hong, Qian-Yong Cao,* Rong Zhong, Yunhua Gao, Sifeng Yan, Lei Shi, Kai Zhang and Qiang Nai, “La/Sm-doped strontium-ferrite/poly-m-toluidine composites obtained by in situ polymerization”, Current Nanoscience, 2013, 9, 371–376. Qian-Yong Cao, Tuhin Pradhan, Min Hee Lee, Kwanghyun No, Jong Seung Kim “Ferrocene-based anion receptor bearing amide and triazolium donor groups”, Analyst, 2012, 137, 4454–4457. Qian-Yong Cao, Tuhin Pradhan, Min Hee Lee, Dong Hoon Choi, Jong Seung Kim, “Cleft-form electrochemical anion chemosensor with amide and triazole donor groups” Tetrahedron Lett. 2012, 53, 4917–4920. Qian-Yong Cao, Tuhin Pradhan, Sungtae Kim, and Jong Seung Kim “Ferrocene-Appended Aryl Triazole for Electrochemical Recognition of Phosphate Ions”, Org. Lett., 2011, 13, 4386–4389. Qian-Yong Cao, Jun Feng Zhang, Wen Xiu Ren, Kihang Choi, Jong Seung Kim, “Ferrocene-based novel electrochemical In3+ sensor”, Tetrahedron Lett. 2011, 52, 4464–4467. Min Hee Lee，Qian-Yong Cao, Sung Kuk Kim, Jonathan L. Sessler, and Jong Seung Kim, “Anion Responsive TTF-Appended Calix[4]arenas . Synthesis and Study of Two Different Conformers”, J. Org. Chem., 2011, 76, 870–874. Qian-Yong Cao, Min Hee Lee, Jun Feng Zhang, Wen Xiu Ren, Jong Seung Kim, “Ferrocene-based novel chemodosimeter for mercury ion recognition”, Tetrahedron Lett. 2011, 52, 2786–2789. Qian-Yong Cao*, Xin Lu, Zhi-Hua Li, Li Zhou, Zhen-Yu Yang, Jiang-Hua Liu “Synthesis and characterization of ferrocenyl-acridine dyads and their multiresponse to Proton and Metal Cations”, J. Organomet. Chem. 2010, 695, 1323–1327. Zhong-Wei Wang, Qian-Yong Cao*, Xin Huang, Sen Lin, Xi-Cun Gao, “Synthesis, structure and electronic spectra of new three-coordinated copper(I) complexes with tricyclohexylphosphine and diimine ligands”, Inorg. Chim. Acta 2010, 363, 15–19. Qian-Yong Cao*, Yan-Hui Chen, Jiang-Hua Liu, Xi-Cun Gao. Novel luminescent Europium(III) Complexes Covalently Bonded to bis(phos-phino)amine oxide functionaliaed MCM-41. Inorg. Chem. Commun. 2009, 12, 48–51.