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研究领域

1. 基于负载过渡金属催化剂和绿色溶剂的有机合成方法学研究 2. 金属有机试剂参与的共轭烯烃的立体选择合成方法学研究 3. 聚芳醚酮等高性能聚合物的设计、合成与性能研究

近期论文

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1. Hong Zhao, Mingzhu Cheng, Jiatao Zhang, Mingzhong Cai,* Recyclable and reusable PdCl2(PPh3)2/PEG-2000/H2O system for the carbonylative Sonogashira coupling reaction of aryl iodides with alkynes, Green Chem., 2014, 16, 2515- 2522. 2. Wenyan Hao, Jiangbo Zeng, Mingzhong Cai,* Copper(I)-catalyzed tandem reaction of o-alkynylphenyl isothiocyanates with isocyanides: a rapid synthesis of 5H-benzo[d]imidazo- [5,1-b][1,3]thiazines, Chem. Commun., 2014, 50, 11686-11689. 3. Wenyan Hao, Yuanyuan Jiang, Mingzhong Cai,* Synthesis of Indolyl Imidazole Derivatives via Base-Promoted Tandem Reaction of Enyne-Carbodiimides with Isocyanides, J. Org. Chem., 2014, 79, 3634-3640. 4. Hong Zhao, Wen He, Ruiya Yao, Mingzhong Cai,* Heterogeneous Copper-Catalyzed Cascade Three-Component Reaction of Amines, Carbon Disulfide and 2-Iodoanilines Leading to 2-Aminobenzothiazoles, Adv. Synth. Catal., 2014, 356, 3092-3098. 5. Wenyan Hao, Shiyun Xie, Yichao Wu, Mingzhong Cai,* Stereoselective synthesis of functionalized (1E,5E)-1,5-dien-3-ynes containing ester or sulfonyl groups by palladium- catalyzed addition and cross-coupling reactions, New J. Chem., 2014, 38, 2686-2692. 6. Bin Huang, Lin Yin, Mingzhong Cai,* A phosphine-free heterogeneous coupling of acyl chlorides with terminal alkynes catalyzed by an MCM-41-immobilized palladium complex, New J. Chem., 2013, 37, 3137-3144. 7. Ruian Xiao, Hong Zhao, Mingzhong Cai,* MCM-41-immobilized bidentate nitrogen copper(I) complex: a highly efficient and recyclable catalyst for Buchwald N-arylation of indoles, Tetrahedron, 2013, 69, 5444-5450. 8. Hong Zhao, Lin Yin, Mingzhong Cai,* A Phosphane-Free, Atom-Efficient Cross-Coupling Reaction of Triarylbismuths with Acyl Chlorides Catalyzed by MCM-41-immobilized Palladium Complex, Eur. J. Org. Chem., 2013, 1337-1345. 9. Hong Zhao, Weisen Yang, Shiyun Xie, Mingzhong Cai,* Stereoselective Synthesis of Difunctionalized 1,3-DIenes Containing Tin and Sulfonyl Groups by Palladium-Catalyzed Regio- and Stereocontroplled Addition Reactions, Eur. J. Org. Chem., 2012, 831-836. 10. Ruian Xiao, Ruiya Yao, Mingzhong Cai,* Practical Oxidative Homo- and Heterocoupling of Terminal Alkynes Catalyzed by Immobilized Copper in MCM-41, Eur. J. Org. Chem., 2012, 4178-4184.

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