刘统信 - 河南师范大学 - 化学化工学院

个人简介

教育与研究经历： 2017年1月—至今河南师范大学化学化工学院副教授 2012年8月—2016年12月河南师范大学化学化工学院讲师 2007年9月—2012年6月中国科学技术大学化学与材料科学学院理学博士 2005年9月—2007年6月山东师范大学化学化工与材料科学学院理学学士近年来主持的主要科研项目: 1. 新型开孔富勒烯的设计、合成与光伏性能研究，国家自然科学基金 (U1904181) 2. 河南省高校科技创新人才支持计划 (18HASTIT006) 3. 富勒烯氮杂衍生物合成，中国博士后科学基金 (2015T80769) 4. 新型富勒烯含氮杂环化合物的合成及其衍生化研究，国家自然科学基金 (21302044) 5. 新型富勒烯碳杂稠环衍生物材料的合成与性能研究，国家自然科学基金 (U1304524) 6. 利用串联反应构建新型杂环富勒烯衍生物研究，中国博士后科学基金 (2013M530339) 7. 芳基酰胺化合物在构建结构多样性富勒烯衍生物中的应用，河南师范大学优秀青年科学基金 (14YQ004)

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Tong-Xin Liu,* Pangting Yang, Nana Ma, Xiaojun Li, Xin Wang, Jinliang Ma, and Guisheng Zhang*, Synthesis of [60]Fullerene-Fused Allylbenzofurans via Palladium-Catalyzed Migration Reaction Chin. J. Chem., 2023, 41, 1733-1739. Tong-Xin Liu,* Xin Wang, Pengling Zhang, Panting Yang, Xiaojun Li, and Guisheng Zhang*, Assembly of Diverse [60]Fullerene-Fused Tricyclic Scaffolds via a Palladium-Catalyzed Cascade [2 + 2 + 2] Annulation Reaction Org. Lett., 2022, 24, 9102-9106. Tong-Xin Liu,* Chuanjie Zhang, Pengling Zhang, Xin Wang, Jinliang Ma, and Guisheng Zhang*, Palladium-catalyzed decarboxylative [2 + 3] cyclocarbonylation reactions of [60]fullerene: selective synthesis of [60]fullerene-fused 3-vinylcyclopentan-4-ones and cyclopentane-4-carbaldehydes Org. Chem. Front., 2022, 9, 5564-5570. Tong-Xin Liu,* Xue Zhu, Shilu Xia, Xin Wang, Pengling Zhang, and Guisheng Zhang*, NHC-Catalyzed Three-Component Hydroalkylation Reactions of [60]Fullerene: An Umpolung Approach to Diverse Monoalkylated Hydrofullerenes Org. Lett., 2022, 24, 3691-3695. Tong-Xin Liu,* Han Wu, Nana Ma, Chuanjie Zhang, Pengling Zhang, Jinliang Ma, and Guisheng Zhang*, Acid-Responsive Dissociation of Ferrocene Compounds: Diels−Alder Diene Equivalents for Selective Preparation of [60]Fullerene-Fused Bicyclo[2.2.1]hept-5-enes J. Org. Chem., 2022, 87, 3104-3113. Jinliang Ma, Tong-Xin Liu,* Pengling Zhang, Xuna Zhao and Guisheng Zhang*, Metal-Free-Catalyzed Three-Component [2+2+2] Annulation Reaction of [60]Fullerene, Ketones, and Indoles: Access to Diverse [60]Fullerene-Fused 1,2-Tetrahydrocarbazoles Org. Lett., 2021, 23, 1775-1781. Jinliang Ma, Tong-Xin Liu,* Pengling Zhang, Chuanjie Zhang and Guisheng Zhang*, Palladium-catalyzed domino spirocyclization of [60]fullerene: synthesis of diverse [60]fullerene-fused spiro[4,5]/[5,5] derivatives Chem. Commun., 2021, 57, 49-52. Conghui Wu, Tong-Xin Liu,* Pengling Zhang, Xue Zhu, and Guisheng Zhang*, Iron-Catalyzed Redox-Neutral Radical Cascade Reaction of [60]Fullerene with γ,δ-Unsaturated Oxime Esters: Preparation of Free (N–H) Pyrrolidino[2¢,3¢:1,2]fullerenes Org. Lett., 2020, 22, 7327-7332. Qingfeng Liu, Tong-Xin Liu,* Jinliang Ma, and Guisheng Zhang*, Palladium-Catalyzed Three-Component Tandem Coupling−Carboannulation Reaction Leading to Polysubstituted [60]Fullerene-Fused Cyclopentanes Org. Lett., 2020, 22, 284-289. Qingfeng Liu, Tong-Xin Liu,* Yifei Ru, Xue Zhu, and Guisheng Zhang*, Palladium-catalyzed decarboxylative heterocyclizations of [60]fullerene: preparation of novel vinyl-substituted [60]fullerene-fused tetrahydrofuran s/pyrans/quinolones Chem. Commun., 2019, 55, 14498-14501. Tong-Xin Liu,* Juan Wei, Pengling Zhang,* Yifei Ru, Jinliang Ma, Xingjie Zhang, Nana Ma, and Guisheng Zhang*, Copper-Catalyzed N−H/C−H Sequential Relay Oxidative Radical Carboannulation: Construction of Diversely Substituted [60]Fullerene-Fused Tetrahydrocyclopenta[b]indoles Org. Lett., 2019, 21, 6461-6465. Qingfeng Liu, Tong-Xin Liu,* Nana Ma, Chenhao Tu, Ruoya Wang, and Guisheng Zhang*, Cu(II)/Mn(III)-Promoted Synergistic Radical N‑Heteroannulation Reaction: Synthesis of [60]Fullerene-Fused Tetrahydroquinoline Derivatives J. Org. Chem., 2019, 84, 7255-7264. Tong-Xin Liu,* Shuaishuai Yue, Changgeng Wei, Nana Ma,*Pengling Zhang, Qingfeng Liu, and Guisheng Zhang*, Solvent-promoted catalyst-free regioselective N-incorporation multicomponent domino reaction: rapid assembly of π-functionalized [60]fullerene-fused dihydrocarbolines Chem. Commun., 2018, 54, 13331-13334. Beibei Hu, Tong-Xin Liu,* Pengling Zhang, Qingfeng Liu, Jingjing Bi, Lei Shi, Zhiguo Zhang, and Guisheng Zhang*, N‑Heterocyclic Carbene-Catalyzed α,β-Unsaturated Aldehyde Umpolung in Fullerene Chemistry: Construction of [60]Fullerene-Fused Cyclopentan-1-ones and Cyclohex-2-en-1-ones Org. Lett., 2018, 20, 4801-4805. Tong-Xin Liu,* Shaoshuai Hua, Nana Ma, Pengling Zhang, Jingjing Bi, Zhiguo Zhang, and Guisheng Zhang*. Reactivity and Synthetic Applications of a-Functionalized Oxime Acetates: Divergent Access to Fulleropyrrolidines and Mono- and Disubstituted 1-Fulleropyrrolines via Copper-Catalyzed Redox-Neutral N-Heteroannulation with [60]Fullerene Adv. Synth. Catal., 2018, 360, 142-152. Shilu Xia, Tong-Xin Liu,* Pengling Zhang, Jinliang Ma, Qingfeng Liu, Nana Ma, Zhiguo Zhang, and Guisheng Zhang*. Broad Synthesis of Disubstituted Dihydrofuran-Fused [60]Fullerene Derivatives via Cu(I)/Ag(I)-Mediated Synergistic Annulation Reaction J. Org. Chem., 2018, 83, 862-870. Di Chao, Tong-Xin Liu,* Nana Ma, Pengling Zhang, Zheng Fu, Jinliang Ma, Qingfeng Liu, Fengjin Zhang, Zhiguo Zhang and Guisheng Zhang*. Silver(I)-mediated three-component annulation reaction of [60]fullerene, sulfonylhydrazones, and nitriles: leading to diverse disubstituted [60]fullerene-fused dihydropyrroles Chem. Commun., 2016, 52, 982-985. Tong-Xin Liu,* Jinliang Ma, Di Chao, Pengling Zhang, Nana Ma, Qingfeng Liu, Lei Shi, Zhiguo Zhang, and Guisheng Zhang*. Synthesis of C60-Fused Tetrahydrocarbazole/Dibenzothiophene/ Benzothiophene and Dibenzofuran Derivatives via Metal-Free Oxidative Dehydrogenative Carboannulation Org. Lett., 2016, 18, 4044-4047. Tong-Xin Liu,* Jinliang Ma, Di Chao, Pengling Zhang, Qingfeng Liu, Lei Shi, Zhiguo Zhang and Guisheng Zhang*. AgNO2-mediated cleavage of the N–N bond of sulfonylhydrazones and oxygen transfer: access to fulleroisoxazolines via radical cyclization with [60]fullerene Chem. Commun., 2015, 51, 12775-12778. Tong-Xin Liu,* Zhenbei Zhang, Qingfeng Liu, Pengling Zhang, Penghao Jia, Zhiguo Zhang, and Guisheng Zhang*. Synthesis of [60]Fullerene-Fused Tetrahydroazepinones and Azepinonimines via Cu(OAc)2-Promoted N-Heteroannulation Reaction Org. Lett., 2014, 16, 1020-1023. Tong-Xin Liu,* Yuquan Liu, Di Chao, Pengling Zhang, Qingfeng Liu, Lei Shi, Zhiguo Zhang, and Guisheng Zhang*. Iron-Mediated Internal-Oxidant Relay Cascade Reaction: Strategy to Synthesize Fullerenooxazoles and Hydroxyfullerenyl Amides J. Org. Chem., 2014, 79, 11084-11090. Tong-Xin Liu, Fa-Bao Li, Dian-Bing Zhou, and Guan-Wu Wang*. Ferric Perchlorate Promoted Reaction of [60]Fullerene with N−Sulfonyl Aldimines: Synthesis and Functionalization of Fulleroxazolidines J. Org. Chem., 2015, 80, 11986-11992. Tong-Xin Liu, Tao Wei, San-E Zhu, Guan-Wu Wang*, Mingzhi Jiao, Shangfeng Yang*, Faye L. Bowles, Marilyn M. Olmstead*, and Alan L. Balch*. Azide Addition to an Endohedral Metallofullerene: Formation of Azafulleroids of Sc3N@Ih-C80 J. Am. Chem. Soc., 2012, 134, 11956-11959. Tong-Xin Liu, Fa-Bao Li, and Guan-Wu Wang*. Synthesis of [60]Fullerene-Fused Tetrahydronaphthalene and Indane Derivatives via a Pathway Switched by Aluminum Chloride Org. Lett., 2011, 13, 6130-6133. Guan-Wu Wang,* Tong-Xin Liu, Mingzhi Jiao, Nan Wang, San-E Zhu, Chuanbao Chen, Shangfeng Yang*, Faye L. Bowles, Dr. Christine M. Beavers, Marilyn M. Olmstead*, Brandon Q. Mercado, and Alan L. Balch*. The Cycloaddition Reaction ofIh-Sc3N@C80with 2-Amino-4,5- diisopropoxybenzoic Acid and Isoamyl Nitrite to Produce an Open-Cage Metallofullerene, Angew. Chem., Int. Ed., 2011, 50, 4658-4662.

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