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研究领域

1. 硼氮氢过渡金属配合物的合成、结构、反应性及性能研究 2. 新型硼烷衍生物的合成及其在储氢材料中的应用

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Qianyi Zhao, Jiaxuan Li, Ewan J.M. Hamilton, Xuenian Chen. The Continuing Story of the Diammoniate of Diborane. J. Organomet. Chem. 2015, in press, DOI: 10.1016/j.jorganchem.2015.05.027 Xiao-Yu Cao, Qianyi Zhao, Zhiqun Lin *, Haiping Xia *. The Chemistry of Aromatic Osmacycles.” Acc. Chem. Res. 2014, 47(2), 341–354. Qianyi Zhao, Xiao-Yu Cao,* Ting Bin Wen, Haiping Xia.* From Osmium Hydrido Vinylidene to Osmacycles: The Key Role of Osmabutadiene Intermediates. Chem.–Asian. J. 2013, 8, 269–275. Qianyi Zhao, Jun Zhu, Zi-Ao Huang, Xiao-Yu Cao,* Haiping Xia.* Conversions of Osmabenzyne and Isoosmabenzene. Chem.–Eur. J. 2012, 18, 11597–11603. (Inside Cover) Qianyi Zhao, Lei Gong, Chunfa Xu, Jun Zhu,* Xumin He, Haiping Xia.* Stable Iso-osmabenzenes from a Formal [3+3] Cycloaddition Reaction of Metal Vinylidene with Alkynols. Angew. Chem. Int. Ed. 2011, 50, 1354-1358. Bin Liu, Qianyi Zhao, Huijuan Wang, Birong Zeng, Xiaoyu Cao, Xia, Haiping.* Reactivity Study of a Hydroxyl Coordinated Osmium Vinyl Complex OsCl2(PPh3)2[CH=C(PPh3)CHPh(OH)]. Sci. China Chem. 2013, 56, 1105–1111. Bin Liu, Qianyi Zhao, Huijuan Wang, Jinxiang Chen, Xiaoyu Cao, Zexing Cao, Xia, Haiping.* Synthesis of Osmapyridiniums by [4+2] Cycloaddition Reaction between Osmium Alkenylcarbyne and Nitriles. Chin. J. Chem. 2012, 30, 2158–2168. Jinbo Huang, Ran Lin, Liqiong Wu, Qianyi Zhao, Congqing Zhu, Ting Bin Wen, Haiping Xia.* Synthesis, Characterization, and Electrochemical Properties of Bisosmabenzenes Bridged by Diisocyanides. Organometallics 2010, 29, 2916-2925. Bin Liu, Hujun Xie, Huijuan Wang, Liqiong Wu, Qianyi Zhao, Jinxiang Chen, Ting Bin Wen, Zexing Cao,* Haiping Xia.* Selective Synthesis of Osmanaphthalene and Osmanaphthalyne by Intramolecular C-H Activation. Angew. Chem. Int. Ed. 2009, 48, 5461-5464. Hong Zhang, Liqiong Wu, Ran Lin, Qianyi Zhao, Guomei He, Fangzu Yang, Ting Bin Wen, Haiping Xia.* Synthesis, Characterization and Electrochemical Properties of Stable Osmabenzenes Containing PPh3 Substituents. Chem. Eur. J. 2009, 15, 3546-3559.

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