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个人简介

学习经历 1996/9—1999/6,中科院兰州化学物理研究所,博士 1985/9—1988/6,兰州大学,化学系,硕士 1979/9—1983/7,兰州大学,化学系,学士 研究工作经历 2013/3—现在,河南师范大学,化学化工学院,教授 2001/1—2012/2,俄亥俄州立大学,化学系,博士后研究员,副研究员,研究员 1999/6—2000/12,河南教育学院,化学系,副教授,教授 1988/6—1996/8,河南教育学院,化学系,讲师,副教授 1983/7—1985/8,河南大学,化学系,助教,

研究领域

硼化学,储氢材料, 金属有机化学,配位化学

近期论文

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Organoboron-Functionalization Enables the Hierarchical Assembly of Giant Polyoxometalate Nanocapsules. Li, S. J.; Zhou, Y. F.; Ma, N. N.; Zhang, J.; Zheng, Z. P.*; Streb, C.* ; Chen, X. N. * Angew. Chem., Int. Ed. 2020, 59 (22), 8537-8540. https://onlinelibrary.wiley.com/doi/10.1002/anie.202003550 Chemical Syntheses of Two-Dimensional Boron Materials. Chen, X. M.; Chen, X. N.* Chem 2020, 6 (2), 324-326. A New Perspective on Borane Chemistry: The Nucleophilicity of the B-H Bonding Pair Electrons. Zhao, Q.; Dewhurst, R. D.; Braunschweig, H.; Chen, X.* Angew. Chem., Int. Ed. 2019, 58 (11), 3268-3278. https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201809733 Facile Synthesis of Unsolvated Alkali Metal Octahydrotriborate Salts MB3H8 (M=K, Rb, and Cs), Mechanisms of Formation, and the Crystal Structure of KB3H8. Xi-Meng Chen+,Nana Ma+,Xin-Ran Liu, Changgeng Wei, Chong-Chao Cui, Bu-La Cao,Yanhui Guo,* Lai-Sheng Wang,* Qinfen Gu, and Xuenian Chen* Angew. Chem., Int. Ed. 2019, 58 (9), 2720-2724 https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201812795 Elucidation of the Formation Mechanisms of Octahydrotriborate Anion (B3H8−) Through the Nucleophilicity of the B−H Bond Xi-Meng Chen,†,⊥ Nana Ma,†,⊥ Qian-Fan Zhang,‡ Jin Wang,† Xiaoge Feng†, Changgeng Wei,† Lai-Sheng Wang,*,‡ Jie Zhang,*, † and Xuenian Chen*,† J. Am. Chem. Soc., 2018, DOI: 10.1021/jacs.8b03785 https://pubs.acs.org/doi/10.1021/jacs.8b03785 Hydroboration of CO2 catalyzed by bis(phosphinite) pincer ligated nickel thiolate complexes Ting Liu, Wenjuan Meng, Qiang-Qiang Ma, Jie Zhang,* Huizhen Li, Shujun Li,Qianyi Zhao and Xuenian Chen* Dalton Transactions, 2017, 46(14) http://pubs.rsc.org/en/content/articlepdf/2017/dt/c7dt00490g Lanthanide derivatives of Ta/W mixed-addendum POMs as proton-conducting materials Qingpo Peng, Shujun Li, Ruoya Wang, Jianxin Zhai, Shuxia Liu, Jie Zhang, Qianyi Zhao and Xuenian Chen Dalton Trans., 2017, DOI: 10.1039/C7DT00091J http://pubs.rsc.org/en/content/articlepdf/2017/dt/c7dt00091j Highly efficient reduction of carbon dioxide with a borane catalyzed by bis(phosphinite) pincer ligated palladium thiolate complexes Qiang-Qiang Maa,Ting Liua,Shujun Lia,Jie Zhang*a,Xuenian Chen*a and Hairong Guan*b Chem. Commun., 2016, 52, 14262-14265 http://pubs.rsc.org/en/content/articlehtml/2016/CC/C6CC07987C#fn1 A Ta/W Mixed Addenda Heteropolyacid with Excellent Acid Catalytic Activity and Proton‐Conducting Property Shujun Li, Qingpo Peng, Xuenian Chen*, Ruoya Wang, Jianxin Zhai, Weihua Hu , Fengji Ma*, Jie Zhang*, Shuxia Liu Journal of Solid State Chemistry, 2016, 243(48):1-7 http://www.sciencedirect.com/science/article/pii/S0022459616303024 Catalyst design based on agostic interactions: synthesis, characterization, and catalytic activity of bis(pyrazolyl)borate copper complexes Hou-Ji Caoa, Qianyi Zhaoa, Qian-Fan Zhangb, Jiaxuan Lia, Ewan J. M. Hamiltonc, Jie Zhang*a, Lai-Sheng Wang*band Xuenian Chen*a Dalton Transactions, 2016, 45, 10194-10199 http://pubs.rsc.org/is/content/articlehtml/2016/dt/c6dt01272h Synthesis of Ammonia Borane Nanoparticles and the Diammoniate of Diborane by Direct Combination of Diborane and Ammonia Yuanzhou Song+,[a] Nana Ma+,[b] Xiaohua Ma,[a, c] Fang Fang,[a] Xuenian Chen,*[b] and Yanhui Guo*[a] Chem. Eur. J. 2016, 22, 6228–6233 http://onlinelibrary.wiley.com/doi/10.1002/chem.201600367/pdf A sandwich-type POM containing mixed cations: synthesis, thermal performance and proton-conducting properties Shujun Li, Fanyu Zhang, Qingpo Peng, Xuenian Chen*, Ruoya Wang, Zhifang Wang, Fengji Ma, Qianyi Zhao & Meilin Wei* Journal of Coordination Chemistry, 2016, 69, 425-432 http://url.cn/2HVZXV6 Metathesis reactivity of bis(phosphinite) pincer ligated nickel chloride, isothiocyanate and azide complexes Huizhen Li, Wenjuan Meng, Anubendu Adhikary, Shujun Li, Nana Ma, Qianyi Zhao, Qiuyu Yang, Nathan A. Eberhardt,Kendra M. Leahy, Jeanette A. Krause, Jie Zhang,* Xuenian Chen,* Hairong Guan* Journal of Organometallic Chemistry, 2016, 804, 132-141 http://www.sciencedirect.com/science/article/pii/S0022328X15302527 The continuing story of the diammoniate of diborane Qianyi Zhao, Jiaxuan Li, Ewan J.M. Hamilton, Xuenian Chen* Journal of Organometallic Chemistry, 2015, 798,24-29 http://www.sciencedirect.com/science/article/pii/S0022328X15003125 Formation Mechanisms, Structure, Solution Behavior, and Reactivity of Aminodiborane Huizhen Li, Nana Ma, Wenjuan Meng, Judith Gallucci, Yongqing Qiu, Shujun Li, Qianyi Zhao, Jie Zhang,* Ji-Cheng Zhao,* and Xuenian Chen* J. Am. Chem. Soc. 2015, 137, 12406-12414 http://pubs.acs.org/doi/abs/10.1021/jacs.5b08033 The Roles of Dihydrogen Bonds in Amine Borane Chemistry Xuenian Chen, Ji-Cheng Zhao, Sheldon G Shore Acc Chem Res, 2013, 46(11):2666-75 http://www.pubfacts.com/detail/24020948 Desolvation and Dehydrogenation of Solvated Magnesium Salts of Dodecahydrododecaborate: Relationship between Structure and Thermal Decomposition Xuenian Chen,* Yi-Hsin Liu, Anne-Marie Alexander, Judith C. Gallucci, Son- Jong Hwang, Hima Kumar Lingam, Zhenguo Huang, Cong Wang, Huizhen Li, Qianyi Zhao, Umit S. Ozkan,* Sheldon G. Shore,* Ji-Cheng Zhao* Chem. Eur. J. 2014, 20, 7325–7333 http://www.pubfacts.com/detail/24788403 Ammonia borane, past as prolog Huizhen Li, Qiuyu Yang, Xuenian Chen*, Sheldon G. Shore*. Journal of Organometallic Chemistry, 2014, 751, 60-66 http://www.sciencedirect.com/science/article/pii/S0022328X13006669

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