Rauchfuss, Thomas B. - University of Illinois at Urbana-Champaign

个人简介

Professor Thomas B. Rauchfuss received his undergraduate degree from the University of Puget Sound (1971) and his Ph.D. from Washington State University (1976). He has studied overseas at the following institutions: the Australian National University, University of Auckland, University of Strasbourg, and the Technical University of Karlsruhe.

研究领域

the synthesis and reactivity of inorganic, organometallic, and main-group compounds and materials.

近期论文

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“Combining Acid-Base, Redox, and Substrate Binding Functionalities to Give a Complete Model for the [FeFe]-Hydrogenase” Camara, J. M.; Rauchfuss, T. B. Nature-Chem. 2012, 4, 26–30. “Protonation-Enhanced Lewis Acidity of Iridium Complexes Containing Non-Innocent Amidophenolates” Ringenberg, M. R.; Rauchfuss, T. B. Eur. J. Inorg. Chem. 2012, 490-495. “Influence of Second Coordination Sphere Hydroxyl Groups on the Reactivity of Copper(I) Complexes” Letko, C. S.; Rauchfuss, T. B.; Gray, D. L.; Zhou, X. Inorg. Chem. 2012, 51, 4511–4520. "Mixed-Valence Nickel-Iron Dithiolates Models of the [NiFe]-Hydrogenase Active Site” Schilter, D.; Nilges, M. J.; Chakrabarti, M.; Lindahl, P. A.; Rauchfuss, T. B.; Stein, M. Inorg. Chem. 2012, 51, 2338−2348. "Unsensitized Photochemical Hydrogen Production Catalyzed by Diiron Hydrides" Wang, W.; Rauchfuss, T. B.; Bertini, L.; Zampella, G. J. Am Chem. Soc. 2012, 134, 4525-4528. "Reaction of Aryl Diazonium Salts and Diiron(I) Dithiolato Carbonyls: Evidence for Radical Intermediates" Olsen, M. T.; Rauchfuss, T. B.; Zaffaroni, R. Organometallics, 2012, 31, 3447−3450. "Connecting [NiFe]- and [FeFe]-Hydrogenases: Mixed-Valence Nickel-Iron Dithiolates with Rotated Structures" Schilter, D.; Rauchfuss, T. B.; Stein, M. Inorg. Chem. 2012, 51, 8931−8941. "EPR/ENDOR, Mössbauer, and Quantum Chemical Investigation of Di-iron Complexes Mimicking the Active Oxidized State of [FeFe] Hydrogenase" Silakov, A.; Olsen, M. T.; Sproules, S.; Reijerse, E.; Rauchfuss, T. B.; Lubitz, W. Inorg. Chem. 2012, 51, 8617−8628. "C2-Symmetric Iron(II) Diphosphine-Dialkoxide Dicarbonyl and Related Complexes" Lei, H.; Royer, A. M.; Rauchfuss, T. B.; Gray, D. L. Organometallics, 2012, 31, 6408–6414. "Nickel-Iron Dithiolates Related to Deactivated [NiFe]-Hydrogenases" Schilter, D.; Rauchfuss, T. B. Dalton Trans. 2012, 41, 13324-13329. "Synthetic Models for the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate" Carroll, M. E.; Barton, B. E.; Rauchfuss, T. B.; Carroll, P. J. J. Am Chem. Soc. 2012, 134,18843−18852. "Regiochemistry of Protonation of the [FeFe]-Hydrogenase Models of the Type Fe2(dithiolate)(CO)2(PMe3)4" Zaffaroni, R.; Rauchfuss, T. B.; Gray, D.; De Gioia, L.; Zampella, G. J. Am. Chem. Soc., 2012, 134, 19260−19269. "Active Site Fe-CN and Fe-CO Vibrations in [NiFe] Hydrogenase – Observation by Nuclear Resonance Vibrational Spectroscopy " Kamali, S.; Wang, H.; Mitra, D.; Ogata, H.; Lubitz, W.; Mack, A. E.; Rauchfuss, T. B.; Bonnefoy, V.; Jenney, Jr., F. E.; Yoda, Y.; Alp, E.; Zhao, J.; Cramer, S. P. Angew. Chem. Int. Ed. 2013, 52, 724-728. "Production of Hybrid Diesel Fuel Precursors from Carbohydrates and Petrochemicals Using Formic Acid as a Reactive Solvent" Zhou, X.; Rauchfuss, T. B. ChemSusChem 2013, 6, 383-388. "Ligand Effects on the Overpotential for Dioxygen Reduction by tris(2-Pyridylmethyl)amine Derivatives" Thorseth, M. A.; Letko, C. S.; Tse, E.; Rauchfuss, T. B.; Gewirth, A. A. Inorg. Chem. 2013, 52, 628-634 "Diphosphido- vs Dithiolato-Diiron(I) Carbonyls as Models for Active Site of the [FeFe]-Hydrogenase" Zaffaroni, R.; Rauchfuss, T. B.; De Gioia, L.; Zampella, G. Organometallics, 2013, 32, 232−238. "Isolation of a Mixed Valence Diiron Hydride: Evidence for a Spectator Hydride in Hydrogen Evolution Catalysis" Wang, W.; Nilges, M. J.; Rauchfuss, T. B.; Stein, M. J. Am. Chem. Soc., 2013, 135, 3633–3639.