研究领域
Electrochemical synthesis of inorganic bulk and nanoscale materials/low-temperature solid-state chemistry/nanomaterials.
The Prieto Group is developing synthetic methods for nanostructured materials with applications in renewable energy. In particular, her group is working on:
1) Using electrodeposition as a synthetic tool for making a 3D, high power density rechargeable battery,
2) developing the solution phase synthesis of nanoparticles of earth abundant, non toxic materials for photovoltaic inks and of light metal hydrides for hydrogen storage, and
3) using chemical vapor deposition reactions to develop hyperbranched nanowire structures for applications in photonics and batteries
近期论文
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F. J. Espinosa-Faller, D. R. Conradson, S. C. Riha, M. B. Martucci, S. J. Fredrick, S. Vogel, A. L. Prieto, and S. D. Conradson, "Neutron Diffraction and X-ray Absorption Fine Structure Evidence for Local Lattice Distortions and Aperiodic Antisite Substitution in Cu2ZnSnS4 Nanoparticles" J. Phys. Chem. C, 2014, 118(45) 26292-26303. [DOI]
D. J. Bates, C. Michael Elliott, and A. L. Prieto, "Synthesis and Characterization of Diazonium Salts with PEG Appendages and Resulting Films Afforded by Electrodeposition for use as a Battery Separator Material"Chem. Mater., 2014, 26(19) 5514-5522. [DOI]
G. A. Kahrilas, W. Haggren, R. L. Read, L. M. Wally, S. J. Fredrick, M. Hiskey, A. L. Prieto, J. E. Owens, "Investigation of Antibacterial Activity by Silver Nanoparticles Prepared by Microwave-Assisted Green Syntheses with Soluble Starch, Dextrose, and Arabinose"ACS Sustainable Chem. Eng., 2014, 2(4) 590-598. [DOI]
G. A. Kahrilas, L. M. Wally, S. J. Fredrick, M. Hiskey, A. L. Prieto, J. E. Owens, "Microwave-Assisted Green Synthesis of Silver Nanoparticles Using Orange Peel Extract"ACS Sustainable Chem. Eng., 2013, 2(3) 367-376. [DOI]
S. J. Fredrick, A. L. Prieto, "Solution Synthesis and Reactivity of Colloidal Fe2GeS4: A Potential Candidate for Earth Abundant, Nanostructured Photovoltaics"J. Am. Chem. Soc., 2013, 135 18256-18259. [DOI]
M. A. Purvis, V. N. Shlyaptsev, R. Hollinger, C. Bargsten, A. Pukhov, A. Prieto, Y. Wang, B. M. Luther, L. Yin, S. Wang, J. J. Rocca "Relativistic plasma nanophotonics for ultrahigh energy density physics"Nature Photonics, 2013, 7 796-800. [DOI]
D. J. Shissler, S. J. Fredrick, M. B. Braun, A. L. Prieto, "Magnesium and Doped Magnesium Nanostructured Materials for Hydrogen Storage", invited book chapter in ‘Low-cost Nanomaterials: Toward Greener and More Efficient Energy Applications’ Springer, Editors: Zhiqun Lin and Jun Wang, in press 2013.
A. L. Prieto, J. M. Mosby, D. C. Johnson, M. T. Rawls, Lithium-ion battery having interpenetrating electrodes U.S. Patent Application # 49386: February, 2012.
S.C. Riha, B.A. Parkinson, A.L. Prieto, "Compositionally Tunable Cu2ZnSn(S1-xSex)4 Nanocrystals: Probing the Effect of Se-Inclusion in Mixed Chalcogenide Thin Films," J. Am. Chem. Soc., 2011, 133, 15272-15275. [DOI]
N. S. Norberg, T. S. Arthur, S. J. Fredrick, A. L. Prieto, "Size-dependent Hydrogen Storage Properties of Mg Nanocrystals Prepared From Solution," J. Am. Chem. Soc., 2011, 133, 10679-10681. [DOI]
D. C. Johnson, A. L. Prieto, "Use of strontium titanate (SrTiO3) as an anode material for lithium-ion batteries," J. Power Sources, 2011, 196, 7736-7741. [DOI]
S. C. Riha, S. J. Fredrick, J. B. Sambur, Y. Liu, A. L. Prieto, B. A. Parkinson, "Photoelectrochemical Characterization of Nanocrystalline Thin-Film Cu2ZnSnS4 Photocathodes," ACS Applied Materials & Interfaces, 2011, 3(1), 58-66. [DOI]
S. Kohli, P. R. McCurdy, D. C. Johnson, J. Das, A. L. Prieto, C. D. Rithner, E. R. Fisher, "Template-Assisted Chemical Vapor Deposited Spinel Ferrite Nanotubes". Journal of Physical Chemistry C, 2010, 114, 19557-19561. [DOI]
S. C. Riha, D. C. Johnson, A. L. Prieto, "Cu2Se Nanoparticles with Tunable Electronic Properties Due to a Controlled Solid-State Phase Transition Driven by Copper Oxidation and Cationic Conduction," J. Am. Chem. Soc., 2011, 133(5), 1383-1390J. Am. Chem. Soc., 2011, 133(5), 1383-1390. [DOI]
D. C. Johnson, J. M. Mosby, A. L. Prieto, Isoelectric Determination Apparatus and Use in the Fabrication of Batteries. U.S. Patent Application # 61318068: March, 2010.
T. Arthur, M. T. Rawls, J. M. Mosby, D. C. Johnson, A. L. Prieto, SEI Layer Formation and Use Within Lithium Ion Batteries. U.S. Patent Application # 61318163: March, 2010.
J. Mosby, D. C. Johnson, A. L. Prieto, "Evidence of Induced Underpotential Deposition of Crystalline Copper Antimonide via Instantaneous Nucleation," J. Electrochem. Soc., 2010, 157, E99-E105. [DOI]
D. C. Johnson, W. D. Morris*, A. L. Prieto, "Effects of transport gradients in a chemical vapor deposition reactor employing vapor-liquid-solid growth of ternary chalcogenide phase-change materials," Nanotechnology , 2010, 21, 165604-165613.[DOI]
D. C. Johnson, J. M. Mosby, S. C. Riha, A. L. Prieto, "Synthesis of Copper Silicide Nanocrystallites Embedded in Silicon Nanowires for Enhanced Transport Properties", J. Mater. Chem. , 2010, 20, 1993-1998.[DOI]
S. C. Riha, B. A. Parkinson, A. L. Prieto, "Solution-Based Synthesis and Characterization of Cu2ZnSnS4 Nanocrystals," J. Am. Chem. Soc., 2009, 131(34), 12054-12055.[DOI]