陈金喜 - 东南大学 - 化学化工学院

研究领域

多孔道材料的设计合成、低热固相合成化学、微波合成化学 1、手性孔道和螺旋结构的构筑研究。我们将在已知的具有手性特征结构研究的基础上，研究生成手性和螺旋结构骨架结构的构筑。i）骨架组成与骨架拓扑结构关系的研究。ii）具有手性孔道结构的结构构筑规律的研究，尤其是骨架中存在的特定结构构筑基元及其连接方式的研究。iii）手性结构导向剂与手性孔道结构关系的研究。合成手性微孔配位聚合物，制作手性敏感探针或敏感器。 2、微介孔双功能催化材料的合成研究。在尝试合成微孔配位聚合物晶体的过程中，同时引入介孔模板，这样，所合成的样品不仅具有微孔晶体的均匀微孔，而且还可以同时有均匀一定的介孔结构，我们期望这些样品可以在某些催化反应中显示出优异的催化性能。开发出具有选择性催化性能的配位聚合物。 3、纳米材料的功能化研究。开发出在药物输送、医学造影方面具有应用前景的微孔配位聚合物纳米晶。 4、传质的捕获和转移研究。单质、分子和粒子等在多孔材料孔内的吸附和扩散。能量的储存与转移：氢气、甲烷、甲醇、乙炔和苯等与多孔材料孔壁吸附中的电子效应、电荷效应、极化效应、空间效应和化学作用。无能源气体分离、醇水分离和有机物分离：多孔材料有序和定向膜的合成和气体分子、水、有机分子在孔道内的吸附和扩散中的尺寸效应、极化效应和动力学效应等。

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Lirong Wu, Xiangli Guo, Zhongjie Wang, and Jinxi Chen,* ‘Syntheses, Crystal Structure, and Fluorescent Property of a New (4,10)-Connected 3D Cd(II) Coordination Polymer’, Chem. Lett. 2015, 44, 451–453. Yongbing Lou,* Jing Liang, Yinglian Peng and Jinxi Chen,* ‘Ultra-small Co3O4 nanoparticles–reduced graphene oxide nanocomposite as superior anodes for lithium-ion batteries’, Phys. Chem. Chem. Phys., 2015,17, 8885-8893. Hongjie He, Lina Zhang, Mingli Deng, Zhenxia Chen, Yun Ling, Jinxi Chen* and Yaming Zhou,* ‘Acid-induced Zn(II)-based metal-organic framework for encapsulation and sensitization of lanthanide cations’, CrystEngComm, 2015, 17, 2294-2300. Zhong-Jie Wang, Ling Qin, Xin Zhang, Jin-Xi Chen,* and He-Gen Zheng,* ‘Syntheses, Characterizations, Luminescent Properties, and Controlling Interpenetration of Five Metal–Organic Frameworks Based on Bis(4-(pyridine-4-yl)phenyl)amine’, Crystal Growth & Design, 2015, 15, 1303-1310. Xiaojuan Wu, Mingliang Wang,*Man Du, Jiao Lu, Jinxi Chen, Arshad Khan, Rabia Usman, Xiang Wei, Qi Feng, and Chunxiang Xu,* ‘Reversible Accommodation and Desorption of Aromatics on a Charge Transfer Cocrystal Involving an Anthracene Derivative and TCNQ’, Crystal Growth & Design, 2015, 15 (1), 434–441. Tiantian Xing, Yongbing Lou,* Qilong Bao and Jinxi Chen,* ‘Surfactant-Assisted Synthesis of ZIF-8 Nanocrystals in Aqueous Solution via Microwave Irradiation’, CrystEngComm, 2014, 16, 8994-9000. Lina Zhang, Jinxi Chen,* Yun Ling and Zhenxia Chen,* ‘Syntheses, Crystal Structures, and Reversible Structural Transformation of Two Zinc Coordination Polymers’, Chem. Lett., 2014, 43(7), 997-998. Ling Qin, Zhong-Jie Wang, Ting Wang, He-Gen Zheng* and Jin-Xi Chen,* ‘Coligand-directed synthesis of five Co(II)/Ni(II) coordination polymers with a neutral tetradentate ligand: syntheses, crystal structures, and properties’, Dalton Trans., 2014, 43, 12528-12535. Yongbing Lou,* Yixin Zhao, Jinxi Chen and Jun-Jie Zhu,* 'Metal ions optical sensing by semiconductor quantum dots,' J. Mater. Chem. C, 2014, 2(4), 595-613. (Front Cover Article) Yinhua Tao, Yongbing Lou, * Yang Li and Jinxi Chen, * ‘Structural Diversity of Five New Lanthanide Coordination Polymers Tuned by Different Salt Anions’, Bull. Korean Chem. Soc., 2014, 35(5), 1417-1421. Ling Qin, Ze-Min Ju, Zhong-Jie Wang, Fan-Dian Meng, He-Gen Zheng* and Jin-Xi Chen,* ‘Interpenetrated Metal-Organic Framework with Selective Gas Adsorption and Luminescent Properties’, Crystal Growth & Design, 2014, 14(6), 2742-2746. Yongbing Lou,*Jinxi Chen,* ‘Recent Development in One Dimensional (1D) Nanostructured TiO2 for Photoelectrochemical Water Splitting’, Nanosci. Nanotechnol. Lett. 2014, 6(5), 361-371. Yongbing Lou, Jingjing Wang, Yinhua Tao, Jinxi Chen,* Akio Mishima and Masaaki Ohba,* 'Structure modulation of manganese coordination polymers consisting of 1,4-naphthalene dicarboxylate and 1,10-phenanthroline,' Dalton Trans., 2014, 43, 8508-8514. Yongbing Lou, Yinhua Tao, Jingjing Wang, Jinxi Chen* and Masaaki Ohba,* 'A new manganese coordination polymer involving in situ generated formate,' Polyhedron, 2014, 73, 72-76. Yongbing Lou, Jinxi Chen,* Jing Jiang and Qilong Bao, 'Rapid synthesis of iron 1,4-naphthalenedicarboxylate by microwave irradiation with enhanced gas sorption,' Dalton Trans., 2014, 43, 1261-1266. Wang Jing-Jing, Qi-Long Bao and Jin-Xi Chen,* ‘Two 2-D layered coordination polymers based on 5-aminoisophthalate and 1,10-phenanthroline’, J. Coord. Chem., 2013, 66(14), 2578-2586. Qilong Bao, Yongbing Lou,* Tiantian Xing and Jinxi Chen,* 'Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) in aqueous solution via microwave irradiation,' Inorg. Chem. Commun., 2013, 37, 170-173. Jinxi Chen,* Qiaoyu Fan and Susumu Kitagawa, ‘Synthesis, structures and adsorption properties of two new magnesium coordination polymers’, Solid State Sciences, 2013, 16, 29-33. Jinxi Chen,* Jingjing Wang and Masaaki Ohba, ‘Two coordination polymers of manganese (II) isophthalate and their preparation, structures, and magnetic properties’, J. Solid State Chem., 2012, 185, 37-41. Jinxi Chen* and Baohua Liu, ‘Construction of cobalt-imidazole-based dicarboxylate complexes with topological diversity: From metal-organic square to one-dimensional coordination polymer’, Inorg. Chem. Commun., 2012, 22, 170-173. Jinxi Chen* andRuobing Zhang, ‘Synthesis of Zinc Isonicotinates by Solid-state Reactions: A Green Route to Coordination Polymers’, Chem. Lett., 2011, 40, 56-57. Jinxi Chen* andSusumu Kitagawa, ‘Guest-induced Single-crystal-to-single-crystal Transformation in Copper Complexes of 1,3,5-Benzenetricarboxylic Acid and 4,4 '-Bipyridine’, Chem. Lett., 2010, 39, 1186-1187. Comotti, S. Bracco, P. Sozzani, S. Horike, R. Matsuda, J. Chen, M. Takata, Y. Kubota and S. Kitagawa, ‘Nanochannels of Two Distinct Cross-Sections in a Porous Al-Based Coordination Polymer’, J. Am. Chem. Soc., 2008, 130, 13664–13672. Jinxi Chen, Zhenxia Chen, Ting Yu, Linhong Weng, Bo Tu and Dongyuan Zha,* ‘Synthesis, structure, and adsorption properties of a new three-dimensional porous yttrium-organic coordination network’, Micropor. Mesopor. Mat., 2007, 98, 16-20. Jinxi Chen, Masaaki Ohba, Dongyuan Zhao, Wakako Kaneko and Susumu Kitagawa,* ‘Polynuclear core-based nickel 1,4-CDC coordination polymers as temperature-dependent hydrothermal reaction products: structures, magnetic and sorption properties’, Crystal Growth & Design, 2006, 6, 664-668. Jinyu Sun, Linhong Weng, Yaming Zhou, Jinxi Chen, Zhenxia Chen, Zhicheng Liu and Dongyuan Zhao,* ‘ QMOF-1 and QMOF-2: Three-Dimensional Metal-Organic Open Frameworks with a Quartzlike Topology’, Angew. Chem. Int. Ed., 2002, 41, 4471-4473. C. Zhang, G. C. Jin, J. X. Chen, X. Q. Xin and K. P. Qian, ‘The Characteristic IR Spectra of HeterothiometallicCluster Compounds’, Coord. Chem. Rev., 2001, 213, 51-77.