杨海涛 - 常州大学 - 石油化工学院食品学院

研究领域

主要从事富勒烯化学的研究，围绕“新方法、新结构、新反应”开展一些对富勒烯进行化学修饰，目前集中于研究Cu (n)试剂和I (n)试剂促进的富勒烯环加成反应化学反应。

近期论文

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Mao, P.-F.; Zhou, L.-J.; Zheng, A.-Q.; Miao, C.-B.; Yang, H.-T. Cu(OAc)2-Triggered Cascade Reaction of Malonate-Tethered Acyl Oximes with Indoles, Indole-2-alcohols, and Indole-2-carboxamides. Org. Lett. 2019, 21, 3153-3157. Miao, C.-B.; Zheng, A.-Q.; Zhou, L.-J; Lyu, X.; Yang, H.-T. Copper-Catalyzed Annulation of Oxime Acetates with α-Amino Acid Ester. Org. Lett. 2020, 22, 3381-3385. Wang, K.; Guan, H.-R.; Ren, W.-L.; Yang, H.-T.; Miao, C.-B. Copper-Catalyzed Cascade Annulation of Malo-nate-Tethered O-Acyl Oximes with Cyclic 1,3-Dicarbonyl Com-pounds for the Synthesis of Spiro-Pentacyclic Derivatives. J. Org. Chem. 2021, 86, 12309-12317. Miao, C.-B.; Guan, H.-R.; Tang, Y.; Wang, K.; Ren, W.-L.; Lyu, X.; Yao, C.; Yang, H.-T. Copper-Catalyzed Bisannulations of Malonate-Tethered O‑Acyl Oximes with Pyridine, Pyrazine, Pyridazine, and Quinoline Derivatives for the Construction of Dihydroindolizine-Fused Pyrrolidinones and Analogues. Org. Lett. 2021, 23, 8699-8704. “Cu(OAc)2-Mediated Reaction of C60 with Ureas for the Preparation of Fulleroimidazolidinones”, Hai-Tao Yang,* Yi-Chen Tan, Yang Yang, Xiao-Qiang Sun, Chun-Bao Miao,J. Org. Chem.2016, 81, 1157-1163. “Cu(OAc)2-promoted reaction of [60]fullerene with primary amines or diamines”，Xin-Wei Lu, Meng-Lei Xing, Chun-Bao Miao, Jia-Xing Li, Xiao-Qiang Sun* and Hai-Tao Yang*Org. Biomol. Chem., 2015, 13, 8405–8410. “Lewis Base-Catalyzed Reaction of Aziridinofullerene with Ureas for the Preparation of Fulleroimidazolidinones”, Meng-Lei Xing, Xin-Wei Lu, Chun-Bao Miao, Jia-Xing Li, Xiao-Qiang Sun, Hai-Tao Yang,*J. Org. Chem.2014, 79, 11774-11779. (二区TOP，IF = 4.638) “BF3·Et2O- or DMAP-Catalyzed Double Nucleophilic Substitution Reaction of Aziridinofullerenes with Sulfamides or Amidines”, Hai-Tao Yang,* Meng-Lei Xing, Xin-Wei Lu, Jia-Xing Li, Jiang Cheng, Xiao-Qiang Sun, Chun-Bao Miao,J. Org. Chem.2014, 79, 11744-11749. (二区TOP，IF = 4.638) “BF3?Et2O-Catalyzed Formal [3+2] Reaction of Aziridinofullerenes with Carbonyl Compounds”, Hai-Tao Yang,* Meng-Lei Xing, Ye-Fei Zhu, Xiao-Qiang Sun, Jiang Cheng, Chun-Bao Miao, Fa-Bao Li,*J. Org. Chem.2014, 79, 1487-1492. (二区TOP，IF = 4.638) “Hypervalent Iodine Reagent Mediated Diamination of [60]Fullerene with Sulfamides or Phosphoryl Diamides”, Hai-Tao Yang,* Xin-Wei Lu, Meng-Lei Xing, Xiao-Qiang Sun, Chun-Bao Miao,*Org. Lett. 2014, 16, 5882-5885. (二区TOP，IF = 6.324) “Hypervalent Iodine Reagent-Mediated Reaction of [60]Fullerene with Amines”, Chun-Bao Miao,* Xin-Wei Lu, Ping Wu, Jiaxing Li, Wen-Long Ren, Meng-Lei xing, Xiao-Qiang Sun, Hai-Tao Yang,*J. Org. Chem.2013, 78, 12257-12262. “CuCl2-Mediated the Reaction of [60]Fullerene with Amines in the Presence or Absence of Dimethyl Acetylenedicarboxylate: Preparation of Fulleropyrroline or Aziridinofullerene Derivatives”, Hai-Tao Yang,* Xi-Chen Liang, Yan-Hong Wang, Yang Yang, Xiao-Qiang Sun,* Chun-Bao Miao,J. Org. Chem.2013, 78, 11992-11998. “PhI(OAc)2/I2-mediated [3+2] reaction of [60]fullerene with amides for the preparation of fullerooxazoles”, Hai-Tao Yang,* Wen-Long Ren, Chun-Ping Dong, Yang Yang, Xiao-Qiang Sun, Chun-Bao Miao,*Tetrahedron Lett.2013, 54, 6799-6803. “CuI-Catalyzed Oxidative [3+2] Reaction of Fullerene with Amidines or Amides Using Air as the Oxidant: Preparation of Fulleroimidazole or Fullerooxazole Derivatives”, Hai-Tao Yang,* Xi-Chen Liang, Yan-Hong Wang, Yang Yang, Xiao-Qiang Sun,* Chun-Bao Miao,Org. Lett.2013, 15, 4650-4653. “DMAP-Catalyzed [3+2] and [4+2] Cycloaddition Reactions between [60]fullerene and Unmodified Morita–Baylis–Hillman Adducts in the Presence of Ac2O”, Hai-Tao Yang,* Wen-Long Ren, Chun-Bao Miao, Chun-Ping Dong, Yang Yang, Hai-Tao Xi, Qi Meng, Yan Jiang, Xiao-Qiang Sun,*J. Org. Chem.2013, 78, 1163-1170. “Reaction of [60]fullerene with α-alkoxyl/acyloxyl/phenolyl ketoxime: unusual C-C and C-O bond cleavage” Hai-Tao Yang,* Wen-Long Ren, Xiao-Jiao Ruan, Zong-Yong Tian, Xi-Chen Liang, Chen Han, Xiao-Qiang Sun,* Chun-Bao Miao,Tetrahedron Lett.2013, 54, 1428-1431. “CuBr/PMDETA-Mediated Reactions of [60]Fullerene with Active Halides: Preparation of Methano[60]fullerene Derivatives”, Hai-Tao Yang,* Zong-Yong Tian, Xiao-Jiao Ruan, Min Zhang, Chun-Bao Miao, Xiao-Qiang Sun,*Eur. J. Org. Chem.2012, 4918-4922.