个人简介
B.S. University of California, Santa Barbara 2006
Ph.D University of California, Santa Barbara 2010
研究领域
Inorganic Chemistry
New and higher-performing materials play a key role in enabling new technology. Central to achieving this goal is a detailed understanding of the impact that structure and composition have on physical properties. To that end, the research conducted in our group broadly focuses on understanding the interplay between spin, charge, and lattice degrees of freedom in the solid state so as to better design new and improve existing functional materials. A few examples of which are outlined below.
We use a large variety of synthetic methods to prepare new materials; including high-temperature ceramic as well as hydrothermal routes. We place equal emphasis on the preparation of materials and their complete physical characterization which includes an accurate determination of: the underlying crystal structure, magnetism, electrical transport, dielectric properties, and electrochemical performance. We also make extensive use of a variety of density functional theory (DFT) computational tools in order to understand the nature of chemical bonding in these materials.
近期论文
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M. Reynaud, P. Barpanda, G. Rousse, J-N. Chotard, B. C. Melot, N. Recham, and J-M. Tarascon Synthesis and crystal chemistry of the NaMSO4F family (M = Mg, Fe, Co, Cu, Zn) Solid State Sci. 14 (2012) 15-20
M. Ati, B. C. Melot, G. Rousse, J-N. Chotard, P. Barpanda, and J-M. Tarascon Structural and Electrochemical Diversity in the LiFe1-xZnxSO4F solid solution: another 3.9V positive electrode based on Fe Angew. Chem. Int. Ed. 50 (2011) 10574-10577
M. Ati, B. C. Melot, G. Rousse, J-N. Chotard, and J-M. Tarascon Synthesis and Electrochemical Properties of pure LiFeSO4F in the triplite structure Electrochem. Comm. 13 (2011) 1280-1283
P. Barpanda, M. Ati, B. C. Melot, G. Rousse, J-N. Chotard, M-L. Doublet, M. T. Sougrati, S. A. Corr, J-C. Jumas, and J-M. Tarascon A 3.9 V Fe-based fluorosulphate material for Li-ion batteries crystallizing in the triplite structure Nat. Mater. 10 (2011) 772-779
B. C. Melot, J.-N. Chotard, G. Rousse, M. Ati, M. Reynaud,and J-M. Tarascon, Synthesis, structure and magnetic properties of the NaCoXO4·2H2O phases where X = S and Se Inorg. Chem. 50 (2011) 7662-7668
B. C. Melot, G. Rousse, J.-N. Chotard, M. Ati, J. Rodríguez-Carvajal, M. C. Kemei, and J.-M. Tarascon Magnetic structure and properties of the Li-ion battery materials FeSO4F and LiFeSO4F Chem. Mater. 23 (2011) 2922-2930
R. Tackett, G. Lawes, B. C. Melot, M. Grossman, E. S. Toberer, and R. Seshadri, Magnetodielectric coupling in Mn3O4, Phys. Rev. B 76 (2007) 024409(1-6)
G. Lawes, B. Melot, K. Page, C. Ederer, M. A. Hayward, Th. Proffen, and R. Seshadri, Dielectric anomalies and spiral magnetic order in CoCr2O4, Phys. Rev. B 74 (2006) 024413(1-6)