研究领域
药物及其中间体的合成，化工新材料与助剂研究，绿色化学与技术研究
近期论文
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1) Wubin Yu, Peizhu Hu, Yuanyuan Fan, Congyao Yu, Xinhuan Yan, Xiaoqing Li*, Xiangsheng Xu*. Metal-free TBAI-catalyzed arylsulfonylation of activated alkenes with sulfonylhydrazides [J].Org. Biomol. Chem., 2015, 13, 3308.
2) Xiangsheng Xu, Yucai Tang, Xiaoqing Li, Guo Hong, Mingwu Fang and Xiaohua Du*. Iron-catalyzed arylalkoxycarbonylation of N-Aryl acrylamides with carbazates[J]. J. Org. Chem., 2014, 79, 446.
3)Xiaoqing Li*, Mingwu Fang, Peizhu Hu, Guo Hong, Yucai Tangand XiangshengXu*. Tetrabutylammonium iodide catalyzed radical alkoxy- carbonylation of 2-isocyanobiphenyls with carbazates: synthesis of phenanthridine-6-carboxylates[J]. Adv. Synth. Catal.,2014, 356, 2103.
4) Xiangsheng Xu*, Peizhu Hu, Wubin Yu, Guo Hong, Yucai Tang, Mingwu Fang, Xiaoqing Li*. Bu4NI-catalyzed synthesis of imidazo[1,2-a]pyridines via oxidative coupling of aminopyridines with nitroolefins[J]. Synlett., 2014, 25, 718.
5) Jiangbin Shao, Peizhu Hu, Guo Hong, Mingwu Fang, Xiaoqing Li, Xiangsheng Xu*.Palladium-catalyzed synthesis of indene derivatives via intramolecular allylic arylation of Baylis– Hillman acetates[J]. Synlett, 2014, 25, 1009.
6) Xiangsheng Xu*, Yanfeng Lu, Guo Hong, Zhiteng Zhao and Xiaoqing Li. Synthesis of dihydrobenzofurans and dihydroindoles by intramolecular Friedel- Crafts cyclizations of aryloxy and arylaminosubstituted propargylic alcohols[J]. Arkivoc, 2014, v, 237.
7) Xiaoqing Li*, Xinhua Shi, Mingwu Fang and Xiangsheng Xu*. Iron halide-mediated region and stereoselective halosulfonylation of terminal alkynes with sulfonylhydrazides: synthesis of (E)-β-chloro and bromo vinylsulfones[J]. J. Org. Chem., 2013, 78, 9499.
8) Xiaoqing Li*, Xiangsheng Xu*, Peizhu Hu, Xuqiong Xiao and Can Zhou. Synthesis of sulfonated oxindoles by potassium iodide catalyzed arylsulfonylation of activated alkenes with sulfonylhydrazides in water[J]. J. Org. Chem., 2013, 78, 7343.
9) Xiaoqing Li*, Xiangsheng Xu* and Yucai Tang. Tetrabutylammonium iodide catalyzed allylic sulfonylation of Baylis–Hillman acetates with sulfonylhydrazides in water[J]. Org. Biomol. Chem., 2013, 11, 1739.
10) Xiaoqing Li, Xiangsheng Xu* and Xinhua Shi. I2/TBHP-mediated reaction of sulfonylhydrazides with alkynes: synthesis of (E)-β-iodovinyl sulfones[J]. Tetrahedron Lett., 2013, 54, 3071.
11) Xiangsheng Xu*, Tao Li, Xiaoqing Li*, Jiangbin Shao. Synthesis of substituted fluorenes by cascade allenylation/electrocyclization/intramolecular Friedel-Crafts reaction of 1,3-diene-substituted propargylic alcohols[J]. Synlett, 2013, 24, 383.
12)许响生，陈傲昂，周莉，李小青，顾辉子，严新焕*. Ru-Fe/C催化剂上邻氯硝基苯原位液相加氢性能[J]. 催化学报，2013, 2, 391.
13) Xiangsheng Xu*, Zhenyong Huang, Yanfeng Lu. Cu(OAc)2·H2O-promoted tandem β-alkynyl elimination of α- or β-hydroxy propargylic alcohols and homocoupling of the resulting alkynyl species[J]. J. Chem. Res., 2013, 546.
14) Xiangsheng Xu, Xiaoqing Li, Huizi Gu, Zhongbin Huang and Xinhuan Yan*. A highly active and chemoselective assembled Pt/C(Fe) catalyst for hydrogenation of o-chloronitrobenzene[J]. Applied Catalysis A: General, 2012, 429, 17- 23.
15) Xiaoqing Li*, Xiangsheng Xu and Can Zhou. Tetrabutylammonium iodide catalyzed allylic sulfonylation of α-methyl styrene derivatives with sulfonylhydrazides[J]. Chem. Commun., 2012, 48, 12240.
16) Xiaoqing Li*, Can Zhou, Xiangsheng Xu*. TBAI-catalyzed oxidative coupling of β-ketoesters with carboxylic acid: synthesis of α-carboxylic-β-ketoesters[J]. ARKIVOC, 2012, ix, 150.
17) Xiangsheng Xu*, Xiaoqing Li, Xinhuan Yan, Hanshen Wang, Yun Deng, Jiangbin Shao. Regiospecific synthesis of 3,4-dihydrocoumarins via substrate controlled [1,3]-or [3,3]-sigma tropic rearrangement[J]. Synlett, 2011, 20, 3026.
18) Xiangsheng Xu*, Yun Deng, Xiaoqing Li, Zhiteng Zhao, Wenying Fang and Xinhuan Yan. Iodine(Ⅲ)-mediated one-pot synthesis of quinoxaline by tandem nucleophilic substitution and cyclisation[J]. J. Chem. Res., 2011, 605.
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