杜云飞 - 天津大学 - 药物科学与技术学院

个人简介

Education Experience： 2007 Ph. D. Tianjin University, CN Professional Experience： 2007-2009 Assistant Professor Tianjin University 2009-2013 Associate Professor Tianjin University 2012-2019 Associate Dean / Party Vice-Secretary Tianjin University 2013-2019 Professor Tianjin University 2019- Associate Dean Tianjin University Honors and Awards：四乙酰核糖和二乙酰阿昔洛韦合成的新工艺，天津市人民政府，科技进步奖，二等奖，2010。（赵康、陈维瑜、魏静、杜云飞、王松青、苏艳芳、张秀东、陈炎泉）第十二届“挑战杯”天津市大学生课外学术科技作品竞赛优秀指导教师，天津市委员会、天津市科学技术委员会、天津市教育工作委员会等，优秀指导教师，2013。（杜云飞）天津大学“北洋青年学者”，2015年。天津市“131”创新型人才培养工程第一层次人选，2016年。

研究领域

The research area of the Du group involves investigation of hypervalent iodine (III) – mediated transformations, including oxidative coupling, rearrangement, cascade reactions, and asymmetric reactions. Additionally, the group develops metal-free methodology for the constructionof heterocyclic compounds and pharmaceutical agents.

近期论文

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Accessing aryl azides via copper powder-catalyzed cross-coupling of arylboronic acids with the hypervalent azido-iodine reagent ABZ(I) Organic Chemistry Frontiers 2023 | Journal article DOI: 10.1039/D3QO00732D CONTRIBUTORS: Zhifang Yang; Feng-Huan Du; Chi Zhang; Yunfei Du The application of NH4SCN as a nontoxic cyanide source for the divergent Strecker synthesis of aminonitriles and iminonitriles Organic Chemistry Frontiers 2023 | Journal article DOI: 10.1039/D2QO01692C CONTRIBUTORS: Xiaofan Wang; Bingyue Zhao; Lingzhi Xu; Xuemin Li; Haofeng Shi; Yunfei Du Synthesis of Trifluoromethylthiolated Quinolinones via Trifluoromethanesulfanamide‐Induced Electrophilic Intramolecular Cyclization of N‐Arylpropynamides Advanced Synthesis & Catalysis 2023-11-21 | Journal article DOI: 10.1002/adsc.202300719 CONTRIBUTORS: Lingzhi Xu; Fengxia Sun; Hui Zhao; Haofeng Shi; Yihang Wu; Xiaoxian Li; Yunfei Du Preparation, Structural Identification and Reactivities of Two Benziodazole‐type I(III) Reagents Advanced Synthesis & Catalysis 2023-08-15 | Journal article DOI: 10.1002/adsc.202300304 CONTRIBUTORS: Zhifang Yang; Fengxia Sun; Jun Xu; Yadong Li; Kaiyue Yang; Yunfei Du Synthesis of 2-Fluoroalkylated Oxazoles from β-Monosubstituted Enamines via Fluoroacyloxylation and Cyclization Mediated by Fluoroalkyl-Containing Hypervalent Iodine(III) Species Generated In Situ The Journal of Organic Chemistry 2023-08-04 | Journal article DOI: 10.1021/acs.joc.3c01032 CONTRIBUTORS: Zhifang Yang; Fengxia Sun; Yadong Li; Kaiyue Yang; Jianing Zhang; Lingzhi Xu; Hui Zhao; Yunfei Du Chemoselective cycloisomerization of O-alkenylbenzamides via concomitant 1,2-aryl migration/elimination mediated by hypervalent iodine reagents Communications Chemistry 2023-06-17 | Journal article DOI: 10.1038/s42004-023-00930-5 CONTRIBUTORS: Jiaxin He; Feng-Huan Du; Chi Zhang; Yunfei Du Intramolecular Heterocyclization/Fluoromethylthiolation of Alkynes Enabled by a Multicomponent Reagent System Organic Letters 2023-05-19 | Journal article DOI: 10.1021/acs.orglett.3c01095 CONTRIBUTORS: Xuemin Li; Fengxia Sun; Haofeng Shi; Beibei Zhang; Jiaxin He; Jialiang Wu; Yunfei Du Synthesis of 3-Haloindoles via Cascade Oxidative Cyclization/Halogenation of 2-Alkenylanilines Mediated by PIDA and LiBr/KI The Journal of Organic Chemistry 2023-02-03 | Journal article DOI: 10.1021/acs.joc.2c02480 CONTRIBUTORS: Bingyue Zhao; Xiaoxian Li; Xiaofan Wang; Luchen Jiang; Zhe Li; Yunfei Du Application of DMSO as a methylthiolating reagent in organic synthesis Organic & Biomolecular Chemistry 2022 | Journal article DOI: 10.1039/D2OB00570K CONTRIBUTORS: Xuemin Li; Xi Wang; Yadong Li; Jiaxi Xiao; Yunfei Du Aryl iodine-catalysed divergent synthesis of isobenzofuranones and isocoumarins via oxidative 1,2-aryl migration/elimination Chemical Communications 2022 | Journal article DOI: 10.1039/D2CC03101A CONTRIBUTORS: Jiaxin He; Jingran Zhang; Xuemin Li; Haofeng Shi; Yunfei Du Divergent synthesis of 2-methylthioindole and 2-unsubstituted indole derivatives mediated by SOCl2 and dimethyl/diethyl sulfoxides Organic & Biomolecular Chemistry 2022 | Journal article DOI: 10.1039/D2OB01580C CONTRIBUTORS: Jingran Zhang; Beibei Zhang; Jiaxin He; Haofeng Shi; Yunfei Du Pyrazole-containing pharmaceuticals: target, pharmacological activity, and their SAR studies RSC Medicinal Chemistry 2022 | Journal article DOI: 10.1039/D2MD00206J CONTRIBUTORS: Guangchen Li; Yifu Cheng; Chi Han; Chun Song; Niu Huang; Yunfei Du Electrophilic Oxythio/selenocyanation of o‐Alkenyl Benzoic Acids: Divergent Synthesis of Thio/selenocyanated Isobenzofuranones and Isocoumarins Asian Journal of Organic Chemistry 2022-12 | Journal article DOI: 10.1002/ajoc.202200595 CONTRIBUTORS: Shanqing Tao; Luchen Jiang; Yunfei Du Synthesis of 3-SCF2H-/3-SCF3-chromones via Interrupted Pummerer Reaction/Intramolecular Cyclization Mediated by Difluoromethyl or Trifluoromethyl Sulfoxide and Tf2O Organic Letters 2022-10-07 | Journal article DOI: 10.1021/acs.orglett.2c03017 CONTRIBUTORS: Xuemin Li; Yue Li; Jingyue Yang; Haofeng Shi; Zhenkang Ai; Chi Han; Jiaxin He; Yunfei Du Construction of the 2-Amino-1,3-selenazole Skeleton via PhICl2/KSeCN-Mediated Selenocyanation/Cyclization Organic Letters 2022-06-17 | Journal article DOI: 10.1021/acs.orglett.2c01468 CONTRIBUTORS: Shanqing Tao; Lingzhi Xu; Kaiyue Yang; Jianing Zhang; Yunfei Du Synthesis of 3-thiocyanated chromones via TCCA/NH4SCN-mediated cyclization/thiocyanation of alkynyl aryl ketones Green Synthesis and Catalysis 2022-05 | Journal article DOI: 10.1016/j.gresc.2021.12.003 CONTRIBUTORS: Jiaxi Xiao; Zhenkang Ai; Xuemin Li; Sanqing Tao; Bingyue Zhao; Xiaofan Wang; Xinbo Wang; Yunfei Du Synthesis of 3‐Halogenated Quinolin‐2‐Ones from N‐Arylpropynamides via Hypervalent Iodine(III)−Mediated Umpolung Process Advanced Synthesis & Catalysis 2022-04-12 | Journal article DOI: 10.1002/adsc.202200131 CONTRIBUTORS: Xiaoxian Li; Beibei Zhang; Bingyue Zhao; Xiaofan Wang; Lingzhi Xu; Yunfei Du Trifluoromethylthiolation/Selenolation and Lactonization of 2-Alkynylbenzoate: The Application of Benzyl Trifluoromethyl Sulfoxide/Selenium Sulfoxides as SCF3/SeCF3 Reagents Organic Letters 2022-03-25 | Journal article DOI: 10.1021/acs.orglett.2c00563 CONTRIBUTORS: Haofeng Shi; Xingzong Wang; Xiaoxian Li; Beibei Zhang; Xuemin Li; Jingran Zhang; Jingyue Yang; Yunfei Du Chemoselective Synthesis of Sulfenylated Spiroindolenines from Indolyl-ynones via Organosulfenyl Chloride-Mediated Dearomatizing Spirocyclization Organic Letters 2022-01-14 | Journal article DOI: 10.1021/acs.orglett.1c04063 CONTRIBUTORS: Beibei Zhang; Xiaoxian Li; Zhenkang Ai; Bingyue Zhao; Zhenyang Yu; Yunfei Du DMSO/SOCl2-mediated C(sp2)–H amination: switchable synthesis of 3-unsubstituted indole and 3-methylthioindole derivatives Chemical Communications 2021 | Journal article DOI: 10.1039/D0CC07453E CONTRIBUTORS: Jingran Zhang; Xiaoxian Li; Xuemin Li; Haofeng Shi; Fengxia Sun; Yunfei Du Lactonization with concomitant 1,2-aryl migration and alkoxylation mediated by dialkoxyphenyl iodides generated in situ Chemical Communications 2021 | Journal article DOI: 10.1039/D1CC03110D CONTRIBUTORS: Jingran Zhang; Ayesha Jalil; Jiaxin He; Zhenyang Yu; Yifu Cheng; Guangchen Li; Yunfei Du; Kang Zhao Nitrile-containing pharmaceuticals: target, mechanism of action, and their SAR studies RSC Medicinal Chemistry 2021 | Journal article DOI: 10.1039/D1MD00131K CONTRIBUTORS: Xi Wang; Yuanxun Wang; Xuemin Li; Zhenyang Yu; Chun Song; Yunfei Du An Interrupted Pummerer Reaction Mediated by a Hypervalent Iodine(III) Reagent: In Situ Formation of RSCl and Its Application for the Synthesis of 3-Sulfenylated Indoles The Journal of Organic Chemistry 2021-12-03 | Journal article DOI: 10.1021/acs.joc.1c02404 CONTRIBUTORS: Beibei Zhang; Xuemin Li; Xiaoxian Li; Zhenyang Yu; Bingyue Zhao; Xiaofan Wang; Yunfei Du; Kang Zhao Synthesis of 4‐Chalcogenylated Isoxazoles Mediated by PhICl2 and Diorganyl Disulfides/Diselenides Asian Journal of Organic Chemistry 2021-11 | Journal article DOI: 10.1002/ajoc.202100599 CONTRIBUTORS: Zhenyang Yu; Dongke Zhang; Xiaoxian Li; Beibei Zhang; Zhifang Yang; Yan Qian; Yunfei Du Formation of Carbon-Oxygen Bond Mediated by Hypervalent Iodine Reagents Under Metal-Free Conditions Mini-Reviews in Organic Chemistry 2021-07-27 | Journal article DOI: 10.2174/1570193X17999200807140943 CONTRIBUTORS: Ayesha Jalil; Yaxin O. Yang; Zhendong Chen; Rongxuan Jia; Tianhao Bi; Xuemin Li; Yunfei Du Unexpected Substituent Effects in Spiro-Compound Formation: Steering N-Aryl Propynamides and DMSO toward Site-Specific Sulfination in Quinolin-2-ones or Spiro[4,5]trienones The Journal of Organic Chemistry 2021-07-16 | Journal article DOI: 10.1021/acs.joc.1c00775 CONTRIBUTORS: Xiaoxian Li; Yuanxun Wang; Yaxin Ouyang; Zhenyang Yu; Beibei Zhang; Jingran Zhang; Haofeng Shi; Han Zuilhof; Yunfei Du Formation of Carbon-Nitrogen Bond Mediated by Hypervalent Iodine Reagents Under Metal-free Conditions Current Organic Chemistry 2021-02-01 | Journal article DOI: 10.2174/1385272822999201117154919 CONTRIBUTORS: Yaxin O. Yang; Xi Wang; Jiaxi Xiao; Yadong Li; Fengxia Sun; Yunfei Du A new hypervalent iodine(iii/v) oxidant and its application to the synthesis of 2H-azirines Chemical Science 2020 | Journal article DOI: 10.1039/C9SC05536C CONTRIBUTORS: Guangtao Zhang; Yuanxun Wang; Jun Xu; Jiyun Sun; Fengxia Sun; Yilin Zhang; Chenglin Zhang; Yunfei Du Hypervalent iodine reagent-mediated reactions involving rearrangement processes Chemical Communications 2020 | Journal article DOI: 10.1039/D0CC05354F CONTRIBUTORS: Beibei Zhang; Xiaoxian Li; Boying Guo; Yunfei Du Metal-free synthesis of 3-chalcogenyl chromones from alkynyl aryl ketones and diorganyl diselenides/disulfides mediated by PIFA Organic Chemistry Frontiers 2020 | Journal article DOI: 10.1039/D0QO01175D CONTRIBUTORS: Zhenkang Ai; Jiaxi Xiao; Yadong Li; Boying Guo; Yunfei Du; Kang Zhao Synthesis of Spiro[benzofuran‐2,2'‐benzo[b]thiophene]‐3,3'‐diones via PIDA/CuBr‐Mediated Spirocyclization European Journal of Organic Chemistry 2020-11-15 | Journal article DOI: 10.1002/ejoc.202001001 CONTRIBUTORS: Xuemin Li; Huiyuan Liang; Yaxin O Yang; Xi Wang; Jingran Zhang; Donghua Wang; Fengxia Sun; Yunfei Du Construction of 4‐(Methylthio)isochromenones Skeleton through Regioselective Intramolecular Cyclization of 2‐Alkynylbenzoate Mediated by DMSO/[D6]DMSO and SOCl2 European Journal of Organic Chemistry 2020-02-21 | Journal article DOI: 10.1002/ejoc.201901723 CONTRIBUTORS: Xuechan An; Beibei Zhang; Xiaoxian Li; Tianshu Du; Zhenkang Ai; Chenglin Zhang; Jun Xu; Fengxia Sun; Yilin Zhang; Yunfei Du Correction to Construction of 2-Arylbenzo[4,5]thieno[2,3-d]thiazole Skeleton via CuCl/S-Mediated Three-Component Reaction Organic Letters 2020-02-21 | Journal article DOI: 10.1021/acs.orglett.0c00229 CONTRIBUTORS: Wei Zhang; Shanqing Tao; Huaibin Ge; Qiao Li; Zhenkang Ai; Xiaoxian Li; Beibei Zhang; Fengxia Sun; Xiaqing Xu; Yunfei Du Construction of 2-Arylbenzo[4,5]thieno[2,3-d]thiazole Skeleton via CuCl/S-Mediated Three-Component Reaction Organic Letters 2020-01-17 | Journal article DOI: 10.1021/acs.orglett.9b04206 CONTRIBUTORS: Wei Zhang; Shanqing Tao; Huaibin Ge; Qiao Li; Zhenkang Ai; Xiaoxian Li; Beibei Zhang; Fengxia Sun; Xiaqing Xu; Yunfei Du