曹松 - 华东理工大学

研究领域

1. 作用靶标特异的仿生农药化学：昆虫生长调节剂(苯甲酰脲类几丁质抑制剂、具有蜕皮激素活性的非甾醇类二芳酰肼类化合物)；含恶二唑哒嗪酮类化合物拒食剂；鱼尼丁受体氟虫双酰胺、氯虫苯甲酰胺类化合物。 2. 高效有机合成方法学(新型多组分反应的设计；多组分反应在农药、医药中的应用；点击化学参与的多组分反应)。 3. 新型含氟砌块的多组分反应；含氟活性化合物的合成。碳氟键的活化及官能团化。

近期论文

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Mild and metal-free trifluoromethylation and pentafluoroethylation of gem-difluoroalkenes with TMSCF3 and TMSCF2CF3 Guanyi Jin, Xuxue Zhang, Dan Fu, Wenpeng Dai and Song Cao* Tetrahedron, 2015, online Metal-free one-pot sequential direct diarylation of pyrazolin-5-ones with diaryliodonium salts Tao Huang, Xinfei Ji, Wei Wu, Fang Liang and Song Cao* RSC Advances, 2015, 5, 66598–66601 Nickel-catalyzed Suzuki-Miyaura type cross-coupling reactions of (2,2-difluorovinyl)benzene derivatives with arylboronic acids Yang Xiong, Tao Huang, Xinfei Ji, Jingjing Wu* and Song Cao* Org Biomol Chem, 2015, 13, 7389–7392 Mild electrophilic trifluoromethylthiolation of ketones with trifluoromethanesulfanamide Wei Wu, Xuxue Zhang, Fang Liang, Song Cao* Org Biomol Chem, 2015, 13, 6992–6999 Copper-Catalyzed Coupling Cyclization of gem-Difluoroalkenes with Activated Methylene Carbonyl Compounds: Facile Domino Access to Polysubstituted Furans Xuxue Zhang, Wenpeng Dai, Wei Wu, Song Cao* Org Lett, 2015, 17(11), 2708–2711 Synthesis of monofluoroalkenes through selective hydrodefluorination of gem-difluoroalkenes with Red-Al? Jingjing Wu,* Juan Xiao, Wenpeng Dai, Song Cao* RSC Advances, 2015, 5, 34498–34501 Perfluorobutyliodide-assisted direct cyanomethylation of azoles and phenols with acetonitrile Juan Zhang, Wei Wu, Xinfei Ji, Song Cao* RSC Advances, 2015, 5, 20562–20565 Synthesis of fluorovinyl aryl ethers by a three component reaction of gem-difluoroalkenes with arylboronic acids and oxygen Mingjin Wang, Fang Liang, Yang Xiong, Song Cao* RSC Advances, 2015, 5, 11996–11999 Base-mediated direct fluoroalkenylation of 2-phenyl-1,3,4-oxadiazole, benzothiazole and benzoxazole with gem-difluoroalkenes Xuxue Zhang, Yingyin Lin, Juan Zhang, Song Cao* RSC Advances., 2015, 5, 7905–7908 Stereoselective synthesis of b-fluoroenyne by the reaction of gem-difluoroalkenes with terminal alkynes Guanyi Jin, Juan Zhang, Wei Wu, Song Cao* J Fluorine Chem, 2014, 168, 240–246 Synthesis of polyfluoroaryl-containing 1,2,3-triazoles by reaction of polyfluoroarenes, sodium azide and active methylene ketones/esters Jingjing Wu,* Dan Fu, Song Cao* J Fluorine Chem, 2014, 168, 230–235 Palladium- or Nickel-catalyzed Kumada Cross-coupling Reaction of gem-Difluoroalkenes and Monofluoroalkenes with Grignard Reagents Wenpeng Dai, Juan Xiao, Guanyi Jin, Jingjing Wu *, Song Cao * J Org Chem, 2014, 79, 10537–10546 Copper-free Direct C–H Trifluoromethylation of Acetanilides with Sodium Trifluoromethanesulfinate Mingxi Wu, Xinfei Ji, Wenpeng Dai, Song Cao*J Org Chem, 2014, 79, 8984–8989 Synthesis of N-(a-Fluorovinyl)azoles by the Reaction of Difluoroalkenes with AzolesYang Xiong, Xuxue Zhang, Tao Huang, Song Cao* J Org Chem, 2014, 79, 6395–6402, Featured article, Cover Nickel-catalyzed N-heterocycle directed cross-coupling of fluorinated arenes with organozinc reagents Sen-Han Xiao, Yang Xiong, Xu-Xue Zhang, Song Cao* Tetrahedron, 2014, 70, 4405–4411