黄焰根 - 东华大学 - 化学化工与生物工程学院

研究领域

本课题组研究方向为含氟有机化合物的设计、合成及应用。主要包含以下两方面内容：(1)设计和合成一些结构新颖的含氟砌块，应用现代有机化学的手段，展开含氟有机化合物的反应研究，并应用所发展的含氟有机化合物的合成方法学开展含氟天然产物类似物的合成；(2)含氟功能材料研究，应用含氟化合物的低表面张力，设计和合成高性能的表面活性剂及纺织品拒水拒油功能整理剂。

近期论文

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[1] Huang, Yangen*; Zhang, Yanqiang; Shreeve, Jean'ne M*. “Nitrogen-Rich Salts Based on Energetic Nitroaminodiazido[1,3,5]triazine and Guanazine”. Chem. Eur. J. 2011, 17, 1538-1546. [2] Tang, Weiyi; Huang, Yangen; Qing, Feng-Ling*. “Synthesis and characterization of fluorinated polyacrylate graft copolymers capable as water and oil repellent finishing agents”. J. Appl. Polym. Sci. 2011, 119, 84-92. [3] Jing, Zhitao; Huang, Yangen*; Qing, Feng-Ling. “Synthesis of a-fluoro-b- amino acids via the Reformatsky reaction of chiral N-tert-butylsulfinylimines with ethyl bromofluoroacetate”. Chin. Chem. Lett. 2011, In press. [4] Xiao, Hengqiao; Huang, Yangen*; Qing, Feng-Ling. “Highly diastereoselective synthesis of α-trifluoromethylated α-propargylamines by acetylide addition to chiral CF3-substituted N-tert-butanesulfinyl ketimines”. Tetrahedron: Asymm. 2010, 21, 2949-2955. [5] Huang, Yangen; Gard, Gary L.; Shreeve, Jean'ne M*. “One-pot syntheses of 1,2,3-triazoles containing a pentafluorosulfanylalkyl group via click chemistry”. Tetrahedron Lett. 2010, 51, 6951-6954. [6] Garg, Sonali; Gao, Haixiang; Joo, Young-Hyuk; Parrish, Damon A.; Huang, Yangen; Shreeve, Jean'ne M*. “Taming of the Silver FOX”. J. Am. Chem. Soc., 2010, 132, 8888-8890. [7] Huang, Yangen; Read, Roger W.*; Wang, Xiaobei. “Efficient Alkylation Methods for the Synthesis of Hybrid Fluorocarbon - Hydrocarbon Tetrazoles as Potential Fluorinated Surfactants”. Aust. J. Chem. 2010, 63, 802-807. [8] Feng, Shijun; Huang, Yangen*; Wang, Qiang; Gao, Yu; Qing, Feng-Ling. “Synthesis and Anti-biofouling Properties of Novel Cross-linkable Terpolymers Containing Semifluoroalkyl Substituted Aromatic Side Chains”. Polym. Eng. Sci., 2010, 50(5), 944-951. [9] Tang, Weiyi; Huang, Yangen; Meng, Weidong; Qing, Feng-Ling*. “Synthesis of fluorinated hyperbranched polymers capable as highly hydrophobic and oleophobic coating materials”. Eur. Polym. J. 2010, 46, 506-518. [10] Gao, Yu; Huang, Yangen; Feng, Shijun; Gu, Guotuan; Qing, Feng-Ling*. “Novel superhydrophobic and highly oleophobic PFPE modified silica nanocomposite ”. J. Mater. Sci. 2010, 45(2), 460-466. [11] Huang, Xiao-Song; Huang, Yan-Gen; Qing, Feng-Ling*. “Novel poly(aryl ether)s containing benzimidazole pendants derived from 1,4-bis(2-benzimidazolyl)- 2,5-difluorobenzene”. J. Mater. Sci. 2009, 44(13), 3566-3573. [12] Feng, Shijun; Wang, Qiang; Gao, Yu; Huang, Yangen*. “Anti-biofouling property of a novel cross-linkable copolymer grafted a short semifluorinated aromatic side chain”. Adv. Mater. Res. 2009, 79-82, 973-976. [13] Huang, Yangen; Gao, Haixiang; Shreeve, Jean’ne M*. “Highly dense nitranilates – containing nitrogen-rich cations” Chem. Eur. J. 2009, 15, 917-923. [14] Huang, Yangen; Gao, Haixiang; Twamley, Brendan; Shreeve, Jean’ne M*. “Nitroamino Triazoles: Nitrogen-Rich Precursors of Stable Energetic Salts” Euro. J. Inorg. Chem., 2008, 2560-2568. [15] Gao, Haixiang; Huang, Yangen; Ye, Chengfeng; Twamley, Brendan; Shreeve, Jean’ne M*. “The Synthesis of Di(aminoguanidine) 5-Nitroiminotetrazolate: Some Diprotic or Monoprotic Acids as Precursors of Energetic Salts” Chem. Eur. J., 2008, 14, 5596-5603. [16] Tao, Guo-Hong; Huang, Yangen; Boatz, Jerry A; Shreeve, Jean’ne M*. “Energetic Ionic Liquids Based on Anionic Rare Earth Nitrate Complexes.” Chem. Eur. J., 2008, 14, 11167-11173. [17] Abe, Takashi; Tao, Guo-Hong; Joo, Young-Hyuk; Huang, Yangen; Twamley, Brendan; Shreeve, Jean''ne M.* “Activation of the C-F Bond: Transformation of CF3N=N- into 5-Azidotetrazoles” Angew. Chem. Inter. Ed. 2008, 47, 7087-7090. [18] Huang, Yangen; Gao, Haixiang; Twamley, Brendan; Shreeve, Jean''ne M *. “Synthesis and characterization of new energetic nitroformate salts.” Euro. J. Inorg. Chem., 2007, 2025-2030. [19] Huang, Yangen; Qing, Feng-Ling*. “Novel fluorous glycol derivatives for the immobilization of boronic acids.” QSAR Com. Sci. 2006, 25, 716-718. [20] Huang, Yangen; Chen, Dajun; Qing, Feng-Ling.* “Palladium(II)-catalyzed cross-coupling of fluorous Bis(pinacolato)diboron: An efficient access to fluorous boronates.” Synlett 2005, 1740-1742.