蔡正国 - 东华大学 - 材料科学与工程学院

研究领域

配位聚合与大分子设计；新型成纤高聚物设计、合成及应用研究

近期论文

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Z.Cai, Z. Shen, R. Jordan: Enhancement of Chain Growth and Chain Transfer Rates in Ethylene Polymerization by (Phosphine-sulfonate)PdMe Catalysts by Binding of B(C6F5)3 to the Sulfonate Group；ACS Catalysis 2 [6]，1187?C1195，（2012） Z. Cai, R. Harada, Y. Nakayama and Takeshi Shiono: Highly Active Living Random Copolymerization of Norbornene and 1-Alkene with ansa-Fluorenylamidodimethyltitanium Derivative: Substituent Effects on Fluorenyl ligand; Macromolecules 43[10], 4527-4531, (2010) Z. Cai, R. Y. Nakayama and Takeshi Shiono: Synthesis of Stereoblock Polypropylene by Change of Temperature in Living Polymerization; Macromole. Res. 18 [8], 737-741 (2010). Z. Cai, M. Oomagari, Y. Nakayama and T. Shiono: Highly Active Syndiospecific Living Polymerization of Higher 1-Alkene with ansa-Fluorenylamidodimethyltitanium Complex; Macromol. Rapid Commun. 30, 1812-1816 (2009) Z. Cai, M. Shinzawa, Y. Nakayama and Takeshi Shiono: Synthesis of Regioblock Polybutadiene with CoCl2-based Catalyst via Reversible Coordination of Lewis Base; Macromolecules 42[20], 7642-7643 (2009) Z. Cai, Y. Nakayama and T. Shiono: Facile Synthesis of Tailor-Made Stereoblock Polypropylenes via Successive Variation of Monomer; Macromolecules 41[17], 6596-6598 (2008) Z. Cai, Y. Nakayama and T. Shiono: Catalytic Synthesis of a Monodisperse Olefin Block Copolymer Using a Living Polymerization System; Macromol. Rapid Commun. 29, 525-529 (2008) Z. Cai, M. Shigemasa, Y. Nakayama and T. Shiono: Catalytic Synthesis of Monodisperse Polypropylene Using a Living Polymerization System with ansa-Fluorenylamidodimethyltitanium Based Catalysts; Macromolecules 39[19], 6321-6323 (2006) Z. Cai, Y. Nakayama and T. Shiono: Living Random Copolymerization of Propylene and Norbornene with ansa-Fluorenylamidodimethyltitanium Complex: Synthesis of Novel Syndiotactic Polypropylene-b-Poly(propylene-ran-norbornene); Macromolecules 39[6], 2031-2033 (2006) Z. Cai, T. Ikeda, M. Akita and T Shiono: Substituent Effect of tert-Butyl Group on Fluorenyl Ligand in Syndiospecific Living Polymerization of Propylene with ansa-Fluorenylamidodimethyltitanium Complex; Macromolecules 38[20], 8135-8139, (2005)