Fout, Alison R. - University of Illinois at Urbana-Champaign

个人简介

EDUCATION 2009 Ph.D. Chemistry Indiana University, Bloomington, IN Thesis Title: Unraveling Strong Bonds: Small Molecule Activation via Metal-Ligand Multiple Bonds Thesis Advisor: Prof. Daniel J. Mindiola 2004 M.S. Chemistry University of North Carolina at Charlotte, Charlotte, NC Thesis Title: Dialkylbis(mercaptoimidazolyl)borates Thesis Advisor: Prof. Daniel Rabinovich 2002 B.S. Chemistry, cum laude Gannon University, Erie, PA EMPLOYMENT 2012-Present University of Illinois at Urbana-Champaign (UIUC), Urbana, IL; Assistant Professor 2009 -2012 Harvard University, Cambridge, MA NIH NRSA and Mary Fieser Postdoctoral Fellow Advisor: Prof. Theodore A. Betley

研究领域

We are interested in developing synthetic systems containing structural and functional motifs found within the particular architecture of metalloproteins. Our approach to facilitate multi-electron transformations is to use a ligand scaffold with two key features: (1) a hydrogen-bonding network to stabilize reactive intermediates and channel substrates toward the metal center; (2) a redox active phenol or tyrosine to mediate multi-electron transformations. The design of

近期论文

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Ford, C. L.;* Park, Y.;* Matson, E. M.; Gordon, Z.; Fout, A. R. “A bio-inspired iron catalyst for nitrate and perchlorate reduction.” Science, 2016, 354, 741-743. * authors contributed equally. Tokmic, K.; Fout, A. R. “Alkyne Semi-hydrogenation with a well-defined non-classical Cobalt catalyst: A H2 spin on isomerization and E-Selectivity.” J. Am. Chem. Soc. 2016, 138, 13700-13705. Tokmic, K.; Markus, C. R.; Zhu, L.; Fout, A. R. “Well-defined Cobalt(I) Dihydrogen Catalyst: Experimental Evidence for a Co(I)/Co(III) Catalytic Redox Process in Olefin Hydrogenation.” J. Am. Chem. Soc. 2016, 138, 11907-11913. Ibrahim, A. D.; Tokmic, K.T. Brennan, M. R.; Kim, D.;* Nilges, M.J.; Bertke, J. A.; Fout, A. R. “Monoanionic bis(carbene) pincer complexes featuring cobalt(I-III) oxidation states.” Dalton Trans. 2016, 45, – invited for New Talent: Americas issue. Ibrahim, A. D.; Entsminger, S. W.;* Zhu, L.; Fout, A. R. “A Highly Chemoselective Cobalt Catalyst for the Hydrosilylation of Alkenes Using Tertiary Silanes and Hydrosiloxanes.” ACS Catal. 2016, 6, 3589-3593. Espinosa Martinez, G.; Ocampo, C.;* Park, Y.; Fout, A. R. “Accessing Pincer Bis(carbene) Ni(IV) Complexes from Ni(II) via Halide and Halide Surrogates.” J. Am. Chem. Soc. 2016, 138, 4290-4293.Alison R. Fout, Ph.D. Matson, E. M.;* Park, Y.;* Bertke, J. A.; Fout, A. R. Synthesis and characterization of M(II) (M = Mn, Fe and Co) azafulvene complexes and their X3- derivatives. Dalton. Trans. 2015, 10377-10384. * authors contributed equally Park, Y.;* Matson, E. M.;* Nilges, M.J.; Fout A. R. Exploring Mn−O Bonding in the Context of an Electronically Flexible Secondary Coordination Sphere: Synthesis of a Mn(III)-Oxo. Chem. Comm. 2015, 5310-5313. * authors contributed equally Matson, E. M.; Park, Y.; Bertke, J. A.; Fout, A. R. Facile Nitrite Reduction in a Non-Heme System: Formation of an Fe(III)-Oxo. J. Am. Chem. Soc. 2014, 136, 17398-17401. Matson, E. M.; Gordon, Z.; Lin, B. L.; Nilges, M. J.; Fout, A. R. Meridional vs. Facial Coordination Geometries of a Dipodal Ligand Framework Featuring a Secondary Coordination Sphere. Dalton Trans. 2014, 43, 16992-16995. Matson, E. M.; Espinosa Martinez, G.; Ibrahim, A.; Jackson, B. J.; Bertke, J. A.; Fout, A. R. Nickel(II) Pincer Carbene Complexes: Oxidative Addition of an Aryl C-H Bond to Form a Ni(II) Hydride.Organometallics 2015 34, 399-407. Brennan, M. R.; Kim, D.;* Fout, A. R. A Synthetic and Mechanistic Investigation into the Cobalt(I)-Catalyzed Amination of Aryl Halides. Chem. Sci. 2014, 5, 4831-4839. Matson, E. M.; Bertke, J. A.; Fout, A. R. Isolation of Fe(II)-Aqua and Hydroxyl Complexes Featuring a Tripodal Hydrogen-Bond Donor and Acceptor Ligand. Inorg. Chem. 2014, 53, 4450-4458. Selected as newsworthy article May 6-19, 2014.Previous Publications Hickey, A.K.; Crestani, M. G.; Fout, A. R.; Gao, X.; Chen, C.-H.; Mindiola, D. J. Dehydrogenation of hydrocarbons with metal-carbon multiple bonds and trapping of a titanium(II) intermediate. Dalton Trans. 2014, 43, 9834-9837. Fan, H.; Fout, A. R.; Bailey, B. C.; Pink, M.; Baik, M.-H.; Mindiola, D. J. Understanding intermolecular C-F bond activation by a transient titanium neopentylidyne: experimental and theoretical studies on the competition between 1,2-CF bond addition and [2+2]-cycloaddition/β-fluoride elimination. Dalton Trans. 2013, 42, 4163-4174. Powers, T. M.; Gu, N.; Fout, A. R.; Baldwin, A. M.; Hernandez Sanchez, R.; Alfonso, D. M.; Chen, Y.-S.; Zheng, S.-L.; Betley, T. A. Synthesis of Open-Shell Bimetallic Mn/Fe Trinuclear Clusters. J. Am. Chem. Soc. 2013, 135, 14448-14458. Fout, A. R.; Xiao, D. J.; Zhao, Q.; Harris, T. D.; King, E. R.; Eames, E. V.; Betley, T. A. Trigonal Mn3 and Co3 Complexes Supported by Weak-Field Ligands: A Structural, Spectroscopic, Magnetic, and Computational Investigation into the Correlation Between Molecular Structure and Electronic Structure. Inorg. Chem. 2012, 51, 10290-10299. Fout, A. R.; Zhao, Q.; Xiao, D. J.; Betley, T. A. Oxidative Group Transfer to a Trimanganese Complex Form an Interstitial µ6-nitride and µ6-oxide, [Mn6(µ6-E)]n-. J. Am. Chem. Soc. 2011, 133, 16750-16753. Andino, J. G.; Fan, H.; Fout, A. R.; Bailey, B. C.; Baik, M.-H.; Mindiola, D. J. 1,2-CF Bond Activation of Perfluoroarenes and Alkylidene Isomers of Titanium. DFT Analysis of the C-F Bond Activation Pathway and Rotation of the Titanium Alkylidene Moiety. J. Organomet. Chem. 2011, 696, 4138-4146.