个人简介
孙伟，男，博士，研究员，博士生导师，羰基合成与选择氧化国家重点实验室副主任。1998年本科毕业于曲阜师范大学，2003年于中国科学院兰州化学物理研究所获理学博士学位。2003年获德国洪堡奖学金，在德国慕尼黑工业大学无机化学研究所进行博士后研究。2005年底回国，并入选中国科学院“百人计划”，在中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室开展仿生催化、均相催化及纳米催化等领域的研究工作，目前主要开展非血红素模拟酶催化的高效不对称氧化反应研究。已在Acc. Chem. Res., J. Am. Chem. Soc., Angew. Chem. Int. Ed.及《催化学报》等国内外重要学术期刊发表研究论文100余篇。现为《有机化学》编委、《催化学报》青年编委。
代表性科研工作：基于高活性非血红素生物酶活性中心，发展了一系列手性四氮配体及其锰铁配合物，实现了烯烃、烷烃的高效不对称氧化反应（Bioinspired Manganese and Iron Complexes for Enantioselective Oxidation Reactions: Ligand Design, Catalytic Activity, and Beyond. Acc. Chem. Res. 2019, 52, 2370-2381.）。最近，Amgen公司基于我们发展的高效非血红素锰催化烯烃不对称环氧化反应（Manganese Catalysts with C1-Symmetric N4 Ligand for Enantioselective Epoxidation of Olefins, Chem. Eur. J., 2012, 18, 6750-6753.），实现了卡非佐米关键中间体手性环氧酮的工业生产，锰催化剂用量低至0.04 mol% （Org. Process Res. Dev. 2020, 24, 490-499.）。相关工作也充分展现了非血红素锰催化剂的高活性。
近期论文
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1. Wei Sun*, Qiangsheng Sun, Bioinspired Manganese and Iron Complexes for Enantioselective Oxidation Reactions: Ligand Design, Catalytic Activity, and Beyond. Acc. Chem. Res. 2019, 52, 2370-2381.
2. Bin Qiu, Daqian Xu, Qiangsheng Sun, Jin Lin, Wei Sun*, Manganese-Catalyzed Asymmetric Oxidation of Methylene C-H of Spirocyclic Oxindoles and Dihydroquinolinones with Hydrogen Peroxide. Org. Lett. 2019, 21, 618-622.
3. Junyi Du, Chengxia Miao, Chungu Xia, Yong-Min Lee, Wonwoo Nam*, Wei Sun*, Mechanistic Insights into the Enantioselective Epoxidation of Olefins by Bioinspired Manganese Complexes: Role of Carboxylic Acid and Nature of Active Oxidant. ACS Catal. 2018, 8, 4528-4538.
4. Bin Qiu, Daqian Xu, Qiangsheng Sun, Chengxia Miao, Yong-Min Lee, Xiao-Xi Li, Wonwoo Nam*, Wei Sun*, Highly Enantioselective Oxidation of Spirocyclic Hydrocarbons by Bioinspired Manganese Catalysts and Hydrogen Peroxide. ACS Catal. 2018, 8, 2479-2487.
5. Wenfang Wang, Qiangsheng Sun, Chungu Xia, Wei Sun*, Enantioselective epoxidation of olefins with hydrogen peroxide catalyzed by bioinspired aminopyridine manganese complexes derived from L-proline, Chin. J. Catal. 2018, 39, 1463-1469.
6. Chengxia Miao, Xiao-Xi Li, Yong-Min Lee, Chungu Xia, Yong Wang, Wonwoo Nam*, and Wei Sun*，Nonheme Manganese Complex-Catalyzed Oxidation and Oxidative Kinetic Resolution of Secondary Alcohols by Hydrogen Peroxide, Chem. Sci. 2017, 8, 7476.
7. Chengxia Miao, Xingbin Yan, Daqian Xu, Chungu Xia, Wei Sun*, Bioinspired Manganese Complexes and Graphene Oxide Synergistically Catalyzed Asymmetric Epoxidation of Olefins with Aqueous Hydrogen Peroxide. Adv. Syn Catal. 2017, 359, 476-484.
8. Chengxia Miao, Bin Wang, Yong Wang, Chungu Xia, Yong-Min Lee, Wonwoo Nam*, and Wei Sun*，Proton-Promoted and Anion-Enhanced Epoxidation of Olefins by Hydrogen Peroxide in the Presence of Nonheme Manganese Catalysts, J. Am. Chem. Soc. 2016, 138, 936 – 943.
9. Duyi Shen, Bin Qiu, Daqian Xu, Chengxia Miao, Chungu Xia, Wei Sun*, Enantioselective Epoxidation of Olefins with H2O2 Catalyzed by Bioinspired Aminopyridine Manganese Complexes, Org. Lett. 2016, 18, 372–375.
10. Chengxia Miao, Hanqing Zhao, Quanyi Zhao, Chungu Xia，Wei Sun*，NHPI and Ferric Nitrate: a Mild and Selective System for Aerobic Oxidation of Benzylic Methylenes，Catal. Sci. Technol. 2016, 6, 1378-1383.
11. Zhenbei Zhang, Qiangsheng Sun, Daqian Xu, Chunggu Xia, Wei Sun*, Directly halogenative dearomatization of 2-naphthols by NXS (X = Cl, Br) in water, Green Chem. 2016,18, 5485–5492.
12. Zhenbei Zhang, Qiangsheng Sun, Chungu Xia, and Wei Sun*, CO2 as a C1 Source: B(C6F5)3-Catalyzed Cyclization of o-Phenylene-diamines to Construct Benzimidazoles in the Presence of Hydrosilane. Org. Lett. 2016, 18, 6316-6319.
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