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“Ligand-Controlled Regiodivergent Ring Expansion of Benzosilacyclobutenes with Alkynes en Route to Axially Chiral Silacyclohexenyl Arenes” Tang,X.; Tang, Y.; Peng, J.; Du, H.; Huang, L.; Gao, J.; Liu, S.; Wang, D.; Wang, W.; Gao, L.; Lan, Y.* Song Z.* J. Am. Chem. Soc. 2024, ASAP. (DOI: 10.1021/jacs.4c00252)
“Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C-H Functionalization” Wang, X.; He, J.; Wang, Y.-N.; Zhao, Z.; Jiang, K.; Yang, W.; Zhang, T.; Jia, S.*; Zhong, K.*; Niu, L.*; Lan, Y.* Chem. Rev. 2024, 124, 10192. (DOI: 10.1021/acs.chemrev.4c00188)
“Asymmetric hydrogenation of ketimines with minimally different alkyl groups” Wang, M.; Liu, S.; Liu, H.; Wang, Y.; Lan, Y.*; Liu, Q.* Nat. 2024, 631, 556-562. (DOI: 10.1038/s41586-024-07581-z)
“Mechanistic insights into facilitating reductive elimination from Ni(II) species” Qiao, B.; Lin, F.-Y.; Fu, D.; Li, S.-J.; Zhang, T.*; Lan, Y.* Chem. Commun. 2024, 60, 8008-8019. (DOI: 10.1039/d4cc02667e)
“Alkene insertion enables ring-opening of vinyl epoxides: a theoretical perspective” Liu, J.; Yang, K.; Liu, J.; Fu, D.; Li, S.-J.*; Zhang, W.*; Lan, Y.* Org. Chem. Front. 2024, 11, 4730-4739. (DOI: 10.1039/d4qo00950a)
“Visible-light-driven synthesis of N-heteroaromatic carboxylic acids by thiolate-catalysed carboxylation of C(sp²)-H bonds using CO2” Jiang, Y.-X.; Liao, L.-L.; Gao, T.-Y.; Xu, W.-H.; Zhang, W.; Song, L.; Sun, G.-Q.; Ye, J.-H.*; Lan, Y.*; Yu, D.-G.* Nat. Synth. 2024, 3, 394-405. (DOI: 10.1038/s44160-023-00465-6)
“Enhancing Hydride Transfer in Catalytic Hydrogenation via σ‑Electron-Induced Polarization of Imines” Liu, S.; Yang, H.; Wang, Y.-N.; Zhao, Q.; Wang, Y.*; Bai, R.*; Liu, Q.*; Lan, Y.* J. Am. Chem. Soc. 2024, 146, 16357-16362. (DOI: 10.1021/jacs.4c02096)
“Synthesis of benzooxepane-fused cyclobutene derivatives via Pd-catalyzed cascade reactions of haloarenes and diynylic ethers” Zhu, S.*; Huang, W.; Liu, S.; Yu, R.; Ma, Y.; Wang, H.; Zhang, R.; Liu, B.; Lan, Y.*; Shen, R. Chem. Commun. 2024, 60, 5707-5710. (DOI: 10.1039/d4cc00999a)
“Bond Dissociation Energy-Controlled Regioselectivity in Hydrofunctionalization” Peng, J.; He, X.; Luo, X.; Zhong, K.*; Liao, L.-L.*; Bai, R.*; Lan, Y.* ACS Catal. 2024, 14, 8030-8040. (DOI: 10.1021/acscatal.4c00304)
“Chemo-, regio- and stereoselective access to polysubstituted 1,3-dienes via Nickel-catalyzed four-component reactions” Chen, S.; Wang, Y.-N.; Xie, J.; Li, W.; Ye, M.; Ma, X.; Yang, K.; Li, S.; Lan, Y.*; Song, Q.* Nat. Commun. 2024, 15, 5479. (DOI: 10.1038/s41467-024-49870-1)
“Making Full Use of TMSCF3: Deoxygenative Trifluoromethylation/Silylation of Amides” Wang, Y.; Li, S.-J.; Jiang, F.; Lan, Y.*; Wang, X.* J. Am. Chem. Soc. 2024, 146, 19286-19294. (DOI: 10.1021/jacs.4c04760)
“Copper- and Palladium-Cocatalyzed Chemo‑, Regio‑, Stereo‑, and Atroposelective Arylboration of 1,3-Enynes” Li, W.; Chen, H.; Zheng, Y.; Lu, Y.; Xie, J.; Chen, S.; Lan, Y.*; Song ,Q.* ACS Catal. 2024, 14, 11318-11331. (DOI: 10.1021/acscatal.4c03301)
“Iron photocatalysis via Brønsted acid-unlocked ligand-to-metal charge transfer” Jiang, X.; Lan, Y.*; Hao, Y.; Jiang, K.; He, J.; Zhu, J.; Jia, S.; Song, J.; Li, S.-J.*; Niu, L.* Nat. Commun. 2024, 15, 6115. (DOI: 10.1038/s41467-024-50507-6)
“Rhodium-Catalyzed Direct ortho-Arylation of Anilines” Jacob, C.; Annibaletto, J.; Peng, J.; Bai, R.; Maes, B. U. W.; Lan, Y.*; Evano, G.* Angew. Chem. Int. Ed. 2024, 63, e202403553. (DOI: 10.1002/anie.202403553)
“Metal-Free 1,3-Boronate Rearrangement to Ketones Driven by Visible Light” Hao, K.; Li, D.; Fu, D.; Zou, P.; Xie, S.; Lan, Y.*; Chen, Y.* Angew. Chem. Int. Ed. 2024, 63, e202316481. (DOI: 10.1002/anie.202316481)
“Enantio- and regioselective [2 + 2 + 2] cycloaddition of BN-diynes for construction of C-B axial chirality” Wang, H.; Qiao, B.; Zhu, J.; Guo, H.; Zhang, Z.; Yang, K.*; Li, S.-J.; Lan, Y.*; Song, Q.* Chem 2024, 10, 317-329. (DOI: 10.1016/j.chempr.2023.09.017)
“Well-defined chiral dinuclear copper complexes in enantioselective propargylic substitution: For a long-standing supposition on binuclear mechanism” Cai, Q.; Rao, H.; Li, S.-J.; Lan, Y.*; Ding, K.*; Wang, X.* Chem 2024, 10, 265-282. (DOI: 10.1016/j.chempr.2023.09.006)
“Transition-metal-free C(sp2)–C(sp3) cross-coupling of α-(pseudo)halo aliphatic ketones with boronic acids via a 1,4-metallate shift” Li, X.; Chen, H.; Wang, H.; Zhang, Q.; Sheng, H.; Lan, Y.*; Song, Q.* Nat. Synth. 2023, 2, 1211-1221. (DOI: 10.1038/s44160-023-00373-9)
“Theoretical Study of How Electronic Effect of Substituent Affects Regioselectivity of C—Si Reductive Elimination” Peng, J.; He, X.; Liao, L.-L.*; Bai, R.*; Lan, Y.* Chin. J. Org. Chem. 2023, 43, 3608-3613. (DOI: 10.6023/cjoc202308009)
“Axial chirality reversal and enantioselective access to Si-stereogenic silylallene” Jin, C.; He, X.; Chen, S.; Guo, Z.; Lan, Y.*; Shen, X.* Chem 2023, 9, 2956-2970. (DOI: 10.1016/j.chempr.2023.06.014)
“Anion-Tuning of Organozincs Steering Cobalt-Catalyzed Radical Relay Couplings” Liu, X.; Chen, H.; Yang, D.; Hu, B.; Hu, Y.; Wang, S.; Lan, Y.*; Lei, A.*; Li, J.* ACS Catal. 2023, 13, 9254-9263. (DOI: 10.1021/acscatal.3c01022)
“Origins of Catalyst-Controlled Chemoselectivity in Transition-Metal-Catalyzed Divergent Epoxide Conversion” Wang, X.; Yang, K.; Wang, Y.-N.; Li, S.-J.*; Wei, D.*; Lan, Y.* ACS Catal. 2023, 13, 7616-7626. (DOI: 10.1021/acscatal.3c01022)
“A bridged backbone strategy enables collective synthesis of strychnan alkaloids” Zhou, W.; Xi, S.; Chen, H.; Jiang, D.; Yang, J.; Liu, S.; He, L.; Qiu, H.; Lan, Y.*; Zhang, M.* Nat. Chem. 2023, 15, 1074-1082. (DOI: 10.1038/s41557-023-01264-4)
“A theoretical study of selective radical relay and coupling reactions for alkene difunctionalization” Yang, K.; Liu, J.; Fu, D.; Niu, L.*; Li, S.-J.*; Lan, Y.* Org. Chem. Front. 2023, 10, 4336-4341. (DOI: 10.1039/d3qo00357d)
“Oxidative cyclopalladation triggers the hydroalkylation of alkynes” Zhong, K.; Liu, S.; He, X.; Ni, H.; Lai, W.; Gong, W.; Shan, C.; Zhao, Z.; Lan, Y.*; Bai, R.* Chin. Chem. Lett. 2023, 34, 108339. (DOI: 10.1016/j.cclet.2023.108339)
“Programmable zigzag π-extension toward graphene-like molecules by the stacking of naphthalene blocks” Yin, J.; Li, J.; Chen, H.; Wang, Y.; Zhang, Y.; Zhang, C.; Bin, Z.; Pyle, D.; Yang, Y.; Lan, Y.*; You, J.* Nat. Synth. 2023, 2, 838-847. (DOI: 10.1038/s44160-023-00306-6)
“Visible-light-driven thio-carboxylation of alkynes with CO2: facile synthesis of thiochromones” Miao, M.; Zhu, L.; Zhao, H.; Song, L.; Yan, S.-S.; Liao, L.-L.; Ye, J.-H.*; Lan, Y.*; Yu, D.-G.* Sci. Chin. Chem. 2023, 66, 1457-1466. (DOI: 10.1007/s11426-022-1554-x)
“Electroreductive Dicarboxylation of Unactivated Skipped Dienes with CO2” Zhang, W.; Liao, L.-L.; Li, L.; Liu, Y.; Dai, L.-F.; Sun, G.-Q.; Ran, C.-K.; Ye, J.-H.*; Lan, Y.*; Yu, D.-G.* Angew. Chem. Int. Ed. 2023, 62, e202301892. (DOI: 10.1002/anie.202301892)
“Catalytic asymmetric oxa-Diels–Alder reaction of acroleins with simple alkenes” Zeng, L.; Liu, S.; Lan, Y.*; Gao, L.* Nat. Commun. 2023, 14, 3511. (DOI: 10.1038/s41467-023-39184-z)
“Palladium-Catalyzed Cross-Coupling, Divergent Allene Generation, and Cycloadditions toward Cyclobuta[b]naphthalen-3(1H)‑ones and 11H-Benzo[b]fluoren-11-ones” Zhu, S.*; Wang, D.; Liu, S.; Ma, Y.; Wang, H.; Lan, Y.*; Bai, R.; Shen, R.* ACS Catal. 2023, 13, 8402-8412. (DOI: 10.1021/acscatal.3c00857)
“Deaminative radical reactions via relayed proton-coupled electron transfer” Shi, Q.; Chen, K.; Guo, L.; Han, L.; Wei, D.*; Lan, Y.* Org. Chem. Front. 2023, 10, 2155-2164. (DOI: 10.1039/d3qo00192j)
“Counteranion-Directed Catalysis for Asymmetric Radical Cation Transformations” Bao, P.; Lan, Y.* Chin. J. Org. Chem. 2023, 43, 1600-1601. (DOI: 10.6023/cjoc202300021)
“Regiodivergent catalytic asymmetric dearomative cycloaddition of bicyclic heteroaromatics” Peng, L.; Zeng, Z.; Li, K.; Liu, Y.; Lan, Y.*; Yan, H.* Sci. Adv. 2023, 9, eadg1645. (DOI: 10.1126/sciadv.adg1645)
“Empowering boronic acids as hydroxyl synthons for aryne induced three-component coupling reactions” Fan, R.; Liu, S.; Yan, Q.; Wei, Y.; Wang, J.; Lan, Y.*; Tan, J.* Chem. Sci. 2023, 14, 4278-4287. (DOI: 10.1039/d3sc00072a)
“UV light–driven late-stage skeletal reorganization to diverse limonoid frameworks: A proof of concept for photobiosynthesis” Wu, J.; Li, S.-J.; Jiang, L.; Ma, X.-C.*; Lan, Y.*; Shen, L.* Sci. Adv. 2023, 9, eade2981. (DOI: 10.1126/sciadv.ade2981)
“Remote Stereocontrol of All-Carbon Quaternary Centers via Cobalt-Catalyzed Asymmetric Olefin Isomerization” Rong, X.; Yang, J.; Liu, S.; Lan, Y.*; Liu, Q.* CCS Chem. 2023, 5, 1293-1300. (DOI: 10.31635/ccschem.023.202202616)
“Organocatalytic asymmetric deoxygenation of sulfones to access chiral sulfinyl compounds” Huang, S.; Zeng, Z.; Zhang, N.; Qin, W.*; Lan, Y.*; Yan, H.* Nat. Chem. 2023, 15, 185-193. (DOI: 10.1038/s41557-022-01120-x)
“N‑Heterocyclic Carbene/Brønsted Acid Cooperatively Catalyzed Conversions of α, β‑Unsaturated Carbonyls: Hydrogen Bond Donor/Acceptor-Electrophile/Nucleophile Combination Models” Wang, X.; Wang, Y.-N.; Pei, Z.; Li, S.-J.; Wei, D.*; Lan, Y.* ACS Catal. 2023, 13, 612-623. (DOI: 10.1021/acscatal.2c05373)
“Revised Mechanism of C(sp3)−C(sp3) Reductive Elimination from Ni(II) with the Assistance of a Z‑Type Metalloligand” Zhang, T.; Zhong, K.; Lin, Z.-K.; Niu, L.; Li, Z.-Q.; Bai, R.*; Engle, K. M.*; Lan, Y.* J. Am. Chem. Soc. 2023, 145, 2207-2218. (DOI: 10.1021/jacs.2c09739)
“Formyl Radical Generation from α-Chloro N-Methoxyphthalimides Enables Selective Aldehyde Synthesis” Liu, D.; Yang, K.; Fang, D.; Li, S.-J.; Lan, Y.*; Chen, Y.* Angew. Chem. Int. Ed. 2023, 62, e202213686. (DOI: 10.1002/anie.202213686)
“Mechanistic views and computational studies on transition-metal-catalyzed reductive coupling reactions” Duan, A.*; Xiao, F.; Lan, Y.*; Niu, L.* Chem. Soc. Rev. 2022, 51, 9986-10015. (DOI: 10.1039/d2cs00371f)
“Triazole-phosphine Pd(II)-Enabled Dehydrogenation of Alcohols or Amines: A Combination of Experimental and Theoretical Study” Tian, Y.; Liu, Y.; Han, J.; Liu, L.; Luo, H.; Hou, M.; Bai, R.; Lan, Y.*; Li, B.* Organometallics 2022, 41, 3504-3513. (DOI: 10.1021/acs.organomet.2c00276)
“Azoarene activation for Schmidt-type reaction and mechanistic insights” Meng, F.-T.; Wang, Y.-N.; Qin, X.-Y.; Li, S.-J.; Li, J.; Hao, W.-J.*; Tu, S.-J.; Lan, Y.*; Jiang, B.* Nat. Commun. 2022, 13, 7393. (DOI: 10.1038/s41467-022-35141-4)
“Nickel-Catalyzed Cross-Redistribution between Hydrosilanes and Silacyclobutanes” Chen, S.; He, X.; Jin, C.; Zhang, W.; Yang, Y.; Liu, S.; Lan, Y.*; Houk, K. N.*; Shen, X.* Angew. Chem. Int. Ed. 2022, 61, e202213431. (DOI: 10.1002/anie.202213431)
“Enantioselective Synthesis of Spirosilabicyclohexenes by Asymmetric Dual Ring Expansion of Spirosilabicyclobutane with Alkynes” Chen, H.; Peng, J.; Pang, Q.; Du, H.; Huang, L.; Gao, L.; Lan, Y.*; Yang, C.*; Song, Z.* Angew. Chem. Int. Ed. 2022, 61, e202212889. (DOI: 10.1002/anie. 202212889)
“The in Vitro Biosynthesis of Chlorophyll b via Enzyme Catalysis” Niu, L.; Lan, Y.* ACS Cent. Sci. 2022, 8, 1373-1375. (DOI: 10.1021/acscentsci.2c00997)
“Catalytic Multicomponent Synthesis of C-Acyl Glycosides by Consecutive Cross-Electrophile Couplings” Jiang, Y.; Yang, K.; Wei, Y.; Wang, Q.*; Li, S.-J.*; Lan, Y.*; Koh, M. J.* Angew. Chem. Int. Ed. 2022, 61, e202211043. (DOI: 10.1002/anie.202211043)
“Structure, reactivity and catalytic properties of manganese-hydride amidate complexes” Wang, Y.; Liu, S.; Yang, H.; Li, H.; Lan, Y.*; Liu, Q.* Nat. Chem. 2022, 14, ASAP. (DOI: 10.1038/s41557-022-01036-6)
“What is the difference between mono- and biphosphine ligands? Revealing the chemoselectivity in Pd-catalysed carbenation of bromonaphthalene” Gong, W.; Fu, D.; Zhong, K.; Ni, H.; He, X.; Shan, C.*; Li, R.*; Lan, Y.* Org. Chem. Front. 2022, 9, 4916-4923. (DOI: 10.1039/d2qo00910b)
“How Strain-Release Determines Chemoselectivity: A Mechanistic Study of Rhodium-Catalyzed Bicyclo[1.1.0]butane Activation” Lai, W.; Zhong, K.*; Liu, S.; Liu, S.; Chen, H.; Ni, H.; Zeng, Z.; Zhao, Z.; Lan, Y.*; Bai, R.* J. Phys. Chem. Lett. 2022, 13, 7694-7701. (DOI: 10.1021/acs.jpclett.2c01528)
“Regio- and Stereoselective 1,2-Oxyhalogenation of Non-Conjugated Alkynes via Directed Nucleopalladation: Catalytic Access to Tetrasubstituted Alkenes” Liu, M.; Sun, J.; Zhang, T.; Ding, Y.; Han, Y.-Q.; Martín-Montero, R.; Lan, Y.*; Shi, B.-F.*; Engle, K. M.* Angew. Chem. Int. Ed. 2022, 61, e202209099. (DOI: 10.1002/anie.202209099)
“Perfluoroarene Interaction-Controlled Chiral Phosphoric Acid-Catalyzed Enantioselective Michael Addition of Difluoroenoxysilanes to Azadienes: a Combination of Experimental and Theoretical Studies” Li, J.; Chen, H.; Zhong, R.; Zhu, L.; Liu, S.; Ding, H.; Yang, J.; Wang, L.; Lan, Y.*; Wang, Z.* ACS Catal. 2022, 12, 9655-9663. (DOI: 10.1021/acscatal.2c01671)
“The chiral pyridoxal-catalyzed biomimetic Mannich reaction: the mechanism and origin of stereoselectivity” Han, L.-L.; Zhang, Q.-Y.; Li, X.; Qiao, Y.*; Lan, Y.*; Wei, D.* Org. Chem. Front. 2022, 9, 4401-4410. (DOI: 10.1039/d2qo00705c)
“Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes” Chen, S.; He, X.; Jin, Y.; Lan, Y.*; Shen, X.* Nat. Commun. 2022, 13, 3691. (DOI: 10.1038/s41467-022-31458-2)
“The regioselectivity of the sulfonylation of tetrazoles: a theoretical view” Liu, C.-C.; Qiao, B.; Qu, L.-B.; Zhang, T.*; Li, S.-J.*; Lan, Y.* Org. Chem. Front. 2022, 9, 4009-4015. (DOI: 10.1039/d2qo00797e)
“Iminyl radical-triggered relay annulation for the construction of bridged aza-tetracycles bearing four contiguous stereogenic centers” Jiang, K.; Li, S.-J.; Liu, Q.-P.; Yu, N.; Li, Y.-L.; Zhou, Y.-Q.; He, K.-C.; Lin, J.; Zheng, T.-Y.; Lang, J.; Lan, Y.*; Wei, Y.* Chem. Sci. 2022, 13, 7283-7288. (DOI: 10.1039/d2sc01548j)
“An alternative non-redox Ni(I) pathway in hydroaminomethylation: A theoretical perspective” Qiao, B.; Bai, R.; Zhang, T.*; Li, S.-J.*; Lan, Y.* Mol. Catal. 2022, 526, 112378. (DOI: 10.1016/j.mcat.2022.112378)
“Design and synthesis of stable four-coordinated benzotriazole-borane with tunable fluorescence emission” Tang, Q.; Li, S.-J.; Ye, X.; Yuan, T.; Zhao, K.; He, Y.; Shan, C.; Wojtas, L.; Richardson, D.; Lan, Y.*; Shi, X.* Chem. Sci. 2022, 13, 5982-5987. (DOI: 10.1039/d2sc01103d)
“Visible-light-induced cross-coupling of aryl iodides with hydrazones via an EDA-complex” Pan, P.; Liu, S.; Lan, Y.*; Zeng, H.*; Li, C.-J.* Chem. Sci. 2022, 13, 7165-7171. (DOI: 10.1039/d2sc01909d)
“NHC-Catalyzed Transformation Reactions of Imines: Electrophilic versus Nucleophilic Attack” Liu, C.; Han, P.; Zhang, X.; Qiao, Y.; Xu, Z.; Zhang, Y.; Li, D.; Wei, D.*; Lan, Y.* J. Org. Chem. 2022, 87, 7989-7994. (DOI: 10.1021/acs.joc.2c00621)
“Enantioselective Nickel-Catalyzed Si−C(sp2) Bond Activation and Migratory Insertion to Aldehydes: Reaction Scope and Mechanism” Wang, Q.; Zhong, K.-B.; Xu, H.; Li, S.-N.; Zhu, W.-K.; Ye, F.; Xu, Z.; Lan, Y.*; Xu, L.-W.* ACS Catal. 2022, 12, 4571-4580. (DOI: 10.1021/acscatal.2c00533)
“Palladium-Catalyzed Asymmetric [3 + 2] Annulation of Vinylethylene Carbonates with Alkenes Installed on Cyclic N‑Sulfonyl Imines: Highly Enantio- and Diastereoselective Construction of Chiral Tetrahydrofuran Scaffolds Bearing Three Vicinal and Quaternary Stereocenters” Ke, M.; Qiao, B.; Yu, Y.; Li, X.; Xiao, X.; Li, S.-J.; Lan, Y.*; Chen, F.* J. Org. Chem. 2022, 87, 5166-5177. (DOI: 10.1021/acs.joc.1c03157)
“Boryl Radical Activation of Benzylic C−OH Bond: Cross-Electrophile Coupling of Free Alcohols and CO2 via Photoredox Catalysis” Li, W.-D.; Wu, Y.; Li, S.-J.; Jiang, Y.-Q.; Li, Y.-L.; Lan, Y.*; Xia, J.-B.* J. Am. Chem. Soc. 2022, 144, 8551-8559. (DOI: 10.1021/jacs.1c12463)
“Theoretical study on mechanism of cycloaddition reaction between o-alkynylbenzaldoximes and hexynol catalyzed by silver(I)” Yang, X.; Hao, Q.; Li, S.*; Zhu, Y.*; Lan, Y.* Mol. Catal. 2022, 522, 112227. (DOI: 10.1016/j.mcat.2022.112227)
“Regioselectivity of Pd-catalyzed o-carborane arylation: a theoretical view” Liu, J.; Fu, D.; Chen, Z.; Li, T.; Qu, L.-B.; Li, S.-J.*; Zhang, W.*; Lan, Y.* Org. Chem. Front. 2022, 9, 1686-1695. (DOI: 10.1039/d2qo00046f)
“Regiospecific construction of m-alkenyl benzaldehyde from b-bromoenal and vinyl borate” Xin, X.; Liu, Y.; Zhong, L.; Li, Y.; Luo, H.; Liu, L.; Bai, R.; Lan, Y.*; Li, B.* Chem. Commun. 2022, 58, 4989-4992. (DOI: 10.1039/d2cc01441f)
“The Stannum–Ene Reactions of Benzyne and Cyclohexyne with Superb Chemoselectivity for Cyclohexyne” Li, L.; Shan, C.; Shi, J.; Li, W.; Lan, Y.*; Li, Y.* Angew. Chem. Int. Ed. 2022, 61, e202117351. (DOI: 10.1002/anie.202117351)
“Ligand-Controlled Site- and Enantioselective Carbene Insertion into Carbon-Silicon Bonds of Benzosilacyclobutanes” Huo, J.; Zhong, K.; Xue, Y.; Lyu, M.; Ping, Y.; Ouyang, W.; Liu, Z.; Lan, Y.*; Wang, J.* Chem. Eur. J. 2022, 28, e202200191. (DOI: 10.1002/chem.202200191)
“Diradical Generation via Relayed Proton-Coupled Electron Transfer” Shi, Q.; Pei, Z.; Song, J.; Li, S.-J.; Wei, D.*; Coote, M. L.*; Lan, Y.* J. Am. Chem. Soc. 2022, 144, 3137-3145. (DOI: 10.1021/jacs.1c12360)
“Mechanistic Investigation of Cu-Catalyzed Asymmetric Alkynylation of Cyclic N‑Sulfonyl Ketimines with Terminal Alkynes” Zeng, Z.; Yan, F.; Dai, M.; Yu, Z.; Liu, F.; Zhao, Z.; Bai, R.*; Lan, Y.* Organometallics 2022, 41, 270-277. (DOI: 10.1021/acs.organomet.1c00624)
“Mechanistic investigation of zwitterionic MOF-catalyzed enyne annulation using UNLPF-14-MnIII as catalyst” Liu, T.; Duan, R.; Wang, Y.; Li, S.; Qu, L.; Song, J.*; Liu, Q.*; Lan, Y.* Chin. Chem. Lett. 2022, 33, 4281-4286. (DOI: 10.1016/j.cclet.2022.01.041)
“Chemo-, regio- and enantioselective dearomative (3+2) reaction of non-functionalized 1-naphthols” Mei, G.-J.*; Luo, Y.; Koay W. L.; Li, R.; Lan, Y.*; Lu, Y.* Chem Catal. 2022, 2, 386-399. (DOI: 10.1016/j.checat.2021.12.012)
“Deoxygenative Cross-Coupling of Aromatic Amides with Polyfluoroarenes” He, Y.; Wang, Y.; Li, S.-J.; Lan, Y.*; Wang, X.* Angew. Chem. Int. Ed. 2022, 61, e202115497. (DOI: 10.1002/anie.202115497)
“Experimental and Computational Studies on the Directing Ability of Chalcogenoethers in Palladium-Catalyzed Atroposelective C-H Olefination and Allylation” Liao, G.; Zhang, T.; Jin, L.; Wang, B.-J.; Xu, C.-K.; Lan, Y.*; Zhao, Y.*; Shi, B.-F.* Angew. Chem. Int. Ed. 2022, 61, e202115221. (DOI: 10.1002/anie.202115221)
“Carbene-Enabled Ether Activation Through the Formation of Oxonium: A Theoretical View” Wang, Y.-N.; Wang, X.; Li, S.-J.*; Lan, Y.* Org. Chem. Front. 2022, 9, 1247-1253. (DOI: 10.1039/D1QO01730F)
“Chiral Phosphoric Acid Catalyzed Conversion of Epoxides into Thiiranes: Mechanism, Stereochemical Model, and New Catalyst Design” Duan, M.; Díaz-Oviedo, C. D.; Zhou, Y.; Chen, X.; Yu, P.; List, B.*; Houk, K. N.*; Lan, Y.* Angew. Chem. Int. Ed. 2022, 61, e202113204. (DOI: 10.1002/anie.2020113204)
“Is the metal involved or not? A computational study of Cu(I)-catalyzed [4 + 1] annulation of vinyl indole and carbene precursor” He, X.; Zhong, K.; Heng, D.; Zeng, Z.; Ni, H.; Bai, R.*; Lan, Y.* Chin. Chem. Lett. 2022, 33, 2031-2035. (DOI: 10.1016/j.cclet.2021.10.010)
“Insights into Organoamine-Catalyzed Asymmetric Synthesis of Axially Chiral Allenoates Using Morita−Baylis−Hillman Carbonates and Trisubstituted Allenoates: Mechanism and Origin of Stereoselectivity” Zhang, J.; Luo, J.; Li, X.; Zhang, Q.; Wu, Z.; Lan, Y.*; Wei, D.* J. Org. Chem. 2021, 86, 15276-15283. (DOI: 10.1021/acs.joc.1c01871)
“Asymmetric Construction of Tertiary/Secondary Carbon-Phosphorus Bonds via Bifunctional Phosphonium Salt Catalyzed 1,6-Addition” Chen, Y.; Yu, Z.; Jiang, Z.; Tan, J.-P.; Wu, J.-H.; Lan, Y.*; Ren, X.; Wang, T.* ACS Catal. 2021, 11, 14168-14180. (DOI: 10.1021/acscatal.1c03149)
“Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation” Yang, B.; Li, S.-J.; Wang, Y.*; Lan, Y.*; Zhu, S.* Nat. Commun. 2021, 12, 5257. (DOI: 10.1038/s41467-021-25594-4)
“On the Me chanism of Cu Catalyzed Hydroboraethylation of Isocyanates” Huang, L.; Wang, Y.; Liu, J.; Li, S.*; Zang, W.*; Lan, Y.* Chin. J. Org. Chem. 2021, 41, 4347-4352. (DOI: 10.6023/cjoc202107031)
“Visible-light photoredox-catalyzed selective carboxylation of C(sp3)-F bonds with CO2” Yan, S.-S.; Liu, S.-H.; Chen, L.; Bo, Z.-Y.; Jing, K.; Gao, T.-G.; Yu, B.; Lan, Y.*; Luo, S.-P.; Yu, D.-G.* Chem 2021, 7, 3099-3113. (DOI: 10.1016/j.chempr.2021.08.004)
“Practical DMSO-promoted selective hydrolysis–oxidation of lignocellulosic biomass to formic acid attributed to hydrogen bonds” Guo, Y.-J.; Li, S.-J.; Sun, Y.-L.; Wang, L.; Zhang, W.-M.; Zhang, P.; Lan, Y.*; Li, Y.* Green Chem. 2021, 23, 7041-7052. (DOI: 10.1039/D1GC02265B)
“Palladium-Catalyzed Enantioselective Carbene Insertion into Carbon−Silicon Bonds of Silacyclobutanes” Huo, J.; Zhong, K.; Xue, Y.; Lyu, M.; Ping, Y.; Liu, Z.; Lan, Y.*; Wang, J.* J. Am. Chem. Soc. 2021, 143, 12968-12973. (DOI: 10.1021/jacs.1c05879)
“Oxymetalation or oxidative cyclization? mechanism of Pd-catalyzed annulation of enynones” Ni, H.; He, X.; Zhong, K.; Chen, H.; Lai, W.; Zhao, Z.; Zeng, Z.; Bai, R.*; Lan, Y.* Chem. Commun. 2021, 57, 8316-8319. (DOI: 10.1039/d1cc02744a)
“Dehydrogenative 6π heterocyclization under visible light irradiation and mechanistic insights” Zhang, Z.; Chen, H.; Keller, N.; Xiong, Q.; Liu, L.; Lan, Y.*; Bein, T.*; Li, J.* Org. Chem. Front. 2021, 8, 3788-3795. (DOI: 10.1039/d1qo00356a)
“Benzyne 1,2,4-Trisubstitution and Dearomative 1,2,4-Trifunctionalization” Shi, J.; Li, L.; Shan, C.; Chen, Z.; Dai, L.; Tan, M.; Lan, Y.*; Li, Y.* J. Am. Chem. Soc. 2021, 143, 10530-10536. (DOI: 10.1021/jacs.1c04389)
“Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations” Qi, X.*; Lan, Y.* Acc. Chem. Res. 2021, 54, 2905-2915. (DOI: 10.1021/acs.accounts.1c00075)
“Rhodium(II)-Catalyzed Regioselective Remote C−H Alkylation of Protic Indoles” Kong, L.; Han, X.; Chen, H.; Sun, H.; Lan, Y.*; Li, X.* ACS Catal. 2021, 11, 4929-4935. (DOI: 10.1021/acscatal.1c01052)
“C(sp2)−X (X = Cl, Br, and I) Reductive Eliminations from Well-Defined Gold(III) Complexes: Concerted or Dissociation Pathways?” Kang, K.; Liu, S.; Xu, C.; Lu, Z.; Liu, S.; Leng, X.; Lan, Y.*; Shen ,Q.* Organometallics 2021, 40, 2231-2239. (DOI: 10.1021/acs.organomet.0c00784)
“C(sp2)‑CF3 Reductive Elimination from Well-Defined Argentate(III) Complexes [nBu4N][Ag(Ar)(CF3)3]” Lu, Z.; Liu, S.; Lan, Y.*; Leng, X.; Shen, Q.* Organometallics 2021, 40, 1713-1718. (DOI: 10.1021/acs.organomet.1c00195)
“Photoredox Catalysis Unlocks the Nickel-Catalyzed Cyanation of Aryl Halides under Benign Conditions” Jia, Y.; Liu, Y.-Y.; Lu, L.-Q.; Liu, S.-H.; Zhou, H.-B.; Lan, Y.*; Xiao, W.-J.* CCS Chem. 2021, 3, 2032-2041. (DOI: 10.31635/ccschem.021.202100934)
“Atom Recombination of Difluorocarbene Enables 3-Fluorinated Oxindoles from 2-Aminoarylketones” Zhang, G.; Shi, Q.; Hou, M.; Yang, K.; Wang, S.; Wang, S.; Li, W.; Li, C.; Qiu, J.; Xu, H.; Zhou, L.; Wang, C.; Li, S.-J.; Lan, Y.*; Song, Q.* CCS Chem. 2021, 3, 1613-1621. (DOI: 10.31635/ccschem.021.202100979)
“Mechanistic studies on nickel-catalyzed enantioselective [3 + 2] annulation for γ-butenolide synthesis via C-C activation of diarylcyclopropenones” Bai, D.*; Liu, S.; Chen, J.; Yu, Y.; Wang, M.; Chang, J.; Lan, Y.*; Li, X.* Org. Chem. Front. 2021, 8, 3023-3031. (DOI: 10.1039/D1QO00322D)
“Tuning the reactivity of alkoxyl radicals from 1,5-hydrogen atom transfer to 1,2-silyl transfer” Yang, Z.; Niu, Y.; He, X.; Chen, S.; Liu, S.; Li, Z.; Chen, X.; Zhang, Y.; Lan, Y.*; Shen, X.* Nat. Commun. 2021, 12, 2131. (DOI: 10.1038/s41467-021-22382-y)
“Biomimetic Carbene Cascades Enabled Imine Derivative Migration from Carbene-Bearing Thiocarbamates” Li, X.; Chen, H.; Xuan, Q.; Ma, S.; Lan, Y.*; Song, Q.* Org. Lett. 2021, 23, 3518-3523. (DOI: 10.1021/acs.orglett.1c00930)
“Oxidation of Pd(II) with disilane in a palladium-catalyzed disilylation of aryl halides: a theoretical view” Zhang, J.; Liu, S.; Zhang, T.; Liu, T.*; Lan, Y.* Dalton Trans. 2021, 49, 7656-7666. (DOI: 10.1039/d1dt00399b)
“Metal-free C(sp3)–H functionalization of sulfonamides via strain-release rearrangement” Hu, J.*; Yang, X.; Shi, S.; Cheng, B.; Luo, X.*; Lan, Y.*; Loh, T.-P.* Chem. Sci. 2021, 12, 4034-4340. (DOI: 10.1039/d0sc06603f)
“Theoretical Model for N‑Heterocyclic Carbene-Catalyzed Desymmetrizing [4 + 1] and [4 + 2] Annulations of an Enal and Aryldialdehyde with 1,3-Cyclopentenedione” Wang, X.; Li, S.-J.; Wang, Y.-N.; Wei, D.*; Lan, Y.* Org. Lett. 2021, 23, 2421-2425. (DOI: 10.1021/acs.orglett.1c00270)
“Insights into the chiral sulfide/selenide-catalyzed electrophilic carbothiolation of alkynes: mechanism and origin of axial chirality” Zhang, Q.-Y.; Li, S.-J.; Wang, Y.; Song, J.; Lan, Y.*; Wei, D.* Org. Chem. Front. 2021, 8, 1983-1990. (DOI: 10.1039/d1qo00036e)
“Ligand coordination- and dissociation induced divergent allylic alkylations using alkynes” Huang, Y.; Ma, C.; Liu, S.; Yang, L.-C.; Lan, Y.*; Zhao, Y.* Chem 2021, 7, 812-826. (DOI: 10.1016/j.chempr.2021.02.018)
“On the mechanism of homogeneous Pt-catalysis: A theoretical view” Chen, H.; Li, Y.*; Liu, S.*; Xiong, Q.; Bai, R.; Wei, D.*; Lan, Y.* Coor. Chem. Rev. 2021, 437, 213863. (DOI: 10.1016/j.ccr.2021.213863)
“Synergistic Dinuclear Rhodium Induced Rhodium-Walking Enabling Alkene Terminal Arylation: A Theoretical Study” Heng, D.; Chen, H.; He, X.; Liu, S.; Zhu, L.; Zhong, K.; Zhang, T.; Bai, R.*; Lan, Y.* ACS Catal. 2021, 11, 3975-3987. (DOI: 10.1021/acscatal.0c05554)
“Desymmetrization of 1,3-Diones by Catalytic Enantioselective Condensation with Hydrazine” Yang, B.; Dai, J.; Luo, Y.; Lau, K. K.; Lan, Y.*; Shao, Z.*; Zhao, Y.* J. Am. Chem. Soc. 2021, 143, 4179-4186. (DOI: 10.1021/jacs.1c01366)
“Multiple Functional Organocatalyst-Promoted Inert C–C Activation: Mechanism and Origin of Selectivities” Zhang, M.; Wang, Y.; Li, S.-J.; Wang, X.; Shi, Q.; Li, X.; Qu, L.-B.; Wei, D.*; Lan, Y.* ACS Catal. 2021, 11, 3443-3454. (DOI: 10.1021/acscatal.0c05511)
“How Solvents Control the Chemoselectivity in Rh-Catalyzed Defluorinated [4 + 1] Annulation” Liu, S.; Zhu, L.; Zhang, T.; Zhong, K.; Li, S.-J.; Bai, R.*; Lan, Y.* Org. Lett. 2021, 23, 1489-1494. (DOI: 10.1021/acs.orglett.1c00223)
“Catalytic Atroposelective Catellani Reaction Enables to Construct Axially Chiral Biaryl Monophosphine Oxides” Feng, Q.; Ma, X.; Bao, W.; Li, S.-J.; Lan, Y.*; Song, Q.* CCS Chem. 2021, 3, 377-387. (DOI: 10.31635/ccschem.021.202000725)
“Aryne 1,2,3,5-Tetrasubstitution Enabled by 3‑Silylaryne and Allyl Sulfoxide via an Aromatic 1,3-Silyl Migration” Shi, J.; Li, L.; Shan, C.; Wang, J.; Chen, Z.; Gu, R.; He, J.; Tan, M.; Lan, Y.*; Li, Y.* J. Am. Chem. Soc. 2021, 143, 2178-2184. (DOI: 10.1021/jacs.0c11119)
“Lewis acid–catalyzed domino generation/[2,3]-sigmatropic rearrangement of ammonium ylidesto access chiral azabicycles” Xi, S.; Dong, J.; Chen, H.; Dong, Q.; Yang, J.; Tan, Q.; Zhang, C.; Lan, Y.*; Zhang, M.* Sci. Adv. 2021, 7, eabd5290. (DOI: 10.1126/sciadv.abd5290)
“Rhodium-Catalyzed Atroposelective Construction of Indoles via C-H Bond Activation” Sun, L.; Chen, H.; Liu, B.; Chang, J.; Kong, L.; Wang, F.*; Lan, Y.*; Li, X.* Angew. Chem. Int. Ed. 2021, 60, 8391-8395. (DOI: 10.1002/anie.202012932)
“Predicting the origin of selectivity in NHCcatalyzed ring opening of formylcyclopropane: a theoretical investigation” Wang, Y.; Qiao, Y.; Lan, Y.*; Wei, D.* Catal. Sci. Tech. 2021, 11, 332-337. (DOI: 10.1039/d0cy01768j)
“Is the reaction sequence in phosphine-catalyzed [8+2] cycloaddition controlled by electrophilicity?” Lin, W.-X.; Pei, Z.; Gong, C.; Mo, H.; Yang, K.; Qu, L.-B.; Wei, D.; Song, J.-S.*; Li, S.-J.*; Lan, Y.* Chem. Commun. 2021, 57, 761-764. (DOI: 10.1039/d0cc07370a)
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