当前位置: X-MOL首页全球导师 国内导师 › 张所波

研究领域

1. 有机合成化学  有机合成是药物、精细化学品、功能材料制备的基本手段。精细有机合成、原子经济型反应、高效催化、过程控制、绿色分离技术是我们重点发展的研究领域。主要针对具有典型代表性及污染严重的重要基本有机化学品和精细化学品的合成,开展离子液体和环境友好催化方面的基础和应用基础研究。运用离子液体技术、过渡金属催化等,研究制备高附加值的合成药物、功能分子及材料等高技术产品。  离子液体是一种完全由离子组成的离子性溶剂,由于其特殊的化学、物理性能,近几年来在催化化学、分离科学、材料化学领域得到了广泛的关注。我们首次从简单、廉价的化工原料出发设计、合成了一系列新型胍盐离子液体。并且,成功的把新型胍盐离子液体应用在了两相催化、纳米金属催化、二氧化碳的化学固定等方面。  离子液体具有与传统分子溶剂完全不同的结构特点,这决定了其具有很多独特的溶解特性。一定结构的基于咪唑盐的氯负离子离子液体具有强烈的破坏氢键的能力。纤维素、蚕丝纤维、羊毛纤维、壳聚糖、甲壳素等是大量存在于自然界的生物可再生大分子资源。充分利用这些资源来缓解对石油资源的需求压力,这方面一直都是绿色化学、材料化学、催化化学领域研究的热点。由于它们特殊、复杂的结构特点,不能溶于一般的普通分子溶剂,传统的溶解加工过程中涉及到大量酸、无机盐、有毒、昂贵溶剂的使用,这很大程度上制约了这些资源的利用。我们成功的为这些生物资源开发了一个基于离子液体为溶剂的简单的、环境友好的加工平台。基于此平台,可以制备各种功能性复合生物降解、保健纤维、膜材料等。

近期论文

查看导师新发文章 (温馨提示:请注意重名现象,建议点开原文通过作者单位确认)

Shenghai Li, Junhua Wang, Yongli Kou, Suobo Zhang*, ""Ionic-Liquid-Grafted Rigid Poly (p-Phenylene) Microspheres: Efficient Heterogeneous Media for Metal Scavenging and Catalysis"". Chemistry-A European Journal 2010, 16(6), 1812 Qiang Zhang, Shenghai Li, Suobo Zhang*, ""A novel guanidinium grafted poly(aryl ether sulfone) for high-performance hydroxide exchange membranes"". Chemical Communications 2010, 46(40), 7495 Junhua Wang, Shenghai Li, Suobo Zhang*, ""Novel Hydroxide-Conducting Polyelectrolyte Composed of an Poly(arylene ether sulfone) Containing Pendant Quaternary Guanidinium Groups for Alkaline Fuel Cell Applications"". Macromolecules 2010, 43(8), 3890 Shenghai Li, Yuntao Wu, Junhua Wang, Qiang Zhang, Yongli Kou, Suobo Zhang*, ""Double-responsive polyampholyte as a nanoparticle stabilizer: application to reversible dispersion of gold nanoparticles"". Journal of Materials Chemistry 2010, 20(21), 4379 Qiang Zhang, Qifeng Zhang, Junhua Wang, Suobo Zhang*, Shenghai Li, ""Synthesis and alkaline stability of novel cardo poly(aryl ether sulfone)s with pendent quaternary ammonium aliphatic side chains for anion exchange membranes"". Polymer 2010, 51,5406 Qiang Zhang, Qifeng Zhang, Suobo Zhang*, Shenghai Li, ""Synthesis and characterization of sulfonated poly(aryl ether sulfone) containing pendent quaternary ammonium groups for proton exchange membranes"". Journal of Membrane Science 2010, 354(1-2), 23 Haifeng Wang, Lei Li, Xiaosa Zhang, Suobo Zhang*, ""Polyamide thin-film composite membranes prepared from a novel triamine 3,5-diamino-N-(4-aminophenyl)-benzamide monomer and m-phenylenediamine"". Journal of Membrane Science 2010, 353(1-2), 78 Qifeng Zhang, Suobo Zhang*, Lei Dai, Xuesi Chen, ""Novel zwitterionic poly(arylene ether sulfone)s as antifouling membrane material"". Journal of Membrane Science 2010, 349(1-2), 217 Feng Zhang, Nanwen Li, Suobo Zhang*, Shenghai Li, ""Ionomers based on multisulfonated perylene dianhydride: Synthesis and properties of water resistant sulfonated polyimides"", Journal of Power Sources 2010, 195(8), 2159 Feng Zhang, Nanwen Li, Suobo Zhang*, ""Preparation and Characterization of Sulfonated Poly(arylene-co-naphthalimide)s for Use as Proton Exchange Membranes"". Journal of Applied Polymer Science 2010, 118(6), 3187 Junhua Wang, Zhuo Zhao, Feixiang Gong, Shenghai Li, Suobo Zhang*, ""Synthesis of Soluble Poly(arylene ether sulfone) Ionomers with Pendant Quaternary Ammonium Groups for Anion Exchange Membranes"". Macromolecules 2009, 42(22), 8711 Feixiang Gong, Nanwen Li, Suobo Zhang*, ""Synthesis and properties of novel sulfonated poly(phenylquinoxaline)s as proton exchange membranes"". Polymer 2009, 50(25), 6001 Nanwen Li, Jia Liu, Zhiming Cui, Suobo Zhang*, Wei Xing, ""Novel hydrophilic-hydrophobic multiblock copolyimides as proton exchange membranes: Enhancing the proton conductivity"". Polymer 2009, 50(19), 4505 Nanwen Li, Feng Zhang, Junhua Wang, Shenghai Li, Suobo Zhang*, ""Dispersions of carbon nanotubes in sulfonated poly[bis (benzimidazobenzisoquinolinones)] and their proton-conducting composite membranes"". Polymer 2009, 50(15), 3600 Junhua Wang, Nanwen Li, Feng Zhang, Suobo Zhang*, Jia Liu, ""Synthesis and properties of soluble poly[bis (benzimidazobenzisoquinolinones)] based on novel aromatic tetraamine monomers"". Polymer 2009, 50(3), 810 Junhua Wang, Nanwen Li, Suobo Zhang*, Zhiming Cui, ""Blends based on sulfonated poly[bis(benzimidazobenzisoquinolinones)] and poly(vinylidene fluoride) for polymer electrolyte membrane fuel cell"". Journal of Membrane Science 2009, 341(1-2), 155

推荐链接
down
wechat
bug