个人简介
1982-1986:长春应化所,研究实习员 1992-1993:日本富士胶片公司,特别研究员 1993-1994:长春应化所,副研究员 1994- : 长春应化所,研究员
研究领域
聚酰亚胺合成与应用开发,不对称合成,药物合成
承担科研项目情况:
含联萘基旋光性聚合物合成与性能(1994-1996,基金委面上); 聚喹啉的合成与性能研究(2000-2002,基金委面上); 异构聚酰亚胺基体树脂及其与增强剂的界面特性(2004-2007,基金委重点); 替代含石棉密封和摩擦材料及填料的系列产品开发及产业化(2006-2009,科技部支撑计划); 炭纤维复合材料(2004-2007,院方向性项目(子课题)); 聚酰亚胺半金属轿车刹车片的研制(2002-2005,省科技厅); 直接法合成聚酰亚胺(2001-2003,省科技厅); 聚酰亚胺纤维研制(2003-2005,省科技厅); 精细化学品合成与合成方法学(1995-2008,国际合作)
近期论文
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1. Polyimides from 3,3’-Dioxo-[1,1’]-spirodiphthalan- 5,5’,6,6’-tetracarboxylic Dianhydride Han FS, Ding MX, Gao LX, Polymer, 40 (13), 3809-3813 Hou SF, Ding MX, Gao LX, Macromolecules, 36 (11), 3826-3832 2003 2. Syntheses of Biphenyl Polyimides via Nickel-catalyzed Coupling Polymerization of Bis(chlorophthalimide)s Gao CL, Zhang SB, Ding MX, Gao LX, et al., Macromolecules, 36(15), 5559-5565 2003 3. Enantioselective Iodolactonization Catalyzed by Chiral Quaternary Ammonium Salts Derived from Cinchonidine Wang M, Gao LX, Mai WP, et al., Journal of Organic Chemistry, 69(8), 2874-2876, 2004 4. Syntheses and Properties of Soluble Biphenyl-based Polyimides from Asymmetric Bis(chlorophthalimide)s Gao CL, Wu X, Lv GH, Gao LX, et al., Macromolecules, 37(8), 2754-2761, 2004 5. Imidazolium Ionic Liquid-grafted 2,2'-Bipyridine-A Novel Ligand for the Recyclable Copper-catalyzed Selective Oxidation of Alcohols in Ionic Liquid [bmim][PF6] Wu XE, Ma L, Ding MX, Gao LX, et al., Chemistry Letters, 34(3), 312-313, 2005 6. TEMPO-derived Task-specific Ionic Liquids for Oxidation of Alcohols Wu XE, Ma L, Ding MX, Gao LX, et al., Synlett, (4), 607-610, 2005 7. Synthesis of New Bis-BINOLs Linked by a 2,2'-Bipyridine Bridge Bai XL, Liu XD, Wang M, Gao LX, et al., Synthesis, (3), 458-464, 2005 8. Chiral C-2-symmetric Ligands Containing Two Binaphthyl Units Linked by 2,2'-Bipyridyl Bridge in Asymmetric Catalysis Bai XL, Kang CQ, Liu XD, Gao LX, et al., Tetrahedron Asymmetry, 16(3), 727-731, 2005 9. The Natural Alkaloid Isoanabasine: Synthesis from 2,3'-Bipyridine, Efficient Resolution with BINOL, and Assignment of Absolute Configuration by Mosher's Method Kang CQ, Cheng YQ, Guo HQ, Gao LX, et al., Tetrahedron Asymmetry, 16(12), 2141-2147, 2005 10. PEG-supported Dipyridyl Ligand for Palladium-catalyzed Suzuki and Suzuki-type Reactions in PEG and Aqueous Media Mai WP, Gao LX, SYNLETT (16), 2553-2558, 2006 11. Synthesis and Characterization of Novel Sulfonated Polyimides from 1,4-Bis(4-aminophenoxy)-naphthyl-2,7-disulfonic Acid Yuhan Li, Rizhe Jin, Zhiming Cui, Zhen Wang, Wei Xing, Xuepeng Qiu, Xiangling Ji and Lianxun Gao, Polymer, 48(8), 2280-2287, 2007 12. Studies on Syntheses and Properties of Novel CeO2/Polyimide Nanocomposite Films from Ce(Phen)3 Complex Zhenping Shang, Changli Lü, Xiaodan Lü and Lianxun Gao Polymer, 48(14), 4041-4046, 2007 13. One-pot Synthesis of Polyimides via Ni-catalyzed Coupling of Bis(chlorophthalimide)s Zhenping Shang, Changlu Gao, Zhen Wang, Mengxian Ding and Lianxun Gao, European Polymer Journal, 43(5), 2135-2140, 2007 任现职以来共申请专利10余项。 中国专利:00128254.9 聚酰亚胺基体树脂溶液的制备方法 丁孟贤,高昌录,张所波,高连勋 中国专利:01110204.7 氯代苯酐及氯代邻苯二甲酸粗产物的精馏前处理方法 丁孟贤,高连勋,张 劲 中国专利:01129547.3 聚酰亚胺水解回收方法 丁孟贤,高连勋,张 劲 中国专利:02104269.1 双氯酞酰亚胺与二氯二苯酮或二氯二苯砜共聚物的制备方法 丁孟贤,高昌录,张所波,高连勋 中国专利:02123897.9 联苯型聚酰亚胺的制备方法 张所波,高昌录,丁孟贤,高连勋 中国专利:02148860.6 电化学制备联苯四甲酸二酐及其衍生物 高连勋,吴雪娥,丁孟贤,高昌录 中国专利:03105026.3 2,3,3’,4’-联苯四酸二酐及其衍生物的制备方法 王震,吴雪娥,高昌录,丁孟贤,高连勋 中国专利:200310115829.8 4-苯乙炔苯酐的制备方法 王震,高连勋,丁孟贤 中国专利:200410010703.9由双氯酞酰亚胺与双酚制备聚醚酰亚胺的方法 高昌录,丁孟贤,高连勋 中国专利:20041001900.0双酚二盐的制备方法 高昌录,丁孟贤,高连勋 中国专利:200410011205.6磺化聚酰亚胺质子传输膜的合成方法 王震,邓鹏飏,刘长鹏,高连勋