郭勇 - 中国科学院上海有机化学研究所

研究领域

1) 碳氟键断裂的抑控在有机合成中的应用； 2) 氟氯烷烃等含氟工业品的资源升级； 3) β-四氟磺内酯衍生物的相关化学研究。

近期论文

查看导师新发文章（温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

Lu, X.-Q.; Guo, Y.; Chen, Q.-Y. “Efficient Synthesis of meso-meso Linked Diporphyrins by Ni(0)-mediated Ullmann Homocoupling,” Synlett, 2011, 77-80. DOI: 10.1055/s-0030-1259101 Wang, W; Chen, Q.-Y.; Guo, Y. “TiCl4-Promoted Mukaiyama Aldol Reaction of Fluorinated Silyl Enolates for the Construction of a Quaternary Carbon Center,” Synlett, 2011, 2705-2708. DOI: 10.1055/s-0031-1289535 Guo, C.; Wang R.-W.; Guo, Y.; Qing, F.-L. “Palladium-catalyzed direct α-arylation of α-fluoroketones: A straightforward route to α-fluoro-α-arylketones,”Journal of Fluorine Chemistry, 2012, 133, 86-96. DOI:10.1016/j.jfluchem.2011.08.004 Hu, H.; Huang, Y.; Guo, Y. “Henry reaction of fluorinated nitro compounds,”Journal of Fluorine Chemistry, 2012, 133, 108-114.DOI:10.1016/j.jfluchem.2011.09.004 Huan, F.; Hu, H.; Huang, Y.; Chen, Q.-Y.; Guo, Y. “Michael addition reaction of fluorinated nitro compounds,” Chin. J. Chem., 2012, 30, 798-802. DOI: 10.1002/cjoc.201100412 Wang, Q.; Chen, Q.-Y.; Yang, X.; Guo, Y. “[RuH2(PPh3)4]-catalyzed Michael addition reaction of α-fluoronitroalkanes,” Synthesis, 2012, 3815-3821. DOI: 10.1055/s-0032-1317526 Zhang, C.-P.; Chen, Q.-Y.; Guo, Y.; Xiao, J.-C.; Gu Y.-C. “Progress in fluoroalkylation of organic compounds via sulfinatodehalogenation initiation system,” Chem. Soc. Rev., 2012, 41, 4536-4559. DOI: 10.1039/C2CS15352A Li, L.; Huang, D.; Chen, Q.-Y.; Guo, Y. “Pd-Catalyzed Allylic Alkylation of CF3-Containing Esters with Three Electron-Withdrawing Groups, ” Synlett, 2013, 24, 611-614. DOI: 10.1055/s-0032-1318313 Chen, J.; Li, K.-L.; Guo, Y.; Guo, C.-C., Chen, Q.-Y. “Design and Synthesis ofβ-Multi-Substituted Push-Pull Porphyrins,” RSC Advances, 2013, 3, 8227-8231. DOI: 10.1039/c3ra40308d Xiao, Z.; Hu, H.; Ma, J.; Chen, Q.; Guo Y. “Radical Addition of Perfluoroalkyl Iodides to Alkenes and Alkynes Initiated by Sodium Dithionite in an Aqueous Solution in the Presence of a Novel Fluorosurfactant,” Chin. J. Chem. 2013, 31, 939-944. DOI: 10.1002/cjoc.201300433 Zheng, J.; Cai, J.; Lin, J.-H.; Guo Y.; Xiao J.-C. “Synthesis and decarboxylative Wittig reaction of difluoromethylene phosphobetaine,” Chem. Commun., 2013, 49, 7513-7515. DOI: 10.1039/c3cc44271c Li, L.; Chen, Q.-Y.; Guo, Y. “Allylic C-H alkylation with a CF3-containing nucleophile,” Chem. Commun. 2013,49,8764-8766. DOI: 10.1039/C3CC43120G Wang, Q.; Huan, F.; Shen, H., Xiao, J.-C.; Gao, M.; Yang, X.; Murahashi, S.-I.; Chen, Q.-Y.; Guo, Y. “Organocatalytic Reactions of α-Trifluoromethylated Esters with Terminal Alkenes at Room Temperature,” J. Org. Chem. 2013, 78, 12525-12531.DOI: 10.1021/jo402212j Zhang, C.-P.; Chen, Q.-Y.; Guo, Y.; Xiao, J.-C. “Bi-Functional Fluoroalkylation Reagents: An introduction to Halo-substituted 3-Oxa-Perfluoroalkanesulfonyl Fluorides,” Tetrahedron 2013, 69, 10955-10989. DOI:10.1016/j.tet.2013.10.058 Zhang, C.-P.; Chen, Q.-Y.; Guo, Y.; Xiao, J.-C.; Gu, Y.-C. “Difluoromethylation and trifluoromethylation reagents derived from tetrafluoroethane β-sultone: Synthesis, reactivity and applications,” Coord. Chem. Rev. 2014, 261, 28–72.DOI:10.1016/j.ccr.2013.11.010 Li, L.; Chen, Q.-Y.; Guo, Y. “Synthesis of α‑Trifluoromethyl Ketones via the Cu-Catalyzed Trifluoromethylation of Silyl Enol Ethers Using an Electrophilic Trifluoromethylating Agent”, J. Org. Chem. 2014, 79, 5145-5152. DOI:10.1021/jo500713f Li, L.; Chen, Q.-Y.; Guo, Y. “Synthesis of α-CF3 ketones from alkenes and electrophilic trifluoromethylating reagents by visible-light driven photoredox catalysis,” J. Fluorine Chem. 2014, 167, 79-83. DOI: 10.1016/j.jfluchem.2014.05.013. Wang, W.; Shen, H.; Wan, X.-L.; Chen, Q.-Y.; Guo, Y. “Enantioselective Pd-catalyzed Allylation of Acyclic α-Fluorinated Ketones,” J. Org. Chem. 2014, 79, 6347-6353. DOI: 10.1021/jo500923u Zhao, S.; Liu, C.; Guo, Y.; Xiao, J.-C.; Chen, Q.-Y. “β-Perfluoroalkylated meso-Aryl-Substituted Subporphyrins: Synthesis and Properties,” Synthesis 2014, 46, 1674-1688. DOI: 10.1055/s-0033-1341055 Zhao, S.; Liu, C.; Guo, Y.; Xiao, J.-C.; Chen, Q.-Y. “Oxidative Coupling of Benzylamines to Imines by Molecular Oxygen Catalyzed by Cobalt(II) β‑Tetrakis(trifluoromethyl)-mesotetraphenylporphyrin,” J. Org. Chem. 2014, 79, 8926-8931. DOI: 10.1021/jo5017212 Jiang, D.-F.; Liu, C.; Guo, Y.; Xiao, J.-C.; Chen, Q.-Y. “A General, Regiospecific Synthetic Route to Perfluoroalkylated Arenes via Arenediazonium Salts with RFCu(CH3CN) Complexes,” Eur. J. Org. Chem. 2014, 6303-6309. DOI: 10.1002/ejoc.201402820 Wang, W.; Huan, F.; Sun, Y.; Fang, J.; Liu, X.-Y.; Chen, Q.-Y.; Guo, Y. “Palladium-Catalyzed Allylation of Trifluoromethylated Ketene Aminoacetals,” J. Fluorine Chem. in press. DOI: 10.1016/j.jfluchem.2014.10.002