陈庆云 - 中国科学院上海有机化学研究所

研究领域

陈庆云同志四十余年来主要从事有机氟化学的研究，参加或领导了含氟单体、含氟润滑油、含氟表面活性剂和新型致冷物质等以及氟材料的研制。从事全氟磺酸及其衍生物、二氟卡宾、三氟甲基化和单电子转移反应等大量基础研究。为我国有机氟材料的开发和有机氟化学基础理论的发展作出了突出贡献，是国际知名有机氟化学家，至今已发表科研论文150 余篇。

近期论文

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N-Substitution Reactions of 20-π-Electron β-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin Xiao-Guang Chen; Chao Liu; Dong-Mei Shen; Qing-Yun Chen, Synthesis, 2009, 22, 3860-3868. DOI: 10.1055/s-0029-1217012 https://www.thieme-connect.de/ejournals/html/10.1055/s-0029-1217012 Partial Bromination and Fluoroalkylation of 5,10,15-Tris(pentafluorophenyl)corrole Ruo-Bing Du; Chao Liu; Dong-Mei Shen; Qing-Yun Chen, Synlett, 2009, 16, 2701-2705. DOI: 10.1055/s-0029-1217955 https://www.thieme-connect.de/ejournals/html/10.1055/s-0029-1217955?update=true Efficient One-Pot Regioselective Synthesis of 2,3-Dibromo-5,10,15,20-tetraarylporphyrins from 5,10,15,20-Tetraarylchlorins Ke-Lai Li; Can-Cheng Guo; Qing-Yun Chen, Synlett, 2009, 17, 2867-2871. DOI: 10.1055/s-0029-1217969 https://www.thieme-connect.de/ejournals/html/10.1055/s-0029-1217969 Unprecedented Degradation of Nickel(II) 2,3,12,13-Tetrabromo-5,10,15,20-tetraarylporphyrins by the Anion of E-Benzaldoxime: A Novel Approach to Nickel(II) Chlorophins and Bacteriophins Ke-Lai Li; Can-Cheng Guo; Qing-Yun Chen, Org. Lett., 2009, 11 (13), 2724–2727. DOI: 10.1021/ol901052w http://pubs.acs.org/doi/abs/10.1021/ol901052w?source=chemport meso-Oxidation of Porphyrins: Convenient Iron(III)-Mediated Synthesis of Dioxoporphyrins Dong-Mei Shen; Chao Liu; Xiao-Guang Chen; Qing-Yun Chen, Synlett, 2009, 6, 945-948. DOI: 10.1055/s-0028-1088212 https://www.thieme-connect.de/ejournals/abstract/10.1055/s-0028-1088212 Regioselective Syntheses of 2- and 4-Formylpyrido[2,1-b]benzoxazoles Ke-Lai Li; Zong-Bo Du; Can-Cheng Guo; Qing-Yun Chen, J. Org. Chem., 2009, 74 (9), 3286–3292. DOI: 10.1021/jo900267c http://pubs.acs.org/doi/abs/10.1021/jo900267c?source=chemport Facile and Efficient Hypervalent Iodine(III)-Mediated meso-Functionalization of Porphyrins Dong-Mei Shen; Chao Liu; Xiao-Guang Chen; Qing-Yun Chen, J. Org. Chem., 2009, 74 (1), 206–211. DOI: 10.1021/jo801855d http://pubs.acs.org/doi/abs/10.1021/jo801855d?source=chemport Magnesium iodide promoted defluorinative reactions of 2,2-difluorocyclopropyl aryl ketones with aryl imines: A new, general synthesis of 2-alkylideneazetidinesWei Xu; Ion Ghiviriga; Qing-Yun Chen; William R. Dolbier, Journal of Fluorine Chemistry,2010, 131(9), 958-963. DOI: 10.1016/j.jfluchem.2010.06.021 http://www.sciencedirect.com/science/article/pii/S0022113910001764 New, Convenient Route for Trifluoromethylation of Steroidal Molecules Xiang-Shu Fei; Wei-Sheng Tian; Kai Ding; Yun Wang; Qing-Yun Chen, Org. Lett., 2010, 87, 126-136. DOI: 10.1002/0471264229.os087.14 http://onlinelibrary.wiley.com/doi/10.1002/0471264229.os087.14/full Efficient Synthesis of meso-meso-Linked Diporphyrins by Nickel(0)-Mediated Ullmann Homocoupling Xiu-Qiang Lu; Yong Guo; Qing-Yun Chen, Synlett, 2011, 1, 77-80. DOI: 10.1055/s-0030-1259101 https://www.thieme-connect.de/ejournals/html/10.1055/s-0030-1259101 Copper-Mediated Radical Cross-Coupling Reaction of 2,2-Dichloro-1,1,1-trifluoroethane (HCFC-123) with Phenols or Thiophenols Xiao-Jun Tang; Qing-Yun Chen, Org. Lett., 2012, 14 (24), 6214–6217. DOI: 10.1021/ol302962p http://pubs.acs.org/doi/abs/10.1021/ol302962p?source=chemport#cor1 Ni(0) or Cu(0) catalyzed cleavage of the unactivated C–Cl bond of 2-chloro-1,1,1-trifluoroethane (HCFC-133a) via a single electron transfer (SET) process Xiao-Jun Tang; Qing-Yun Chen, Chem. Sci., 2012, 3, 1694-1697. DOI: 10.1039/C2SC01083F http://pubs.rsc.org/en/content/articlehtml/2012/SC/C2SC01083F Rational and practical synthesis of α,α-difluoro-γ-lactams Bin-Hui Li; Ke-Lai Li; Qing-Yun Chen, Journal of Fluorine Chemistry,2012, 133, 163-166. DOI: 10.1016/j.jfluchem.2011.10.013 http://www.sciencedirect.com/science/article/pii/S0022113911003848 Design and synthesis of β-multi-substituted push–pull porphyrins Jing Chen; Ke-Lai Li; Yong Guo; Chao Liu; Can-Cheng Guo; Qing-Yun Chen, RSC Adv., 2013, 3, 8227-8231. DOI: 10.1039/C3RA40308D http://pubs.rsc.org/en/Content/ArticleLanding/2013/RA/c3ra40308d#!divAbstract"