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个人简介

1988年9月─1992年7月 湖南师范大学化学系,理学学士 1992年7月─1997年7月 湖南省邵阳师范高等专科学校,讲师 1997年8月─2000年7月 上海化工研究院,硕士 2000年8月─2003年7月 中科院上海有机所,理学博士 2003年8月─2005年7月 美国University of Idaho,博士后 2005年9月─ 中科院上海有机所,研究员,博士生导师

研究领域

含氟有机盐 发展新的有机盐及其合成方法,研究其催化、反应性能以及理化特性;发展新的氟化试剂,发现新的氟化反应;探索有机盐在电解质、光学材料等领域的应用 熔盐化学 研究金属氟化物的合成以及相应熔盐的制备,探索氟化盐及熔盐中杂质的存在形式与迁移规律,发展氟化熔盐的纯化方法 稀土萃取 探索稀土金属离子的结构化学特征和配位化学反应规律,阐明稀土萃取剂的分子结构与萃取性能之间的关系,发展碳磷键的合成方法学 高张力含氟小分子 通过考察含氟卡宾与双键、叁键的反应,探索高张力含氟小分子的合成与反应性能,发展有机氟化物的合成方法学 含氟卟啉化学 研究含氟卟啉的合成与反应规律,探索其在催化和材料方面的应用

近期论文

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Xiao-Yun Deng , Jin-Hong Lin , Ji-Chang Xiao , One-pot synthesis of gem-difluorostyrenes from benzyl bromide via olefination of phosphonium ylide with difluorocarbene , Journal of Fluorine Chemistry , Available online 11 June 2015 , DOI: 10.1016/j.jfluchem.2015.06.009 Xiao-Yun Deng , Jin-Hong Lin , Jian Zheng and Ji-Chang Xiao , Difluoromethylation and gem-difluorocyclopropenation with difluorocarbene generated by decarboxylation , Chem. Commun , 2015 , 51(42) , 8805-8808 , DOI: 10.1039/c5cc02736e Jian Zheng , Jin-Hong Lin , Xiao-Yun Deng and Ji-Chang Xiao , 1,8-Diazabicyclo[5.4.0] undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation , Organic Letters , 2015 , 17(3) , 532-535 , DOI: 10.1021/ol503548s Yaya Duan , Bin Zhou , Jin-Hong Lin , Ji-Chang Xiao , Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation Chem. Commun , 2015 , 51(66) ,13127-13130 ,DOI: 10.1039/c5cc04991a Wang Shi-Meng , Han Jia-Bin , Zhang Cheng-Pan , Qin Hua-Li , Xiao Ji-Chang , An overview of reductive trifluoromethylatio reactions using electrophilic ‘+CF3’ reagents , Tetrahedron, Available online 20 June 2015 , DOI:10.1016/j.tet.2015.06.056 Wu Hao , Xiao Zhiwei , Wu Junhui , Guo Yong , Xiao Ji-Chang , Liu Chao , Chen Qing Yun, Direct trifluoromethylthiolation of unactivated C(sp(3)​)​-​H using silver(I) trifluoromethanethiolate and potassium persulfate , Angewandte Chemie , 2015 , 54(13) , 4070-4074 , DOI: 10.1002/anie.201411953 Shen Qian , Huang Yan-Gen , Liu Chao , Xiao Ji-Chang , Chen Qing-Yun , Guo Yong , Review of recent advances in C-​F bond activation of aliphatic fluorides , Journal of Fluorine Chemistry , Available online 13 July 2015 , DOI:10.1016/j.jfluchem.2015.07.007 Liu Hao , Yu Jing , Li Xinyu , Yan Rui , Xiao Ji-Chang , Hong Ran, Stereoselectivity in N-​Iminium Ion Cyclization: Development of an Efficient Synthesis of (±)​-​Cephalotaxine, Organic Letters , 2015, DOI: 10.1021/acs.orglett.5b02106 Jian Zheng , Lu Wang , Jin-Hong Lin , Ji-Chang Xiao , Steven H. Liang , Difluorocarbene-Derived Trifluoromethylthiolation and [18F] Trifluoromethylthiolation of Aliphatic Electrophiles , Angewandte Chemie , 2015 , 54 , 1-6 , DOI: 10.1002/anie.201505446 44. He Zhang , Jin-Hong Lin , Ji-Chang Xiao , Yu-Cheng Gu , Rh-catalyzed allylic C-F bond activation : the stereoselective synthesis of trisubstituted monofluoroalkenes and a mechanism study , Org. Biomol. Chem , 2014 , 12 , 581-588 , DOI: 10.1039/C3OB42038H Tang-Po Yang , Qiang Li , Jin-Hong Lin , Ji-Chang Xiao , Boron-trihalide-promoted regioselective ring-opening reactions of gem-difluorocy clopropyl ketones , Chemical Communications , 2014 , 50(9) , 1077-1079 , DOI: 10.1039/c3cc47879c Xiao-Ping Wang , Jin-Hong Lin , Ji-Chang Xiao , Xing Zheng , Decarboxylative Julia-Kocienski gem-Difluoro-Olefination of 2-Pyridinyl Sulfonyldifluoroacetate , European Journal of Organic Chemistry , 2014 , 2014(5), 928-932 , DOI: 10.1002/ejoc.201301654 Qiang Li , Jin-Hong Lin , Zu-Yong Deng , Jian Zheng , Ji Cai , Ji-Chang Xiao , Wittig gem-difluoroolefination of aldehydes with difluoromethyltriphenyphosphonium bromide , Journal of Fluorine Chemistry , 2014 , 163 , 38-41, DOI: 10.1016/j.jfluchem.2014.04.011 Yun-Long Ji , Jun-Jie Kong , Jin-Hong Lin , Ji-Chang Xiao , Yu-Cheng Gu , Copper-mediated trifluoromethylation of propargyl acetates leading to trifluoromethyl-allenes , Organic &Biomolecular Chemistry , 2014 , 12(18) , 2903-2906 , DOI: 10.1039/C3OB42575D Wei-Peng Gu , Jin-Hong Lin , Ji-Chang Xiao , Direct N-gem-difluorocyclopropylation of nitro-heterocycles by utilizing gem-difluorocyclopropylation tosylate , Chinese Chemical Letters , 2014 , 25(1) , 24-28, DOI: 10.1016/j.cclet.2013.11.027 Dong-Fang Jiang , Chao Liu , Yong Guo , Ji-Chang Xiao , Qing-Yun Chen , A General, Regiospecific Synthetic Route to Perfluoroalkylated Arenes via Arenediazonium Salts with RFCu(CH3CN) Complexes , European Journal of Organic Chemistry , 2014(28), 6303-6309, DOI: 10.1002/ejoc.201402820 Shuai Zhao , Chao Liu , Yong Guo , Ji-Chang Xiao , Qing-Yun Chen , B-Perfluoroalkylated meso-Aryl-Substituted Subporphyrins: Synthesis and Properties , Synthesis , 2014 , 46(12) , 1674-1688. DOI: 10.1055/S-0033-1341055. Yun-Long Ji , Jin-Hong Lin , Ji-Chang Xiao and Yu-Cheng Gu , Copper-catalyzed tandem trifluoromethylation/cyclization of internal alkynes , Organic Chemistry Frontiers , 2014 , 1(11) , 1280-1284. DOI: 10.1039/c4qo00240g Cheng-Pan Zhang , Qing-Yun Chen , Yong Guo , Ji-Chang Xiao , Yu-Cheng Gu , Difluoromethylation and trifluoromethylation reagents derived from terrafluoroethane B-sultone: Synthesis , reactivety and applications , Coordination Chemistry Reviews , 2014 , 261 , 28-72. DOI: 10.1016/j.ccr.2013.11.010 Shuai Zhao , Chao Liu , Yong Guo , Ji-Chang Xiao , Qing-Yun Chen , Oxidative coupling of benzylamines to imines by molecular oxygen catalyzed by cobalt(Ⅱ) β-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin , The Journal of Organic Chemistry , 2014 , 79(18) , 8926-8931. DOI: 10.1021/jo5017212 Jin-Hong Lin , Ji-Chang Xiao , Recent advances in asymmetric fluorination and fluoroalkylation reactions via organocatalysis , Tetrahedron Letters , 2014 , 55(45) , 6147-6155. DOI: 10.1016/j.tetlet.2014.09031 Yun-Long Ji , Jin-Hong Lin , Ji-Chang Xiao , Yu-Cheng Gu , Stereoselective Synthesis of α-Trifluoromethyl Enones by AuⅠ/CuⅠ-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates , European Journal of Organic Chemistry , 2014(35) , 7948-7954 . DOI: 10.1002/ejoc.201403115

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