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两价钯催化的化学反应研究

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Wang, H.; Han, X.*; Lu, X.* Pd(II)-Catalyzed Annulation of N-Benzyl-N-Aroylmethyl-2- Alkynamides with Arylboronic Acids: An Efficient Synthesis of Highly Substituted α-Alkylidene-β-Hydroxy-γ-Lactams. Tetrahedron 2010, 66, 9129-9134. Han, X.; Lu, X.* Cationic Pd(II)-Catalyzed Tandem Reaction of 2-Arylethynylanilines and Aldehydes: An Efficient Synthesis of Substituted3-Hydroxymethyl Indoles Org. Lett. 2010, 12, 3336-3339. Han, X.; Lu, X.* Control of Chemoselectivity by Counteranions of Cationic Palladium Complexes: A Convenient Enantioselective Synthesis of Dihydrocoumarins Org. Lett. 2010, 12, 108-111. Han, X.; Lu, X.* Novel Palladium-Catalyzed Acyloxylation/Cyclization of 2-(3’-Alkenyl)indoles. Org. Lett. 2009, 11, 2381-2384. Feng, J.; Lu, X.*; Kong, A.; Han, X. A Highly Regio- and Stereo-Selective [3+2] Annulation of Allylic Compounds and 2-Substituted1,1-Dicyanoalkenes through a Catalytic Carbon–Phosphorus Ylide Reaction. Tetrahedron 2007, 63, 6035-6041. Kong, A.; Han, X.; Lu, X.* Highly Efficient Construction of Benzene Ring in Carbazoles by Palladium-Catalyzed Endo-Mode Oxidative Cyclization of 3-(3’-Alkenyl)indoles. Org. Lett. 2006, 8, 1339-1343. 韩秀玲,刘桂霞,陆熙炎* 钯催化反应中的β-氢消除反应。有机化学, 2005, 25, 1182-1197. Du, Y.; Han, X.; Lu, X.* Alkaloids-Catalyzed Regio- and Enantioselective Allylic Nucleophilic Substitution of tert-Butyl Carbonate of the Morita-Baylis-Hillman ProductsTetrahedron Lett. 2004, 45, 4967-4971. Zhang, Q.; Lu, X.;* Han, X. Palladium(II)-Catalyzed Asymmetric Cyclization of (Z)-4’-Acetoxy-2’-butenyl 2-Alkynoates. Role of Nitrogen-Containing Ligands in Palladium(II)-Mediated Reactions. J. Org. Chem. 2001, 66, 7676-7684. Zhang, Z.; Lu, X.*; Xu, Z.; Zhang, Q.; Han, X. Role of Halide Ions in Divalent Palladium Mediated Reactions: Competition between β-Heteroatom Elimination and β-Hydride Elimination of a Carbon-Palladium Bond. Organometallics 2001, 20, 3724-3728.

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