唐勇 - 中国科学院上海有机化学研究所 -

个人简介

教育经历 1982.09-1986.06 四川师范大学化学系本科 1990.09-1993.02 中国科学院上海有机化学研究所硕士（导师：黄耀曾院士） 1993.03-1996.02 中国科学院上海有机化学研究所博士（导师：黄耀曾院士、戴立信院士）工作经历工作经历 1996.03-1996.07 中国科学院上海有机化学研究所助理研究员 1996.08-1997.05 美国Colorado State University 博士后 1997.05-1999.04 美国Georgetown University 博士后 1999.05-1999.12 中国科学院上海有机化学研究所副研究员 2000.01至今中国科学院上海有机化学研究所研究员 2009.11-2017.01 金属有机化学国家重点实验室主任 2009.05-2018.12 中国科学院上海有机化学研究所副所长 2019.01至今中国科学院上海有机化学研究所所长

研究领域

主要从事金属有机化学研究。针对均相催化领域的选择性控制与催化效率等核心科学问题，应用边臂策略设计金属有机催化剂，发展在催化剂的活性中心区域装载配位基团（边臂）以调控其催化行为的新方法和有机合成新反应 1. 不对称催化 2. 烯烃聚合催化剂的设计、合成与应用 3. 叶立德化学 4. 天然产物全合成

近期论文

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Li Zhou, Liping Li, Sudong Zhang, Xiao-kang Kuang, You-Yun Zhou*, and Yong Tang*. “Catalytic Regio- and Enantioselective Remote Hydrocarboxylation of Unactivated Alkenes with CO2”. J. Am. Chem. Soc. 2024, ASAP. Sudong Zhang, Liping Li, Dingxi Li, You-Yun Zhou*, and Yong Tang*. “Catalytic Regio- and Enantioselective Boracarboxylation of Arylalkenes with CO2 and Diboron” J. Am. Chem. Soc. 2024, 146, 2888−2894. Xing-Wang Han, Xun Zhang, Youyun Zhou, Aizezi Maimaitiming, Xiu-Li Sun, Yanshan Gao*, Peizhi Li, Boyu Zhu, Eugene Y.-X. Chen*, Xiaokang Kuang, Yong Tang*. Circular olefin copolymers made de novo from ethylene and α-olefins.Nat. Commun. 2024, 15, 1462. Tianyang Li, Yanshan Gao, Xiu-Li Sun, Yong Tang, Qiang Fu*. Significantly enhanced crystallization of polylactide Ingeo 4032D by polyethylene ionomer. Polymer 2024, 290, 126557. Liu-Peng Zhao, Sheng-Ye Zhang, Hua-Kui Liu, Yu-Jing Cheng, Zhi-Pan Liu*, Lijia Wang*, and Yong Tang*. Insights into Stereoselectivity Switch in Michael Addition-Initiated Tandem Mannich Cyclizations and Their Extension from Enamines to Vinyl Ethers. J. Am. Chem. Soc., 2023, 145, 15553–15564. Yang Ma, Ya-Nan Zhao, Xi-Man Yang, Jun-Fang Li, Xiao-Yan Wang*, and Yong Tang*. SaBOX/Copper-Catalyzed Synthesis, Degradation, and Upcycling of a PMMA-Based Copolymer. Macromolecules 2023, 56, 7032–7042. Bingxin Qu, Yanan Zhao, Ping Song, Yanshan Gao, You-Yun Zhou*, Xiu-Li Sun, Qiang Fu, Xiaoshan Ning, Junfang Li, Xiaokang Kuang, and Yong Tang*. Norbornene Monomer Effects and Mechanistic Insights in Binuclear Nickel-Catalyzed Olefin Chain Walking Copolymerizations. ACS Catal. 2023, 13, 12849–12858. Xiao-Yan Wang, Yanshan Gao*, Yong Tang*. Sustainable Developments in Polyolefin Chemistry: Progress, Challenges, and Outlook. Prog. Polym. Sci. 2023, 143, 101713. Ge Du, Hongmei Yang*, Xiuli Sun, Yong Tang. Tribological Behavior and Wear Protection Ability of Graphene Additives in Synthetic Hydrocarbon Base Stocks. Lubricants 2023, 11, 200. Li Ji, Ping Song, Youyun Zhou*, Xiu-Li Sun, Yanshan Gao* and Yong Tang*. A Tridentate Phenoxy-Phosphine (POP) Divalent Chromium Complex and Its Reactivities in Olefin Polymerization. Polym. Chem., 2023, 14, 763–772. Xian-Ya Fang, Long Qin, Jiashuai Liu, Haonan Shi, Xiu-Li Sun, Xiaokang Kuang, Yanshan Gao*, Yong Tang*, Synthesis and Characterization of Oxazoline-Amine Zirconium Complexes for Ethylene Homo- and Co-Polymerization Catalysis. Mol. Catal. 2023, 541, 113108. Liu-Peng Zhao, Peng-Juan Li, Lijia Wang* and Yong Tang*. Allenamide-Initiated Cascade [2+2+2] Annulation Enabling the Divergent Total Synthesis of (−)-Deoxoapodine, (−)-Kopsifoline D and (±)-Melotenine A. Angew. Chem. Int. Ed. 2022, 61, e202207360. Ya-Ning Li, Sheng-Ye Zhang, Yang Ma, Yi-Jie Ding, Zhi-Hao Chen, Qiao-Ling Che, Long Qin, Xiu-Li Sun, Xiaohua Liu, Xiaoming Feng*, Zhi-Pan Liu*, Xiao-Yan Wang* and Yong Tang*. Hydrogen Bond Effects: A Strategy for Improving Controllability in Organocatalytic Photoinduced Controlled Radical Polymerization Targeting High Molecular Weight. ACS Catal. 2022, 12, 11606–11614. Yang Chen, Geng-Xie Li, Ai-Qing Peng, Yong Tang, and Lijia Wang*. Rapid Construction of Enantioenriched Benzofurochromanes by SaBOX/Copper(II) Catalyzed Enantioselective [3 + 2] Annulation of γ-Chromenes with Quinones. Org. Lett. 2022, 24, 5525–5529. Zhi-Hao Chen, Xiao-Yan Wang* and Yong Tang. Reversible complexation mediated polymerization: an emerging type of organocatalytically controlled radical polymerization. Polym. Chem. 2022, 13, 2402–2419. Yu-Jing Cheng, Liu-Peng Zhao, Lijia Wang* and Yong Tang*. Catalytic [2+2+2] Tandem Cyclization with Alkyl Substituted Methylene Malonate Enabling Concise Total Synthesis of Four Malagasy Alkaloids. CCS Chem. 2022, 5, 124–132. Lijia Wang*, Yong Tang. Side Arm Modified Chiral Bisoxazoline Ligands: Recent Development and Prospect in Asymmetric Catalysis. Tetrahedron 2022, 129, 133121. Aizezi Maimaitiming, Xiuli Sun, Ying Lu, Guozhong Wu, Yongfeng Men*, Xia Dong*, Yong Tang. Thermal Insulative 2D-Oriented Bimodal Micro-foams and High Strength Photonic Thermoplastic Elastomers by Assembling Olefin Multiblock Copolymers. Compos. Part B-Eng. 2022, 246, 110283. Gang Ji, Zhou Chen, Xiao-Yan Wang, Xiao-Shan Ning, Chong-Jie Xu, Xing-Min Zhang, Wen-Jie Tao, Jun-Fang Li, Yanshan Gao, Qi Shen, Xiu-Li Sun*, Hao-Yang Wang, Jun-Bo Zhao, Bo Zhang, Yin-Long Guo, Yanan Zhao, Jiajie Sun, Yi Luo*, Yong Tang*. Direct Copolymerization of Ethylene with Protic Comonomers Enabled by Multinuclear Ni Catalysts. Nat. Commun. 2021,12, 6283. Yang Ma, Hong-Mei Yang, Zhi-Hao Chen, Ya-Ning Li, Jun-Fang Li, Xiuli Sun, Xiao-Yan Wang* and Yong Tang*. Highly Branched Polymethacrylates Prepared Efficiently: Brancher-Directed Topology and Application Performance. Polym. Chem. 2021,12, 6606−6615. Li Zhou, Wen-Guang Yan, Xiu-Li Sun, Lijia Wang* and Yong Tang*. A Versatile Enantioselective Catalytic Cyclopropanation-Rearrangement Approach to the Divergent Construction of Chiral Spiroaminals and Fused Bicyclic Acetals. Angew. Chem. Int. Ed. 2020, 59, 18964–18969. Zhi-Hao Chen, Yang Ma, Xiao-Yan Wang*, Xiu-Li Sun, Jun-Fang Li, Ben-Hu Zhu and Yong Tang*. A Winning Strategy for Iron-Based ATRP Using In-Situ Gener-ated Iodine as a Regulator. ACS Catal. 2020, 10, 14127–14134. Song Wei, Long Zheng, Sunewang R. Wang* and Yong Tang*. Catalytic Diastereoselective [5 + 2] Annulation of N-Acryloyl Indoles with Cyclic Sulfonyl Enamides: Facile Access to Isoeburnamonine. Org. Lett. 2020, 22, 1013−1017. Xiang-Yang Song, Liu-Peng Zhao, Lijia Wang* and Yong Tang*. Highly Stereoselective Direct Construction of Diaryl-Substituted Cyclobutanes. Chin. J. Chem. 2020, 38, 259–262. Shuai Wu, Jun-Fang Li, Xiu-Li Sun, Xiao-Yan Wang* and Yong Tang*. Synthesis of Novel Polyethers with Abundant Reactive Sites and Diverse Skeletons Based on the Ring-Opening Reaction of D–A Cyclopropanes. Polym. Chem. 2020, 11, 5969–5973. Zhong-Bo Zheng, Wen-Fu Cheng, Lijia Wang*, Jun Zhu, Xiu-Li Sun* and Yong Tang*. Asymmetric Catalytic [3+2] Annulation of Donor-Acceptor Cyclopropane with Cyclic Ketones: Facile Access to Enantioenriched 1-Oxaspiro[4.5]decanes. Chin. J. Chem. 2020, 38, 1629–1634. Hua-Kui Liu, Sunewang R. Wang, Xiang-Yang Song, Liu-Peng Zhao, Lijia Wang* and Yong Tang. Selectivity Switch in a Rhodium(II) Carbene Triggered Cyclopentannulation: Divergent Access to Three Polycyclic Indolines. Angew. Chem. Int. Ed. 2019, 58, 4345–4349. Song Wei, Lei Yin, Sunewang R. Wang* and Yong Tang*. Catalyst-Controlled Chemoselective All-Alkene [2+2+2] and [2+2] Cyclizations of Enamides with Electron-Deficient Alkenes. Org. Lett. 2019, 21, 1458–1462. Li Ji, Jia-Shuai Liu, Xiao-Yan Wang, Jun-Fang Li, Zhou Chen, Saihu Liao*, Xiu-Li Sun* and Yong Tang. An Efficient and Mild Route to Highly Fluorinated Polyolefins via Copolymerization of Ethylene and 5-Perfluoroalkylnorbornenes. Polym. Chem. 2019, 10, 3604–3609. Zhu Cao, Jian-Bo Zhu, Lijia Wang*, Saihu Liao*, Yong Tang. A Synthesis of Multifunctionalized Indoles from [3+2] Annulation of 2-Bromocyclopropenes with Anilines. Org. Lett. 2019, 21, 4097–4100. Xiao-Yan Wang*, Zhi-Hao Chen, Xiu-Li Sun, Yong Tang*. Low Temperature Effect on ATRP of Styrene and Substituted Styrenes Enabled by SaBOX Ligand. Polymer 2019, 178, 121630–121637. Li Zhou, Shu-Yang Yu, Yong Tang, and Lijia Wang*. Facile Stereoselective Approach to Diverse Spiroheterocyclic Tetrahydropyrans: Concise Synthesis of (+)-Broussonetine G and H. Angew. Chem. Int. Ed. 2019, 58, 15016–15020. Zhi-Hao Chen, Xiao-Yan Wang*, Xiu-Li Sun, Jun-Fang Li, Ben-Hu Zhu, and Yong Tang*. Highly Efficient Atom Transfer Radical Polymerization System Based on the SaBOX/Copper Catalyst. Macromolecules 2019, 52, 9792–9798. Chao Deng, Jiao-Long Zhou*, Hua-Kui Liu, Lijia Wang*, Yong Tang. Rh2(OAc)4 Catalyzed Wittig-Type Olefination: A Facile Access to Alkylidene and Arylidene Malonates. Chin. J. Org. Chem. 2019, 39, 2328–2332.