刘元红 - 中国科学院上海有机化学研究所 - 金属有机化学国家重点实验室

研究领域

前过渡金属锆、钛杂环化合物促进的高选择性合成反应过渡金属与烯烃、炔烃、共轭多炔类化合物的配位行为与反应性能研究金（gold）催化的碳-碳键与碳-杂原子键的形成反应过渡金属催化的高效串联反应研究具有潜在应用价值的π-共轭体系有机分子的设计与合成

近期论文

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Gold-Catalyzed Oxidative Ring Expansion of 2-Alkynyl-1,2-Dihydropyridines or -quinolines: Highly Efficient Synthesis of Functionalized Azepine or Benzazepine Scaffolds Ming Chen, Yifeng Chen, Ning Sun, Jidong Zhao, Yuanhong Liu* and Yuxue Li* Angew. Chem. Int. Ed. 2015, 54, 1200. Gold(I)-Catalyzed 1,2-Acyloxy Migration/[3+2] Cycloaddition of 1,6-Diynes with an Ynamide Propargyl Ester Moiety: Highly Efficient Synthesis of Functionalized Cyclopenta[b]indoles Jun Liu, Ming Chen, Liangwei Zhang, Yuanhong Liu* Chem. Eur. J. 2015, 21, 1009. Zirconium-Mediated Multicomponent Reactions of 1,3-Butadiynes with Ylidenemalononitriles to Form Functionalized 1,8-Naphthyridine and Cyclopenta[b]pyridine Derivatives Shasha Yu, Renhong Sun, Haoyi Chen, Xin Xie, and Yuanhong Liu* Chem. Eur. J. 2015, 21, 1420. Gold(I)-Catalyzed 1,4 and/or 1,5-Heteroaryl Migration Reactions via Regiocontrolled Cyclizations Chengyu Wang, Xin Xie, Jun Liu, Yuanhong Liu* and Yuxue Li* Chem. Eur. J. 2015, 21, 559. Insertion of Nitriles into Zirconocene-1-aza-1,3-diene Complexes: Chemoselective Synthesis of N-H and N-Substituted Pyrroles. Shasha Yu, Meijun Xiong, Xin Xie, and Yuanhong Liu*Angew. Chem. Int. Ed. 2014, 53, 11596. Titanium-mediated Cross-coupling Reactions of 1,3-butadiynes with α-iminonitriles to 3-aminopyrroles: Observation of an Imino aza-Nazarov Cyclization Xu You, Xin Xie, Renhong Sun, Haoyi Chen, Shi Li and Yuanhong Liu* Org. Chem. Front., 2014, 1, 940. Gold(I)-Catalyzed Furan-yne Cyclizations Involving 1,2-Rearrangement: Efficient Synthesis of Functionalized 1-Naphthols and Its Application to the Synthesis of Wailupemycin G. Yifeng Chen, Lu Wang, Ning Sun, Xin Xie, Xiaobo Zhou, Haoyi Chen, Yuxue Li,* and Yuanhong Liu* Chem. Eur. J. 2014, 20, 12015. Gold-Catalyzed Cascade Reactions of Furan-ynes with External Nucleophiles Consisting of 1,2-Rearrangement: Straightforward Synthesis of Multi-Substituted Benzo[b]furans. Ning Sun, Xin Xie, and Yuanhong Liu* Chem. Eur. J. 2014, 20, 7514. Gold-Catalyzed Oxidative Reactions of Propargylic Carbonates Involving 1,2-Carbonate Migration: Stereoselective Synthesis of Functionalized Alkenes. Ning Sun, Ming Chen, and Yuanhong Liu* J. Org. Chem. 2014, 79, 4055. Titanium-mediated reductive cross-coupling reactions of imines with nitriles: an efficient route for the synthesis of a-aminoketones or 1,2-diketones Haoyi Chen, Guoqin Fan, Shi Li, Kebin Mao, Yuanhong Liu* Tetrahedron Letters, 2014, 55, 1593. Gold-Catalyzed Oxidative Rearrangement Involving 1,2-Acyl Migration: Efficient Synthesis of Functionalized Dihydro-γ-Carbolines from α-(2-Indolyl) Propargylic Alcohols and Imines, Lu Wang, Xin Xie, Yuanhong Liu* Angew. Chem. Int. Ed. 2013, 52, 13302. Gold-catalyzed cascade cycloisomerization of 1,7-diyn-3,6-bis(propargyl carbonate)s. Stereoselective synthesis of naphtho[b]cyclobutenes, Chen Ming, Liu, Jun, Wang Lu, Xiaobo Zhou, Yuanhong Liu* Chem. Commun., 2013, 49, 8650. Silver-catalyzed cascade cyclization-stannylation of o-alkynylaniline derivatives with 2-tributylstannylfuran: an efficient synthesis of (3-indolyl)stannanes, Liu Jun, Xin Xie, Yuanhong Liu* Chem. Commun., 2013, 49, 11794. Environmentally Benign Synthesis of Indeno[1,2-b]quinolines via an Intramolecular Povarov Reaction, Chen Ming, Ning Sun, Yuanhong Liu* Org. Lett. 2013, 15, 5574. Unusual Regioselectivity in the Aldehyde Addition Reactions of Allenyl/Propargyl Zirconium Complexes Derived from γ-(2-Pyridyl)propargyl Ethers: Synthesis of Multisubstituted α-Hydroxyallenes, Guoqin Fan, Xin Xie, Yuanhong Liu*, Yuxue Li*, Organometallics, 2013, 36, 1636. Reactions of Zirconocene Butadiyne or Monoyne Complexes with Nitriles: Straightfoward Synthesis of Functionalized Pyrimidines, Xu You, Shasha Yu, Yuanhong Liu* Organometallics, 2013, 32, 5273. Titanium-mediated reductive cross-coupling reactions of imines with terminal alkynes: an efficient route for the synthesis of stereodefined allylic amines，Mao Kebin, Guoqin Fan, Yuanhong Liu*, Shi Li, You Xu, Liu Dan, Beilstein J. Org. Chem., 2013, 9, 621. 锆-苯炔参与的金属杂环的形成及其在有机合成中的应用，毛可彬，付晓平，刘丹*，李石，刘元红* 有机化学, 2013, 33, 780。 Palladium-catalyzed highly efficient synthesis of tetracenes and pentacenes. Ming Chen, Y. Chen, and Yuanhong Liu* Chem. Commun. 2012, 48, 12189. Facile Synthesis of Fully Substituted Dihydro-β-carbolines via Brønsted Acid Promoted Cascade Reactions of α-Indolyl Propargylic Alcohols with Nitrones. Lu Wang, Xin Xie, and Yuanhong Liu* Org. Lett. 2012, 14, 5848.