邓亮 - 中国科学院上海有机化学研究所 -

个人简介

Professional Experience and Education 2009.08-present Research Professor, State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, CAS 2007.01-2009.07 Postdoc at Harvard University ( Supervisor: Prof. R. H. Holm) 2006.08-2006.12 Postdoc at the Chinese University of Hong Kong (Supervisor: Prof. Zuowei Xie) 2002.08-2006.07 Ph.D. degree from the Chinese University of Hong Kong (Supervisor: Prof. Zuowei Xie) 1998.09-2002.07 B.S. degree from Peking University (Supervisor: Prof. Zhenfeng Xi) Awards National Science Fund For Distinguished Young Scholars (2017) ACS Organometallics Young Investigator Fellowship (2014) Thieme Chemistry Journals Award (2013) Excellent Young Scientist Fundation of NSFC (2012) Shanghai Pujiang Program (2011) The Hundred-Talented Program of the Chinese Academy of Sciences (2010)

研究领域

Research in our group focuses on the synthesis, structure, and reactivity aspects of organometallic chemistry with emphasizing on the complexes capable of facilitating small molecules and inert bond activation, performing homogeneous catalysis, and mimicking the organometallic units in enzymes and cofactors. Research involves extensive synthesis, structural analyses with modern spectroscopic and computational methods, and detailed investigations of reactivity. Currently, our group’s research mainly focuses on three projects listed as below: Low-coordinate Transition-metal Complexes Small Molecule Activation Hydrosilylation reaction

近期论文

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Zhao, Z.; Zhang, F.; Wang, D.*; Deng, L.* Advances in Transition‐Metal‐Catalyzed Hydrogermylation of Alkenes and Alkynes. Chin. J. Chem. 2023, DOI: 10.1002/cjoc.202300276. Zhou, L.; Wang, D.; Yang, C.; Deng, L.* Four-coordinate Disilyl Cobalt(II) Complexes with NHC Ligation: Synthesis, Characterization, and Reactivity. Chin. Chem. Lett. 2023, DOI: 10.1016/j.cclet.2023.108682. Li, H.; Yang, C.; Wang, D.*; Deng, L.* Cobalt-Catalyzed Regio- and Stereoselective Hydrosilylation of Alk-2-ynes with Tertiary Silanes. Organometallics 2023, 42, 1693-1698. Balch, A.; Everett, G.; Power, P. P.; Armstrong, W. H.; Kovacs, J.; Stack, T. D. P.; Donahue, J. P.*; Gray, T. G.; Groysman, S.; Deng, L. Richard Hadley Holm: A Remembrance and A Tribute. Comments Inorg. Chem. 2022, 42, 61-108. Yang, C.; Jiang, X.; Chen, Q.; Leng, X.; Xiao, J.; Ye, S.*; Deng, L.* Signet-Ring-Shaped Octaphosphorus-Cobalt Complexes: Synthesis, Structure, and Functionalization Reactions with Carbene Analogs. J. Am. Chem. Soc. 2022, 144, 20785-20796. Bai, W.; Sun, J.; Wang, D.*; Bai, S.-D.*; Deng, L.* Low-coordinate cobalt(0) N-heterocyclic carbene complexes as catalysts for hydrosilylation of alkynes. Appl Organomet Chem. 2022, 36, e6694. Li, S.; Ouyang, Z.; Zou, J.; Wang, D.; Xu, B.*; Deng, L.* A Mononuclear Iron Thiolate Complex with N-Heterocyclic Carbene Ligation. Acta Chim. Sinica 2022, 80, 272-276. Yang, J.; Ma, Y.; Liu, Q,; Leng, X.; Zhou, S.*; Ye, S.; Deng, L.*; Wang, S.* Noninnocent Behavior of a (3-Imino)indol-2-yl Ligand in Metal Complexes. Organometallics 2022, 41, 480-485. Chen, Q.; Liu, Q.; Xiao, J.; Leng, X.; Deng, L.* Catalytic Method for the Synthesis of Deuterium-Labeled N-Heterocyclic Carbenes Enabled by a Coordinatively Unsaturated Ruthenium N-Heterocyclic Carbene Catalyst. J. Am. Chem. Soc. 2021, xxx, xxx-xxx. Deng, L.; Mo, Z. Organometallic Chemistry of NHCs and Analogues. Comprehensive Organometallic Chemistry IV, https://doi.org/10.1016/B978-0-12-820206-7.00027-5 Wang, D.#; Lai, Y.#; Wang, P.; Leng, X.; Xiao, J.; Deng, L.* Markovnikov Hydrosilylation of Alkynes with Tertiary Silanes Catalyzed by Dinuclear Cobalt Carbonyl Complexes with NHC Ligation. J. Am. Chem. Soc. 2021, 143, 12847-12856. Liu, J.; Bollmeyer, M. M.; Kim. Y.; Xiao, D.; MacMilan, S. N.; Chen, Q.; Leng, X.; Kim, S. H.*; Zhao, L.*; Lancaster, K. M.*; Deng, L.* An Isolable Mononuclear Palladium(I) Amido Complex. J. Am. Chem. Soc. 2021, 143, 10751-17059. Liu, Q.; Long, L.; Ma, P.; Ma, Y.; Leng, X.; Xiao, J.; Chen, H.*; Deng, L.* Synthesis, Structure, and C–H Bond Activation Reaction of An Iron(IV) Terminal Imido Complex Bearing Trifluoromethyl Groups. Cell. Rep. Phys. Sci. 2021, 2, 100454. Wang, L.; Cheng, J.; Ma, Y.; Chen, Q.; Leng, X.; Deng, L.* Three-Coordinate Bis(N-heterocyclic carbene)iron(0) Complexes with Alkene and Alkyne Ligation: Synthesis and Characterization. Polyhedron 2021, 197, 115054. Deng, L. Pioneers and Influencers in Organometallic Chemistry: Professor Yao-Zeng Huang and His Three "Treasure Chests".Organometallics 2020, 39, 2327-2330. Liu, J.; Xiao, J.; Mondal, S.; Leng, X.; Deng, L.* Reactions of Iron(II) Complexes Supported by Tripodal Amido-Phosphine-Amido Ligands with Diazo Compounds. Chin. J. Org. Chem. 2020, 40, 3380-3389. Wang, P.; Cheng, J.; Wang, D.; Yang, C.; Leng, X.; Deng, L.* Cobalt(-I)- and Rhodium(-I)-Mediated Dearylation of N-Aryl N-Heterocyclic Carbene Ligands. Organometallics 2020, 39, 2871-2877. Cao, C.; Mao, G.*; Cheng, J.; Leng, X.; Deng, L.* Reactions of a Bis(vinyltrimethylsilane)-nickel(0) N-Heterocyclic carbene complex with organic azides. J. Organomet. Chem. 2020, 913, 121195-121203. Chen, W.; Chen, Q.; Ma, Y.; Leng, X.; Bai, S.-D.*; Deng, L.* Formal Co(0), Fe(0), and Mn(0) Complexes with NHC and Styrene ligation. Chin. Chem. Lett. 2020, 31, 1342–1344. Liu, Y.; Cheng, J.; Deng, L.* Three-Coordinate Formal Cobalt(0), Iron(0), and Manganese(0) Complexes with Persistent Carbene and Alkene Ligation. Acc. Chem. Res. 2020, 53, 244-254. Du, J.; Chen, W.; Chen, Q.; Leng, X.; Meng, Y.-S.; Gao, S.; Deng, L.* Reactivity of a Two-Coordinate Cobalt(0) Cyclic (Alkyl)(amino)carbene Complex. Organometallics 2020, 39, 729-739. Wang, D.; Tamizmani, M.; Leng, X.; Deng, L.* Isolable Anion Radicals of Nitrosoarenes. Chin. J. Chem. 2020, 38, 158-162. Huang, Z.; Zheng, Y.; Zhang, W.-X.; Ye, S.*; Deng, L.;* Xi, Z.* Dinickelaferrocene: A Ferrocene Analogue with Two Aromatic Nickeloles Realized by Electron Back-Donation from Iron. Angew. Chem. Int. Ed. 2020, 59, 14394-14398. Cheng, J.; Chen, Q.; Leng, X.; Ye, S.*; Deng, L.* Three-Coordinate Iron(0) Complexes with N-Heterocyclic Carbene and Vinyltrimethylsilane Ligation: Synthesis, Characterization, and Ligand Substitution Reactions. Inorg. Chem. 2019, 58, 13129-13141. Wang, D.; Leng, X.; Ye, S.; Deng, L.* Substrate Redox Non-innocence Inducing Stepwise Oxidative Addition Reaction: Nitrosoarene C–N Bond Cleavage on Low-Coordinate Cobalt(0) Species. J. Am. Chem. Soc. 2019, 141, 7731-7735. Wang, P.; Xiao, J.; Leng, X.; Deng, L.* A High-Spin Iron(II) Complex Supported by a Tridentate Di-amido-Stibine Ligand:Synthesis, Structure and Its Reactions with Organic Azides and Diazo Compounds. Chin. J. Org. Chem. 2019, 39, 2243-2250. Cheng, J.; Liu, J.; Leng, X.; Lohmiller, T.; Schnegg, A.; Bill, E.; Ye, S.*; Deng, L.* A Two-Coordinate Iron(II) Imido Complex with NHC Ligation: Synthesis, Characterization, and Its Diversified Reactivity of Nitrene Transfer and C–H Bond Activation. Inorg. Chem. 2019, 58, 7634-7644. Gao, Y.; Chen, Q.; Leng, X.; Deng, L.* Cyclometallation Reactions of a Three-Coordinate Cobalt(I) Complex Bearing a Nonsymmetric N-Heterocyclic Carbene Ligand. Dalton Trans. 2019, 48, 9676–9683.