陈耀峰 - 中国科学院上海有机化学研究所 - 金属有机化学国家重点实验室

研究领域

金属有机化合物，特别是新型稀土金属有机化合物的设计，合成及催化的有机和高分子合成

近期论文

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Jiaxiang Chu, Christos E. Kefalidis, Laurent Maron,* Xuebing Leng, Yaofeng Chen,* “Chameleon Behavior of a Newly Synthesized Nitrilimine Scandium Derivative” J. Am. Chem. Soc. 2013, 135, 8165-8168. Jiliang Zhou, Jiaxiang Chu, Yanyan Zhang, Guang Yang, Xuebing Leng, Yaofeng Chen,* “An Yttrium Hydride-Silane Complex as a Structural Model for a σ-Bond Metathesis Transition State” Angew. Chem. Int. Ed. 2013, 52, 4243-4246. Jiaxiang Chu, Erli, Lu, Yaofeng Chen,* Xuebing Leng, “Reversible Addition of Si-H Bond of Phenylsilane to Sc=N Bond of Scandium Terminal Imido Complex” Organometallics, 2013, 32, 1137-1140. (Invited for the special issue entitled “Recent Advances in Organo-f-Element Chemistry”). Yangjian Hu, Xiufang Wang, Yaofeng Chen,* Lucia Caporaso,* Luigi Cavallo,* Eugene Y.-X. Chen,* “Rare-Earth Half-Sandwich Dialkyl and Homoleptic Trialkyl Complexes for Rapid and Stereoselective Polymerization of a Conjugated Polar Olefin” Organometallics, 2013, 32, 1459-1465. Erli Lu, Yuanyuan Yuan, Yaofeng Chen,* Wei Xia, “1-Methyl Boratabenzene Yttrium Alkyl: A Highly Active Catalyst for Dehydrocoupling of Me2NH×BH3” ACS Catalysis 2013, 3, 521-524. (Invited for the virtual special issue on Catalysis at SIOC). Erli Lu, Qinghai Zhou, Yuxue Li, Jiaxiang Chu, Yaofeng Chen,* Xuebing Leng, Jie Sun, “Reactivity of Scandium Terminal Imido Complexes towards Metal Halides” Chem. Commun. 2012, 48, 3403-3405. Erli Lu, Yaofeng Chen,* Jiliang Zhou, Xuebing Leng, “C−P or C−H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride” Organometallics, 2012, 31, 4574-4578. Yilin Sun, Guangming Wu, Dinghai Cen, Yaofeng Chen,* Limin Wang,* “Synthesis and Catalytic Activity of Heterogeneous Rare-earth Metal Catalysts Coordinated with Multitopic Schiff-base Ligands” Dalton Trans., 2012, 41, 9682-9688. Jiaxiang Chu, Erli Lu, Zhixiao Liu, Yaofeng Chen,* Xuebing Leng, Haibing Song “Reactivity of a Scandium Terminal Imido Complex towards Unsaturated Substrates” Angew. Chem. Int. Ed. 2011, 50, 7677-7680. Yingdong Lv, Xin Xu, Yaofeng Chen,* Xuebing Leng, Maxim V. Borzov “Well-defined Soluble P3- Containing Rare-earth Metal Compounds” Angew. Chem. Int. Ed. 2011, 50, 11227-11229. Erli Lu, Jiaxiang Chu, Yaofeng Chen,* Maxim V. Borzov, Guangyu Li, “The Scandium Terminal Imido Complexes Induced C-H Bond Selenation and the Formation of Sc-Se Bond” Chem. Commun. 2011, 47, 743-745. Erli Lu, Yaofeng Chen,* Xuebing Leng, “Yttrium Anilido Hydride: Synthesis, Structure, and Reactivity” Organometallics, 2011, 30, 5433-5441. Yuanyuan Yuan, Xiufang Wang, Yuxue Li, Liyan Fan, Xin Xu, Yaofeng Chen,* Guangyu Li, Wei Xia, “Rapid Entry to Functionalized Boratabenzene Complexes Through Metal Induced Hydroboration at Anionic 1-H-Boratabenzene Ligand” Organometallics 2011, 30, 4330-4341. Peng Cui, Yaofeng Chen,* Guangyu Li, Wei Xia, “Versatile Reactivities of ansa-Heteroborabenzene Divalent Ytterbium Amide toward Alkali-Metal Salts and the Generation of Heterometallic Ytterbium-Alkali-Metal Boratabenzene Complexes” Organometallics 2011, 30, 2012-2017. Erli Lu, Wei Gan, Yaofeng Chen,* “Monoalkyl and monoanilide yttrium complexes containing tridentate pyridyl-1-azaallyl dianionic ligands” Dalton Trans. 2011, 40, 2366-2374. (Invited for the themed issue entitled “New Talent: Asia”). 刘智潇, 陈耀峰,* “稀土金属有机化学的一个前沿领域：稀土卡宾化学” 中国科学(化学), 2011, 41, 304-313. (评述)。 Erli Lu, Yuxue Li, Yaofeng Chen,* “A Scandium Terminal Imido Complex: Synthesis, Structure and DFT Studies” Chem. Commun., 2010, 46, 4469-4471. (封面文章) Yuanyuan Yuan, Yaofeng Chen,* Guangyu Li, Wei Xia, “Synthesis and Structural Features of Boratabenzene Rare-earth Metal Alkyl Complexes” Organometallics 2010, 29, 3722-3728. Xin Xu, Yaofeng Chen,* Jian Feng, Gang Zou, Jie Sun, “Half-sandwich Mono(indenyl) Rare-earth Metal Dialkyl Complexes: Syntheses, Structures and Catalytic Reactivities of (1,3-(SiMe3)2C9H5)RE(CH2SiMe3)2(THF)” Organometallics 2010, 29, 549-553. Yangjian Hu, Xin Xu, Yuetao Zhang, Yaofeng Chen,* Eugene Y.-X. Chen,* “Polymerization of Naturally Renewable Methylene Butyrolactones by Half-Sandwich Indenyl Rare Earth Metal Dialkyls with Exceptional Activity” Macromolecules 2010, 43, 9328-9336.