当前位置: X-MOL首页全球导师 国内导师 › 孙文华

个人简介

1963年出生 1986年兰州大学理学学士 1989年中国科学院兰州化学物理研究所理学硕士 1993年中国科学院兰州化学物理研究所副研究员 1994年中国科学院兰州化学物理研究所理学博士 1995年-1999年日本北海道大学催化中心 日本学术振兴会(JSPS)研究员 核心机关外国人(COE)研究员 日本科学技术事业团(JST)研究员 1999年10月至今中国科学院化学研究所研究员 2001年11月-2002年4月德国明斯特大学有机化学研究所洪堡基金访问教授 2003年3月-2003年5月日本名古屋大学国际物质研究中心访问教授 2005年7月法国LouisPasteur大学2004/2005年度访问教授 2004年至2019年"高分子学报"编委 2005年至今中国化学会会员 2009年1月法国斯特拉斯堡大学访问教授 2010年3月-2014年12月"AdvancesinMaterialsScienceandEngineering"编委 2010年6月-2014年12月"CurrentChemicalResearch"编委 2008年11月-2013年4月中国科学院化学研究所学术委员会委员 2009年美国化学会会员 2010年英国皇家化学会会员 2011年至今英国皇家化学会会士 2012年10月至今PolyolefinsJournal编委 2013年5月至2018年8月中国科学院分子科学中心第四届学术委员会委员 2015年8月中国科学院工程塑料重点实验室学术委员会副主任 2016年至今Molecules编委 2017年9月中国化学会均相催化专业委员会委员 2017年11月RoyalSocietyOpenScience化学顾问委员 2017年至今欧洲科学院院士 2018年6月GeneralChemistry国际顾问委员 2018年8月至今中国科学院分子科学中心第五届学术委员会委员 2019年1月印度喀拉拉邦"THEERUDITE"学者到圣雄甘地大学做学术报告和公众演讲 2019年至今Polymer执行委员会委员

研究领域

基于烯烃聚合催化剂和催化机理,开展金属有机化学的基础和应用研究。主要开展配合物型催化剂的设计、合成和催化机理研究,力图发现新颖、高效聚烯烃催化剂,分离催化中间体,解释不同催化剂差异的结构基础和催化机理,为国家聚烯烃工业催化剂的开发铺路。 基于国家聚烯烃产业的巨大需求,利用课题组基础研究结果,与国内外聚烯烃研发机构合作,推动催化剂应用研究,在高分子量聚乙烯、高支化线性聚乙烯,以及含极性单体聚乙烯等新型聚乙烯材料实用催化剂和催化工艺开发中有所贡献。强化环烯烃聚合和共聚催化工艺研究,提高材料的实用性和性能。 基于配位催化的理念和Ziegler-Natta催化中内(外)给电子体的作用,设计合成给电子体有机化合物,应用于提高运行中Ziegler-Natta催化剂的效率,改善聚烯烃树脂的结构和性能。 为了解决我国化工基础原料α-烯烃生产的关键问题,课题组数年来,努力设计合成新型乙烯齐聚催化剂,为工业研究院提供基础研究支撑,配合工业研究院的研究和中试放大。 开展双金属配合物的设计与合成,用于新型烯烃聚合催化剂开发研究;探询两个烯烃聚合催化剂复合时动力学和热力学吻合的催化条件和体系,推动聚烯烃基础和应用发展。

近期论文

查看导师新发文章 (温馨提示:请注意重名现象,建议点开原文通过作者单位确认)

Zheng Wang, Ziwei, Zhao, Yong Li, Yanxia Zhong,Qiuyue Zhang,Qingbin Liu, Gregory A. Solan, Yanping Ma and Wen-Hua Sun,Ruthenium-catalyzed Hydrogenation of CO2 as a Route to Methyl Esters for use as Biofuels or fine Chemicals, Chemical Science, 2020, DOI: 10.1039/D0SC02942D Hongyi Suo, Qiang Chen, Wenjuan Zhang, Yanping Ma and Wen-Hua Sun, Methylene-bridged bis(8-arylimino)-5,6,7-trihydro-quinolylinickel precatalysts for ethylene polymerization, Journal of Polymer Science, 2020, 58, 1675–1686. DOI: 10.1002/pol.20200195 Qiuyue Zhang, Randi Zhang, Mingyang Han, Wenhong Yang, Tongling Liang and Wen-Hua Suna, 4,4'-difluorobenzhydryl-modified bis(imino)-pyridyliron(II) chlorides as thermally stable precatalysts for strictly linear polyethylenes with narrow dispersity, Dalton Transactions, 2020, 49, 7384 – 7396.DOI: 10.1039/D0DT01344G Muhammad Zada, Arumugam Vignesh, Hongyi Suo, Yanping Ma, Hua Liu, and Wen-Hua Sun,NNN-type iron(II) complexes consisting sterically hindered dibenzocycloheptyl group: Synthesis and catalytic activity towards ethylene polymerization, Molecular Catalysis, 2020,492, 110981. DOI: 10.1016/j.mcat.2020.110981 Wenhua Lin, Liping Zhang, Hongyi Suo, Arumugam Vignesh, Nighat Yousuf, Xiang Hao and Wen-Hua Sun, Achieving Characteristic Polyisoprenes through Rationally Designed Iminopyridyl Metal (Fe & Co) Precatalysts: Investigation of Co-catalysts and Steric Influence on their Catalytic Activity, New Journal of Chemistry, 2020, 44, 8076 - 8084. DOI: 10.1039/D0NJ00942C. Muhammad Zada, Arumugam Vignesh,Liwei Guo, Randi Zhang,Wenjuan Zhang, Yanping Ma,Yang Sun and Wen-Hua Sun, Sterically and electronically modified aryliminopyridyl-nickel bromide precatalysts for an access to branched polyethylene with vinyl/vinylene end group, ACS Omega 2020, 5, 10610−10625. DOI: 10.1021/acsomega.0c01208 Ana Maria Faisca Phillips, Hongyi Suo, Maria de Fátima C. Guedes da Silva, Armando J. L. Pombeiro and Wen-Hua Sun, Recent developments in vanadium-catalyzed olefin coordination polymerization, Coordination Chemistry Reviews, 2020, 416, 213332. DOI: 1016/​j.​ccr.​2020.213332. Mingyang Han, Qiuyue Zhang, Ivan I. Oleynik, Hongyi Suo, Gregory A. Solan, Irina V. Oleynik, Yanping Ma, Tongling Liang and Wen-Hua Sun, High molecular weight polyethylenes of narrow dispersity promoted using bis(arylimino)cyclohepta[b]pyridine-cobalt catalysts ortho-substituted with benzhydryl & cycloalkyl groups, Dalton Transactions, 2020, 49, 4774 - 4784. DOI: 10.1039/D0DT00576B Artem A. Antonov, Wen-Hua Sun, and Konstantin P. Bryliakov, New family of single-component Ni catalysts for ethylene polymerization to high and ultrahigh molecular weight polyethylene, Sci China Chem, 2020, 63, https://doi.org/10.1007/s11426-020-9708-3 Shi-Fang Yuan, Zhe Fan, Qiuyue Zhang, Zygmunt Flisak, Yanping Ma, Yang Sun, and Wen-Hua Sun, Enhancing performance of α-diiminonickel precatalyst for ethylene polymerization by substitution with the 2,4-bis(4,4'-dimethoxybenzhydryl)-6-methylphenyl group, Applied Organometallic Chemistry, 2020, 34, DOI: 10.1002/aoc.5638 Shi-Fang Yuan, Yi Yan, Gregory A. Solan, Yanping Ma and Wen-Hua Sun, Recent advancements in N-ligated group 4 molecular catalysts for the (co)polymerization of ethylene, Coordination Chemistry Reviews, 2020, 411, 213254. DOI: 1016/​j.​ccr.​2020.​213254. Xin-E Duan, Bo Yuan, Rui Li, Arumugam Vignesh, Chantsalnyam Bariashir, Zilong Li, Sheng-Di Bai, Yanping Ma, Jian-Bin Chao, Hong-Bo Tong, and Wen-Hua Sun, Alkyl substituents triggered an unexpected formation of mono-and dinuclear zirconium hydrazonate complexes: synthesis, characterization and their catalytic behavior toward ethylene polymerization,Applied Organometallic Chemistry, 2020, 34, e5586. DOI:10.1002/aoc.5586. Wenhong Yang, Timothy Tizhe Fidelis, and Wen-Hua Sun, Prediction of Catalytic Activities of Bis(imino)pyridine Metal Complexes by Machine Learning, Journal of Computational Chemistry, 2020,41, 1064–1067. DOI: 10.1002/JCC.26160 Badral Gansukh, Qiuyue Zhang, Zygmunt Flisak, Tongling Liang, Yanping Ma, and Wen-Hua Sun, The chloro-substituent enhances performance of 2,4-bis(imino)pyridylchromium catalysts yielding highly linear polyethylene, Applied Organometallic Chemistry, 2020, 34, e5471. DOI:10.1002/aoc.5471. Arumugam Vignesh, Qiuyue Zhang, Yanping Ma, Tongling Liang, and Wen-Hua Sun, Attaining highly branched polyethylene elastomers by employing modified α-diiminonickel(II) catalysts: Probing the effects of enhancing fluorine atom on the ligand framework towards mechanical properties of polyethylene, Polymer, 187 (2020),122089. DOI:10.1016/j.polymer.2019.122089. Wenhong Yang, Timothy Tizhe Fidelis, Wen-Hua Sun, Machine Learning in Catalysis, From Proposal to Practicing, ACS Omega 2020, 5, 83-88. DOI:acsomega.9b03673 Igor E. Soshnikov, Nina V. Semikolenova, Konstantin P. Bryliakov, Artem A. Antonov, Wen-Hua Sun, Evgenii P. Talsi, The nature of nickel species formed upon the activation of α-diimine nickel(II) precatalyst with alkylaluminum sesquichlorides, Journal of Organometallic Chemistry, 2020, 907, 1210632019. DOI: https://doi.org/10.1016/j.jorganchem.2019.121063 Badral Gansukh, Randi Zhang, Jingjing Guo, Wenjuan Zhangand Wen-Hua Sun, Paradox of late transition-metal catalysts in ethylene polymerization, General Chemistry, 2020, 6, 190031. DOI: 10.21127/yaoyigc20190031 Jiaxin Li, Qiuyue Zhang, Xinquan Hu, Yanping Ma, Gregory A. Solan, Yang Sun and Wen-Hua Sun, 2-Acetyloxymethyl-substituted 5,6,7-trihydroquinolinyl-8-ylideneamine-Ni(II) chlorides and their application in ethylene dimerization/trimerization, Applied Organometallic Chemistry, 2020, 34, e5254. DOI: DOI: 10.1002/aoc.5254 Jingjing Guo, Wenjuan Zhang, Ivan I. Oleynik,Gregory A. Solan, Irina V. Oleynik, Tongling Liang, Wen-Hua Sun, Probing the effect of ortho-cycloalkyl ring size onactivity and thermostability in cycloheptyl-fused N,N,N-iron ethylene polymerization catalysts, Dalton Transactions, 2020,49, 136-146. DOI: 10.1039/C9DT04325J

推荐链接
down
wechat
bug