个人简介
Education
2002-2007: Ph.D., Dalian Institute of Chemical Physics,CAS (Advisor: Zhengkun Yu)
2005: Exchange Student, University of Ottawa (Advisor: Howard Alper)
2002-2003: Basic Courses Study, University of Science and Technology of China
1998-2002: B.S., Hubei University
Experience
2013-present: Full Professor, Sun Yat-Sen University
2010-2013: Post-Doctoral Fellow, Colorado State University (Advisor: Tomislav Rovis)
2008-2010: Post-Doctoral Fellow, University of Toronto (Advisor: Vy M. Dong)
近期论文
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Huang, N.; Luo, J.; Liao, L.; Zhao, X.* Catalytic Enantioselective Aminative Difunctionalization of Alkenes. J. Am. Chem. Soc. 2024, 146, 7029-7038.
Jiang, Q.; Luo, J.; Zhao, X.* Enantioselective cross-dehydrogenative coupling enabled by organocatalysis. Green. Chem. 2024, DOI: 10.1039/D3GC04154A.
Liang, Y.;# Huang, H.;# Huang, N.;# Liao, L.*; Zhao, X.* Catalytic Enantioselective Construction of Chiral γ-Azido Nitriles through Nitrile Group-Promoted Electrophilic Reaction of Alkenes. (# These authors contributed equally to this work) Org. Lett. 2023, 25, 6757-6762.
Huang, N.; Liao, L.; Zhao, X.* Intermolecular Hydrazinative Halogenation of Alkenes with Potassium Halides as Nucleophilic Halogen Sources: Modular Entry to Phenelzine Derivatives. Org. Lett. 2023, 25, 6587-6592.
Liu, P.; Zhong, F.; Liao, L.; Tan, W.*; Zhao, X.* Progress in the Construction of Spirocyclohexadienone Derivatives via Alkyne-involving Dearomatization. Chin. J. Org. Chem. 2023, 43, 4019-4035.
Zhang, Y.; Wu, J.; Qiu, W.; Liao, L.*; Wang, B.; Zhao, X.* Lewis Acid-Mediated Electrophilic Thiolative Difunctionalization of Enimides: Rapid Access to β-Amino Sulfides. Org. Lett. 2023, 25, 5173-5178.
Liang, Y.; Jiao, H.; Zhang, H.; Wang, Y.-Q. Zhao, X.* Chiral Chalcogenide-Catalyzed Enantioselective Electrophilic Hydrothiolation of Alkenes. Org. Lett. 2022, 24, 7210-7215.
Liao, L.; Xu, X.; Ji, J.; Zhao, X.* Asymmetric Intermolecular Iodinative Difunctionalization of Allylic Sulfonamides Enabled by Organosulfide Catalysis: Modular Entry to Iodinated Chiral Molecules. J. Am. Chem. Soc. 2022, 144, 16490-16501.
Liao, L.; Zhao, X.* Indane-Based Chiral Aryl Chalcogenide Catalysts: Development and Applications in Asymmetric Electrophilic Reactions. Acc. Chem. Res. 2022, 55, 2439-2453.
Wei, W.; Zhao, X.* Organoselenium-Catalyzed Cross-Dehydrogenative Coupling of Alkenes and Azlactones. Org. Lett. 2022, 24, 1780-1785.
Cui, F.-H.;# Hua, Y.;# Lin, Y.-M.*; Fei, J.; Gao, L.-H.; Zhao, X.; Xia, H.* Selective Difunctionalization of Unactivated Aliphatic Alkenes Enabled by a Metal–Metallaaromatic Catalytic System. (# These authors contributed equally to this work) J. Am. Chem. Soc. 2022, 144, 2301-2310.
Zhong, F.; Zhao, X.* Selective Transformations of Carbonyl Derivatives via Selenium Catalysis. Chin. J. Org. Chem. 2022, 42, 314-315.
Jiang, Q.;# Li, H.;# Zhao, X.* Catalytic Electrophilic Thiocarbocyclization of Allenes.(# These authors contributed equally to this work) Org. Lett. 2021, 23, 8777-8782.
Liao, L.; Zhao, X.* Modern Organoselenium Catalysis: Opportunities and Challenges. Synlett 2021, 32, 1262-1268.
Luo, J.; Zhang, Y.; Zhong, F.; Zhao, X.* Catalytic Enantioselective Construction of Chiral Benzo-Fused N-Heterocycles through Friedel-Crafts-Type Electrophilic Chlorination. CCS Chem. 2021, 3, 1363-1375.
Zhang, Y.; Liang, Y.; Zhao, X.* Chiral Selenide-Catalyzed, Highly Regio- and Enantioselective Intermolecular Thioarylation of Alkenes with Phenols. ACS Catal. 2021, 11, 3755-3761.
Liao, L.; Zhao, X.* Selenium-Catalyzed Functionalization of Alkynes. Chem. Lett. 2021, 50, 1104-1113.
Jiang, Q.; Zhao, X.* Chiral Bifunctional Chalcogenide-Catalyzed Enantioselective Electrophilic Thiofunctionalization of Alkenes. Chin. J. Org. Chem. 2021, 41, 443-454.
Guo, R.; Liu, Z.; Zhao, X.* Efficient Synthesis of P-Chirogenic Compounds Enabled by Chiral Selenide-Catalyzed Enantioselective Electrophilic Aromatic Halogenation. CCS Chem. 2020, 2, 2617-2628.
Wei, W.; Zhao, X. Selenopyrylium and Benzoselenopyrylium Salts (Uptate 2020). Science of Synthesis Knowledge Updates, 2020, 3, 435-458.
Jiang, Q.; Liang, Y.; Zhang, Y.; Zhao, X.* Chalcogenide-Catalyzed Intermolecular Electrophilic Thio- and Halofunctionalization of gem-Difluoroalkenes: Construction of Diverse Difluoroalkyl Sulfides and Halides. Org. Lett. 2020, 22, 7581-7587.
Xu, Y.; Liao, L.; Zhao, X.* Progress in the Synthesis of Aza-Heterocyclic Compounds via Selenium-π-Acid Catalysis. Chemistry (Huaxue Tongbao) 2020, 83, 970-976.
Liao, L.; An, R.; Li, H.; Xu, Y.; Wu, J.-J.; Zhao, X.* Catalytic Access to Functionalized Allylic gem‐Difluorides via Fluorinative Meyer‐Schuster‐Like Rearrangement. Angew. Chem. Int. Ed. 2020, 59, 11010-11019.
Liang, Y.; Ji, J.; Zhang, X.; Jiang, Q.; Luo, J.; Zhao, X.* Enantioselective Construction of Axially Chiral Amino Sulfide Vinyl Arenes by Chiral Sulfide‐Catalyzed Electrophilic Carbothiolation of Alkynes. Angew. Chem. Int. Ed. 2020, DOI:10.1002/anie.201915470.
Wei, W.; Liao, L.; Qin, T.; Zhao, X.* Access to Saturated Thiocyano-Containing Azaheterocycles via Selenide-Catalyzed Regio- and Stereoselective Thiocyanoaminocyclization of Alkenes. Org. Lett. 2019, 21, 7846-7850.
Liang, Y.; Zhao, X.* Enantioselective Construction of Chiral Sulfides via Catalytic Electrophilic Azidothiolation and Oxythiolation of N-Allyl Sulfonamides. ACS Catal. 2019, 9, 6896-6902.
Li, H.; Liao, L.; Zhao, X.* Organoselenium-Catalyzed Aza-Wacker Reactions: Efficient Access to Isoquinolinium Imides and an Isoquinoline N-Oxide.Synlett 2019, 30, 1688-1692.
Cao, Q.; Luo, J.; Zhao, X.* Chiral Sulfide Catalysis for Desymmetrizing Enantioselective Chlorination. Angew. Chem. Int. Ed. 2019, 58, 1315-1319.
Qin, T.; Jiang, Q.; Ji, J.; Luo, J.; Zhao, X.* Chiral selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated 2,5-disubstituted oxazolines. Org. Biomol. Chem. 2019, 17, 1763-1766.
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