个人简介
1999.9-2003.7 青岛大学，本科，化学专业
2003.9-2006.1 南开大学，硕士，无机化学专业
2006.9-2010.9 新加坡南洋理工大学，博士，有机化学专业
2010.10-2012.2新加坡南洋理工大学，博士后，有机化学专业
研究领域
有机硅合成及应用研究。
新型有机金属有机试剂制备、合成及应用研究。
药物活性分子和天然产物有机分子的合成研究
近期论文
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1) Catalytic Asymmetric Conjugate Protosilylation and Protoborylation of 2‑Trifluoromethyl Enynes for Synthesis of Functionalized Allenes
Org. Lett. 2020, 22, 1360-1367.
2) Synthesis of Functionalized Vinylsilanes via Metal-Free Dehydrogenative Silylation of Enamides
Org. Lett. 2020, 22, 1326-1330.
3) Palladium(II)-Catalyzed Stereospecific Alkenyl C–H Bond Alkylation of Allylamines with Alkyl Iodides
ACS Catal. 2019, 9, 4271-4276.
4) Divergent Protosilylation and Protoborylation of Polar Enynes
Org. Lett. 2019, 21, 2932-2936.
5) Palladium-Catalyzed Cycloaromatization/Alkylation of o-(Alkynyl)styrenes
J. Org. Chem. 2019, 84, 12848-12855.
4) Palladium-Catalyzed Dialkylation of C–C Triple Bonds: Access to Multi-Functionalized Indenes
Org. Lett. 2019, 21, 3696-3700.
5) Palladium-Catalyzed Cascade Intramolecular Cyclization and Allylation of Enynoates with Allylic Alcohols
J. Org. Chem. 2019, 84, 6729-6736.
6) Copper-catalyzed regiodivergent 1,4- and 1,6-conjugate silyl addition to diendioates: access to functionalized allylsilanes
Org. Biomol. Chem. 2019, 17, 6122–6126.
7) Copper-Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes
Angew.Chem. Int.Ed. 2019, 58, 16538–16542.
8) Macrolide Synthesis through Intramolecular Oxidative Cross-Coupling of Alkenes
Angew.Chem. Int. Ed. 2018, 57, 5555 –5559.
9) Catalytically Asymmetric Synthesis of 1,3-Bis(silyl)propenes via Copper-Catalyzed Double Proto-Silylations of Polar Enynes.
ACS Catal. 2018, 8, 5306-5312.
10) Copper-Catalyzed Stereo- and Enantioselective 1,4-Protosilylation of alpha,beta-Unsaturated Ketimines To Synthesize Functionalized Allylsilanes
ACS Catal. 2018, 8, 6239-6245.
11) Palladium-catalyzed silaborative carbocyclization of 1,6-diynes
Chem. Commun. 2018, 54, 2357-2360.
12) Copper-Catalyzed Dehydrogenative Diels-Alder Reaction
Org. Lett. 2018, 20, 3215-3219.
13) Multi-catalyst promoted asymmetric relay reactions.
Org. Chem. Front. 2018, 5, 2765-2768.
14) Palladium-Catalyzed Regioselective Olefination of O‑Acetyl Cyanohydrins.
J. Org. Chem. 2018, 83, 8265-8271.
15) Palladium-Catalyzed One-Pot Highly Regioselective 6-Endo Cyclization and Alkylation of Enynoates: Synthesis of 2‑Alkanone Pyrones
J. Org. Chem. 2018, 83, 13414-13426.
16) Copper-Catalyzed Silylperoxidation Reaction of α,β-Unsaturated Ketones, Esters, Amides, and Conjugated Enynes
ACS Catal. 2017, 7, 7120-7125.
17) Chelation versus Non-Chelation Control in the Stereoselective Alkenyl sp2 C-H Bond Finctionalization Reaction
Angew.Chem. Int.Ed. 2017, 56, 5091 –5095.
18) Palladium-Catalyzed Direct Intramolecular C−N Bond Formation: Access to Multisubstituted Dihydropyrroles
Org. Lett. 2017, 19, 914-917.
19) Direct coupling of sp3 carbon of alkanes with α,β-unsaturated carbonyl compounds using a copper/hydroperoxide system
Org. Chem. Front. 2017, 4, 1411-1415.
20) Copper-catalyzed silylation reactions of propargyl epoxides: easy access to 2,3-allenols and stereodefined alkenes
Chem. Commun. 2017, 57, 9344-9347.
21) Palladium-catalyzed Silylation reaction between benzylic halides and silylboronate
Chem. Commun. 2016, 52, 5609-5612.
22) Palladium-catalyzed cross-coupling of enamides with sterically hindered alpha-bromocarbonyls
Chem. Commun. 2016, 52, 5617-5620.
23) Pd-Catalyzed Intramolecular C-N Bond Cleavage, 1,4-Migration, sp(3) C-H Activation, and Heck Reaction: Four Controllable Diverse Pathways Depending on the Judicious Choice of the Base and Ligand
J. Am. Chem. Soc. 2015, 137, 1341-1347.
24) Stereo- and Chemoselective Cross-Coupling between Two Electron-Deficient Acrylates: An Efficient Route to (Z, E)-Muconate Derivatives
J. Am. Chem. Soc. 2015, 137, 3169-3172.
25) Synthesis of Highly Substituted Racemic and Enantioenriched Allenylsilanes via Copper-Catalyzed Hydrosilylation of (Z)‑2-Alken-4-ynoates with Silylboronate
J. Am. Chem. Soc. 2015, 137, 14830–14833.
26) Copper-Catalyzed Enantioselective Conjugate Addition of Grignard Reagents to Methyl 4,4,4-Trifluorocrotonate: Synthesis of Enantioenriched Trifluoromethylated Compounds
Chem. Asian. J. 2015, 10, 844-848.
27) Palladium-Catalyzed Difunctionalization of Internal Alkynes via Highly Regioselective 6-Endo Cyclization and Alkenylation of Enynoates: Synthesis of Multisubstituted Pyrones
Org. Lett. 2015, 17, 1636-1639.
28) Palladium-Catalyzed Intermolecular Oxylation of Vinylacetates with Retention of an Alkenyl Moiety
Org. Lett. 2015, 17, 3462-3465.
29) B(C6F5)3: A New Class of Strong and Bulky Lewis Acid forExo-Selective Intermolecular Diels–Alder Reactions of Unreactive Acyclic Dienes with α,β-Enals
Org. Lett. 2015, 17, 4432-4435.
30) Highly Enantioselective and Anti-Diastereoselective Catalytic Intermolecular Glyoxylate–Ene Reactions: Effect of the Geometrical Isomers of Alkenes
Org. Lett. 2015, 17, 2736-2739.
31) Synthesis of multi-substituted pyrroles using enamides and alkynes catalyzed by Pd(OAc)(2) with molecular oxygen as an oxidant
Chem. Commun. 2014, 50, 2784-2786.
32) Synthesis of multi-substituted vinylsilanes via copper(I)-catalyzed hydrosilylation reactions of allenes and propiolate derivatives with silylboronates
Chem. Commun. 2014, 50, 7195-7197.
Palladium-Catalyzed Direct Alkynylation of N-Vinylacetamides
Adv. Synth. Cat. 2014, 356, 1539-1543.
33) Mild Rh(III)-Catalyzed Direct C-H Bond Arylation of (Hetero)Arenes with Arylsilanes in Aqueous Media
Org. Lett. 2014, 16, 2614-2617.
34) Preparation of highly substituted (β-acylamino)acrylates via iron-catalyzed alkoxycarbonylation of N-vinylacetamides with carbazates
Chem. Commun. 2014, 50, 11661-11664.
35) Palladium-catalyzed cross-coupling of simple alkenes with acrylates: a direct approach to 1,3-dienes through C-H activation
Chem. Sci. 2013, 4, 4520-4524.
36) Palladium-catalyzed alkenyl C-H bond sulfonylation reaction using organosulfonyl chlorides
Tetrahedron 2013, 69 4403-4407 (Invited)
37) Synthesis of Dienyl Ketones via Palladium(II)-Catalyzed Direct Cross-Coupling Reactions between Simple Alkenes and Vinyl Ketones: Application to the Synthesis of Vitamin A1 and Bornelone
Org. Lett. 2013, 15, 5531-5533.
38) Palladium-Catalyzed Direct C-H Arylation of Enamides with Simple Arenes
Angew. Chem. Int. Ed. 2012, 51, 5701-5705.
39) Palladium-Catalyzed Cross-Coupling of Unactivated Alkenes with Acrylates: Application to the Synthesis of the C13–C21 Fragment of Palmerolide A
Chem. Eur. J. 2012, 18, 13284-13287.
40) Organoindium Reagents: The Preparation and Application in Organic Synthesis
Peng Loh*
Chem. Rev. 2013, 113, 271-401.
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