龚流柱 - 中国科学技术大学 - 合肥微尺度物质科学国家研究中心

个人简介

1989.09~1993.07 河南师范大学化学系，化学教育专业，理学学士； 1993.09~1996.07 中国科学院成都有机化学研究所，有机合成，理学硕士； 1996.09~1998.06 中国科学院化学研究所，有机合成, 博士生； 1998.06~2000.06 美国弗吉尼亚大学化学系，访问学者（联合培养博士生） 2000.08~2000.11 中国科学院成都有机化学研究所，助理研究员； 2000.12-2001.11 中国科学院成都有机化学研究所，副研究员； 2001.12-2005.12 中国科学院成都有机化学研究所，研究员，博士生导师，不对称合成和手性技术四川省重点实验室常务副主任，主任； 2003.10-2004.09 德国慕尼黑大学有机化学研究所, 洪堡学者，访问教授； 2006.01-至今中国科学技术大学化学系，合肥微尺度物质科学国家实验室（筹），教授。获奖及荣誉 2003年先后获“德国洪堡研究奖学金”，“国家杰出青年基金”和“中国化学会青年化学奖”。2005年获“中国化学会有机合成创造奖”，“中国科学院优秀导师奖”和“国务院政府特殊津贴”。

研究领域

有机合成方法学，不对称催化和天然产物合成。

近期论文

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Chiral Phosphoramidite Ligand-Modulated Palladium Auto-tandem Catalysis for Asymmetric Dehydrogenative Dienylation of Imines with α-Alkenes Publication Date: Dec 20, 2024 Remote Enantioselective ε-Alkylation of Copper Ethynylallenylidenes: Precise Control of Central and Axial Chirality Angew. Chem. Int. Ed. 2024, e202416089 Asymmetric Bromination/Semipinacol Rearrangement Enabled by Brønsted Acids of Stereogenic-at-Cobalt(III) Complexes J. Org. Chem. 2024 Palladium-Catalyzed Branch-Selective Allylic C–H Amination Enabled by Nucleophile Coordination Org. Lett. 2024 Enantioselective Synthesis of Chiral 1,4-Enynes via Palladium-Catalyzed Branch-Selective Allylic C–H Alkylation ACS Catal. 2024, 14, 14855−14862 Catalytic Asymmetric Dearomative [2 + 2] Photocycloaddition/Ring-Expansion Sequence of Indoles with Diversified Alkenes J. Am. Chem. Soc. 2024, 146, 23457−23466 Nickel-Catalyzed Enantioconvergent Allenylic Amination of Allenols Activated by Hydrogen-Bonding Interaction with Methanol Angew. Chem. Int. Ed. 2024, e202410743 Photoinduced Decatungstate Anion-Catalyzed 1,4-Difunctionalization of 1,3-Butadienes via C–H Activation Org. Lett. 2024, 26, 5528−5533 Photoinduced Pd-Catalyzed Enantioselective Carboamination of Dienes via Aliphatic C–H Bond Elaboration J. Am. Chem. Soc. 2024, 146, 17, 12053–12062 Rhodium and Isothiourea Dual Catalysis: Enantiodivergent Transformation of Terminal Alkynes Org. Lett. 2024, 26, 7, 1421–1425 Enantioselective synthesis of β- and α-amino ketones through reversible alkane carbonylation Nat. Synth. 3, 507–516 (2024) Enantio-and Diastereodivergent N-Heterocyclic Carbene/Nickel Dual-Catalyzed Umpolung Propargylic Substitutions of Enals J. Am. Chem. Soc. 2023, 145, 51, 28085–28095 213.Lewis Base/3d Transition-Metal Cooperatively Catalyzed Asymmetric Reactions Synlett 2023, 34, A–H 212.Atom Transfer Radical Coupling Enables Highly Enantioselective Carbo-Oxygenation of Alkenes with Hydrocarbons J. Am. Chem.Soc. 2023, 145, 22031−22040 211.Enantioconvergent Palladium-Catalyzed Alkylation of Tertiary Allylic C−H Bonds Angew. Chem.Int. Ed. 2023, 62, e2023125 210.Asymmetric construction of phosphono dihydropyranones from α-ketophosphonates enabled by Pd/chiral isothiourea relay catalysis Org. Biomol. Chem. 2023, 21, 7305–7310 209.Organo–metal cooperative catalysis for C(sp3)–H alkylation polymerization Nat. Synth. 2, 1232–1242 (2023) 208. Access to Fluorinated Quaternary Stereogenic Centers via Palladium-Catalyzed Asymmetric Allylic C–H Alkylation Synlett 2023, 34, A–F 207.Feng chiral N,N′-dioxide ligands: uniqueness and impacts Org. Chem. Front., 2023,10, 3676-3683 Asymmetric redox benzylation of enals enabled by NHC/Ru cooperative catalysis Sci. Adv. 9, eadf5606(2023) Cooperative Dual Organocatalytic Asymmetric Decarboxylative [4 + 3] Annulations with Benzoxazinanones Precis. Chem. 2023, 1, 241–247 Chiral Bisphosphoric Acids and Their Applications in Asymmetric Catalysis Chem.Rec. 2023, e202300049 Pd-Catalyzed Asymmetric Allylic C-H Functionalization Chin. J. Chem. 2023,41, 1841—1848 Diastereodivergent Desymmetric Annulation to Access Spirooxindoles: Chemical Probes for Mitosis J. Am. Chem. Soc. 2023, 145, 7, 4199–4207