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研究领域

1、有机合成方法学 主要研究过渡金属催化下的碳-碳、碳-氮、碳-氧偶联反应新体系。 2、超分子化学 主要以瓜环[n](n=6, 7, 8)为主体,以含三联吡啶钌、菲罗啉、咪唑、紫精、香豆素等结构片段的衍生物及药物分子为客体进行分子识别、组装及荧光探针方面的研究。 3、药物及其中间体的合成

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One-pot double benzylation of 2-substituted pyridines using palladium-catalyzed decarboxylative coupling of sp2 and sp3 carbons. Yaping Wang, Xinjian Li, Faqiang Leng, Helong Zhu, Jingya Li, Dapeng Zou*, Yangjie Wu, Yusheng, Wu, Adv. Syn. & catal. 2014, 356(16), 3307-3313. Cucurbit[7]uril promoting PdCl2-catalyzed cross-coupling reaction of benzyl halides and arylboronic acids in aqueous media. Guangkuan Zhao, Zhen Wang, Ruixin Wang, Jingya Li, Dapeng Zou*, Yangjie Wu, Tetrahedron Lett., 2014, 55, 5319-5322. Preparation of tert-Butyl Esters via Pd-catalyzed tert-Butoxycarbonylation of (Hetero)aryl Boronic Acid Derivatives. Xinjian Li, Dapeng Zou, Helong Zhu, Yaping Wang, Jingya Li, Yangjie Wu, Yusheng Wu. Org. Lett., 2014, 16, 1836-1839. A Metal-free Route to CF3-Containing Oxindoles by PhI(OAc)2-Mediated Trifluoromethylation of N-Arylacylamides with TMSCF3. Weijun Fu, Fengjuan Xu, Yuqin Fu, Chen Xu, Shihui Li, Dapeng Zou*. Eur. J. Org. Chem. 2014, 709-712. Facile synthesis of trifluoroethyl compounds by the Suzuki cross-coulping reactions of CF3CH2OTs with arylboronic acids. Faqiang Leng, Yaping Wang, Hui Li, Jingya Li, Dapeng Zou,* Yangjie Wu, Yusheng Wu, Chem. Commun, 2013, 49, 10697-10699. Synthesis of 3,3-Disubstituted Oxoindoles by Visible-Light-Mediated Radical Reactions of Aryl Diazonium Salts with N-Arylacrylamides. Weijun Fu, Fengjuan Xu, Yuqin Fu, Mei Zhu, Jiaqi Yu, Chen Xu, Dapeng Zou*. J. Org. Chem., 2013, 78(23), 12202-12206. Highly efficient synthesis if aryl and heteroaryl trifluoromethyl ketones via o-iodobenzoic acid(IBX), Huicheng Cheng, Yu Pei, Faqiang Leng, Jingya Li, Apeng Liang, Dapeng Zou,* Yangjie Wu, Yusheng Wu, Tetrahedron Lett., 2013, 54, 4483-4486. Formation and Rupture of a Supramolecular Nanocapsule Triggered on–off–on Supramolecular Switch for Zn2+, Song Jiang, Man Liu, Yanting Cui, Dapeng Zou,* and Yangjie Wu , Eur. J. Org. Chem. 2013, 13, 2591-2596. Guest-size determining the selective binding modes of cucurbit[8]uril, electron-rich guests and N-alkyl-N´-methyl-4, 4´-bipyridinium”, Song jiang, Xiaona Yang, Chunxue Yang, Mingqiong Tong, Dapeng Zou,* Yangjie Wu, Tetrahedron Lett., 2013, 54, 1638-1644. Arylation of 2-substituted pyridines via Pd-catalyzed decarboxylation cross-coupling reactions of 2-picolinic, Xinjian li, Dapeng Zou, Faqiang Leng, Chunxia Sun, Jingya Li, Yangjie Wu, Yusheng Wu, Chem. Commun, 2013, 49, 312-314. The palladium-catalyzed cross-coupling reactions of trifluoroethyl iodide with aryl and heteroaryl boronic acid esters, Apeng Liang, Xinjian Li, Dongfeng Liu, Jingya Li, Dapeng Zou,* Yangjie Wu and Yusheng Wu, Chem. Commun, 2012, 48, 8273-8275. Palladium-catalyzed SuzukieMiyaura cross-coupling reaction of potassium 2-pyridyl trifluoroborate with aryl (heteroaryl) halides, Wei Ren, Jingya Li, Dapeng Zou,*, Yangjie Wu, Yusheng Wu, Tetrahedron, 2012, 68, 1351-1358. Aminomethylation via Cyclopalladated-Ferrocenylimine-Complexes-Catalyzed Suzuki-Miyaura Coupling of Aryl Halides with Potassium N,N-Dialkylaminomethyltrifluoroborates, Dapeng Zou, Hongmeng Cui, Lijin Qin, Jingya Li, Yangjie Wu, Yusheng Wu, synlett, 2011,349-356. Pd-catalyzed amidation of aryl(Het) halides with tert-butyl carbamate", Lijin Qin, Hongmeng Cui, Dapeng Zou*, Jingya Li, Yangjie Wu, Zhiwu Zhu, Yusheng Wu, Tetrahedron lett. 2010, 51, 4445-4448. Light driven formation of a supramolecilar system with CB[8]s locked between redox-active Ru(bpy)3 complexes, Samir Andersson, Dapeng Zou, Rong Zhang, Shiguo Sun, Licheng Sun. Org. Biomol. Chem. 2009, 17, 3605-3609. Selective positioning of CB[8] on two linked viologens and electrochemically driven movement of the host compound, Samir Andersson, Dapeng Zou, Rong Zhang, Shiguo Sun, Björn Åkermark, Licheng Sun. Eur. J. Org. Chem., 2009, 1163-1172. Host-induced intromocular charge-transfer complex formation: Binding interactions between the host cucurbit[8]uril and the guest containing Ru(bpy)3-MV2+-Naphthol, Dapeng Zou, Samir Andersson, Rong Zhang, Björn Åkermark, Licheng Sun. J. Org. Chem., 2008, 73, 3775-3783. Selective binding of Cucurbit[7]uril and β-Cyclodextrin with a Redox-active Molecular triad Ru(bpy)3-MV2+-Naphthol, Dapeng Zou, Samir Andersson, Rong Zhang, Shiguo Sun, Jingxi Pan, Björn Åkermark, Licheng Sun, Chem. Comm. 2007, 4734-4736.

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