颜振宁 - 郑州大学 - 化学与分子工程学院

研究领域

1.生物小分子与有机电解质相互作用的功能溶液化学研究氨基酸和小肽具有很强的活性、多样性和重要的生物学功能，它们对人体的生命活动具有非常重要的意义。水溶液是生物分子的主要溶剂环境，其中含有许多内源性和外源性物质，这些物质对生物分子的构型和特性有很大的影响，其中电解质的影响在生物物质的物理化学性质的研究中是一个十分重要的课题。我们的研究着眼于生物小分子（例如氨基酸和小肽）与功能有机电解质（简单有机电解质、离子型表面活性剂、离子液体等）之间的相互作用。研究手段以热力学和光谱学技术为主。该研究为了解生理学体系中有机电解质对肽和氨基酸生物活性的影响以及有机电解质的科学使用提供线索。 2.功能材料离子选择性电极（ISEs）是近十多年来在电位法领域里发展起来的一种新的测试工具，它可以通过简单的电位测量直接测定溶液中某一离子的活度。离子选择性电极目前还是发展中的一门新技术，除少数品种较为成熟外，多数还不够成熟，现阶段，还面临着改进电极的选择性，提高测量精度，研制新的品种以及有关基础理论的研究等问题。我们的研究拟以各种新型有机化合物作为离子选择电极高分子膜的功能材料，制备对某些离子响应的选择电极，用于水质、土壤、食品中相关离子的检测。该项目涉及有机化学和电分析化学的前沿领域，具有重要的基础理论研究意义，在环境保护等方面具有实际应用价值。

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Zhenning Yan, Shuangyan Wu, Qi Pan, Rui Geng, Bixin Gu, Jianji Wang, Interactions of dipeptides with Triton X-100 in aqueous solution: A volumetric and spectroscopic study, J. Chem. Thermodynamics, 2014, 71, 112–117 Zhenning Yan, Rui Geng Bixin Gu, Qi Pan, Jianji Wang, Densities, electrical conductances, and spectroscopic properties of glycyl dipeptide + ionic liquid ([C12mim]Br) + water mixtures at different temperatures, Fluid Phase Equilibria, 2014, 367, 125–134 Zhenning Yan, Haixia Wang, CuiyingXu, Xiangli Wen, Bixin Gu Preparation of a new aluminum (III) selective electrode based on a hydrazone-containing benzimidazole derivative as a neutral carrier, Journal of Molecular Liquids, 2014, 190, 185–189 Zhenning Yan, Shuangqiang Wang, Haixia Wang, Shuangyan Wu, Bismuth (III) PVC membrane ion selective electrodes based on two compounds: Acylhydrazone and thiosemicarbazone with 1,3,4-thiadiazole, Materials Science and Engineering C, 2013, 33, 2562–2568 Zhenning Yan, Yanqi Lu, Haixia Wang, Shuangyan Wu, Bangtun Zhao, A heterocycle functionalizedp-tert-butylcalix[4]arene as a neutral carrier for silver (I) ion-selective electrode, Journal of Molecular Liquids, 2013, 183, 72 –78 Zhenning Yan, Ruili Liu, Shuangyan Wu, Xiangru Bai, Jianji Wang, Effect of temperature on the interactions of glycyl dipeptides with sodium perfluorooctanoate in aqueous solution: Volumetric, conductometric, and spectroscopic study, J. Chem. Thermodynamics, 2013, 57, 360–366 Zhenning Yan, Xiangru Bai, Ruili Liu, Shuangyan Wu, Jianji Wang, Effect of dipeptides on the micellization and thermodynamic parameters of sodium dodecyl sulfonate: Conductometric andfl uorimetric studies, Journal of Molecular Liquids, 2013, 177, 78 –84 Zhenning Yan, Yuanchao Pei, Jing Fan, Shuangqiang Wang, Jianji Wang, Selective electrodes for [PF6]− and [BF4]− anions based on the associates formed by ionic liquid and cationic dyes, Materials Science and Engineering C, 2013, 33, 356–361 Zhenning Yan, Xiaolan Wang, Xiangru Bai, Shuangqiang Wang, Jianji Wang, Volumetric, conductometric and fluorescence probe studies of interactions between glycyl dipeptides and sodium caprylate in aqueous media, J. Chem. Thermodynamics, 2012, 52, 89–94 Zhenning Yan, Junying Dan, Liqin Li, Shuangqiang Wang, Bangtun Zhao, Lead (II) ion-selective membrane electrodes based on four nitrogen-containing heterocyclic thioethers, Sensor Letters, 2012, 10, 1–9. Zhenning Yan, Xia Li, Yan Xu, Baoxian Ye, Amide and acyl-hydrazine functionalized calix[4]arenes as carriers for hydrogen phosphate selective electrodes, Electroanaysis, 2007, 19, 958-963. Zhenning Yan, Yanqi Lu, Xia Li, Silver ion-selective electrodes based on bis(dialkyldithiocarbamates) as neutral ionophores, Sens. Actuators B: Chem., 2007, 122, 174-181. Hao Zheng, Zhenning Yan, Huimin Dong, Baoxian Ye, Simultaneous determination of lead and cadmium at a glassy carbon electrode modified with Langmuir-Blodgett film of p-tert-butylthiacalix[4]arene, Sens. Actuators B: Chem., 2007, 120, 603-609. Zhenning Yan, Qian Zhang, WeiWei Li, Jianji Wang, Effect of temperature on the interactions of glycyl dipeptides with sodium dodecyl sulfate in aqueous solution: a volumetric, conductometric, and fluorescence probe study, J. Chem. Eng. Data, 2010, 55, 3560-3566. Zhenning Yan, Yang Zhao, Ronghua Xing, Xiaoge Wang, Jianji Wang, Volumetric and conductometric behavior at T=298.15 K of 2-[(2-aminoacetyl)amino]acetic acid, 2-[(2-aminoacetyl)amino]-3-methylbutanoic acid, and (2S)-2-[(2-aminoacetyl)amino]-4-methylpentanoic acid with sodium hexanoate, J. Chem. Eng. Data, 2010, 55, 759-764. Zhenning Yan, Xiaoge Wang, Ronghua Xing, Jianji Wang, Interactions of some glycyl dipeptides with sodium butyrate in aqueous solutions at 298.15 K: a volumetric and conductometric study, J. Chem. Eng. Data, 2009, 54, 1787-1792 Zhenning Yan, Weiwei Li, Qian Zhang, Xiaoge Wang, Jianji Wang, Effect of sodium caproate on the volumetric and conductometric properties of glycyl-L-glutamine and L-alanyl-L-glutamine in aqueous solution at 298.15 K, Fluid Phase Equilibria, 2011, 301, 156-162 Zhenning Yan, Qian Zhang, Weiwei Li, Xiaoge Wang, Jianji Wang, Effect of sodium caproate on the volumetric and conductometric properties of glycyl-L-glutamine and L-alanyl-L-glutamine in aqueous solution at 298.15 K，Fluid Phase Equilibria, 2011, 301, 156-162. Zhenning Yan, Ximeng Sun, WeiWei Li, Yu Li, Jianji Wang, Interactions of glutamine dipeptides with sodium dodecyl sulfate in aqueous solution measured by volume, conductivity, and fluorescence spectra, J. Chem. Thermodyn., 2011, 43, 1468-1474 Zhenning Yan, Xiaoge Wang, Ronghua Xing, Jianji Wang, Volumetric and conductometric studies on the interactions of dipeptides with sodium acetate and sodium butyrate in aqueous solutions at T = 298.15 K, J. Chem. Thermodyn., 2009, 41(12), 1343-1349 Zhenning Yan, Yu Li, Xiaolan Wang, Junying Dan, Jianji Wang, Effect of glycyl dipeptides on the micellar behavior of gemini surfactant: A conductometric and fluorescence spectroscopic study, Journal of Molecular Liquids, 2011, 161, 49-54