个人简介

龚军芳，博士、教授，河南省教育厅学术技术带头人。主要从事金属有机化学研究，近年来主持完成教育部留学回国人员科研启动费、河南省自然科学基金、国家自然科学基金等项目；目前主持河南省高校科技创新人才基金等项目。先后在Adv.Synth.Catal.;J.Org.Chem.;Organometallics;DaltonTrans.;TetrahedronLett.;J.Mol.Catal.A:Chem.等国内外期刊上发表学术论文60多篇，参与翻译、编写著作3部。获得2008年度宝钢优秀教师奖、河南省教育系统2010教学技能竞赛一等奖并获“河南省教学标兵”称号。 学习经历： 1992年获得南开大学理学学士学位， 1995年获得南开大学理学硕士学位， 1998年中国科学院化学研究所毕业，获得博士学位。 研究工作经历： 1999/10–2001/09郑州大学化学系博士后 2001/10–2003/02法国巴黎国家高等化学学校(ENSCP)博士后 2003年–至今郑州大学化学与分子工程学院(原化学系)工作承担科研项目 1.2010.1－2012.12“混合给体钳形镍化合物的合成、结构及其在催化反应中的应用”编号20972141国家自然科学基金资助项目 2.2012.1－2014.12“手性钳形钯化合物催化剂的合成与应用研究”编号2012HASTIT003河南省高校科技创新人才支持计划资助项目 3.2009.1－2012.12“非对称三齿配位钯化合物的催化性能研究”编号102101210200河南省科技攻关重大项目 4.2010.1－2012.12“含氮杂环卡宾的钯和镍化合物的合成与催化性能研究”编号2010GGJS-015河南省高等学校青年骨干教师资助计划 5.2006.01-2007.12“新型氮磷配体的合成及其在催化反应中的应用研究”编号0611012100河南省自然科学基金 6.2004.01-2005.12“多取代四氢吡喃的立体选择性合成、新型二茂铁衍生物的合成及其应用”教育部留学回国人员科研启动基金

研究领域

研究方向：金属有机化学。过渡金属催化的反应在现代有机合成中有着举足轻重的地位，所得到的产物是合成许多药物、天然产物及功能性材料等的关键中间体，具有重要的应用价值。作为一类独特的金属有机化合物，钳形金属化合物(pincermetalcomplexes)已被用于化学键的活化、发光材料、超分子化学、分子识别等领域，特别是研究发现，该类化合物也是多种催化反应的有效催化剂、在反应中表现出高的催化活性或立体选择性。近年来，我们对钳形金属化合物的合成及其在催化反应中的应用进行了研究，包括：利用廉价易得的原料、通过芳环的C-H键活化方法，合成得到了多种类型的非手性和手性钳形金属化合物，例如：PCP钳形钯化合物、PCN钳形钯和镍化合物、双(咪唑啉)NCN钳形钯、铂、镍、铑和铱化合物、NCN'钳形钯化合物、CNN'钳形钯和钌化合物等。非手性的钳形钯化合物被用于催化Suzuki、Sonogashira、醛的烯丙基化以及醛、胺和烯丙基锡的三组分反应等；钌化合物被用于酮的氢转移反应；手性的钳形钯化合物被用于催化不对称Suzuki反应、醛、N-磺酰亚胺或靛红与烯丙基锡的不对称加成反应、二芳基膦烷与a,β-不饱和酮的不对称加成反应等；铂化合物被用于吲哚与硝基烯烃的不对称傅-克烷基化反应；镍化合物被用于Suzuki和Michael加成等反应；铑化合物被用于三氟丙酮酸酯与端基炔的不对称炔基化反应、醛的烯丙基化以及三氟丙酮酸酯的羰基-烯反应等，均取得了良好的催化效果。

金属有机化学。过渡金属催化的反应在现代有机合成中有着举足轻重的地位，所得到的产物是合成许多药物、天然产物及功能性材料等的关键中间体，具有重要的应用价值。作为一类独特的金属有机化合物，钳形金属化合物(pincer metal complexes)已被用于化学键的活化、发光材料、超分子化学、分子识别等领域，特别是研究发现，该类化合物也是多种催化反应的有效催化剂、在反应中表现出高的催化活性或立体选择性。近年来，我们对钳形金属化合物的合成及其在催化反应中的应用进行了研究，包括：利用廉价易得的原料、通过芳环的C-H键活化方法，合成得到了多种类型的非手性和手性钳形金属化合物，例如：PCP钳形钯化合物、PCN钳形钯和镍化合物、双(咪唑啉)NCN钳形钯、铂、镍、铑和铱化合物、NCN'钳形钯化合物、CNN'钳形钯和钌化合物等。非手性的钳形钯化合物被用于催化Suzuki、Sonogashira、醛的烯丙基化以及醛、胺和烯丙基锡的三组分反应等；钌化合物被用于酮的氢转移反应；手性的钳形钯化合物被用于催化不对称Suzuki反应、醛、N-磺酰亚胺或靛红与烯丙基锡的不对称加成反应、二芳基膦烷与a,β-不饱和酮的不对称加成反应等；铂化合物被用于吲哚与硝基烯烃的不对称傅-克烷基化反应；镍化合物被用于Suzuki和Michael加成等反应；铑化合物被用于三氟丙酮酸酯与端基炔的不对称炔基化反应、醛的烯丙基化以及三氟丙酮酸酯的羰基-烯反应等，均取得了良好的催化效果。

近期论文

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Xin-QiHao,Yong-WeiZhao,Jing-JingYang,Jun-LongNiu,Jun-FangGong*,Mao-PingSong*.“EnantioselectiveHydrophosphinationofEnoneswithDiphenylphosphineCatalyzedbyBis(imidazoline)NCNPincerPalladium(II)Complexes.”Organometallics2014,33(7),1801-1811. http://pubs.acs.org/doi/abs/10.1021/om500144b?source=chemport ZhaoWang,ZhemingSun,Xin-QiHao,Jun-LongNiu,DonghuiWei,TaoTu,Jun-FangGong*,Mao-PingSong*.“NeutralandCationicNCNPincerPlatinum(II)Complexeswith1,3-Bis(benzimidazol-2'-yl)benzeneLigands:Synthesis,Structures,andTheirPhotophysicalProperties.”Organometallics2014,33(7),1563-1573. http://pubs.acs.org/doi/abs/10.1021/om400946n?source=chemport TaoWang,Xin-QiHao,Juan-JuanHuang,KaiWang,Jun-FangGong*,Mao-PingSong*.“ChiralCNNPincerPalladium(II)Complexeswith2-Aryl-6-(Oxazolinyl)pyridineLigands:Synthesis,Characterization,andApplicationtoEnantioselectiveAllylationofIsatinsandSuzuki-MiyauraCouplingReaction.”Organometallics2014,33(1),194-205. http://pubs.acs.org/doi/abs/10.1021/om400945d?source=chemport TaoWang,Xin-QiHao,Juan-JuanHuang,Jun-LongNiu,Jun-FangGong*,Mao-PingSong*.“ChiralBis(imidazolinyl)phenylNCNPincerRhodium(III)CatalystsforEnantioselectiveAllylationofAldehydesandCarbonyl-EneReactionofTrifluoropyruvates.”J.Org.Chem.2013,78(17),8712-8721. http://pubs.acs.org/doi/abs/10.1021/jo4014194?source=chemport TaoWang,Jun-LongNiu,Shuang-LiangLiu,Juan-JuanHuang,Jun-FangGong*,Mao-PingSong*.“ChiralNCNPincerRhodium(III)ComplexeswithBis(imidazolinyl)phenylLigands:SynthesisandEnantioselectiveCatalyticAlkynylationofTrifluoropyruvateswithTerminalAlkynes.”Adv.Synth.Catal.2013,355(5),927-937.(HighlightedbySynfacts2013,9(6),0636) http://onlinelibrary.wiley.com/doi/10.1002/adsc.201200967/abstract 研究专题：郝新奇,牛俊龙,赵雪梅,龚军芳*,宋毛平*.“第VIII族钳形金属催化剂的研究进展.”有机化学2013,33(4),663-674. http://sioc-journal.cn/Jwk_yjhx/CN/abstract/abstract341980.shtml Xin-QiHao,Yan-XiaoXu,Ming-JunYang,LiWang,Jun-LongNiu,Jun-FangGong*,Mao-PingSong*.“ACationicNCNPincerPlatinum(II)AquoComplexwithaBis(imidazolinyl)phenylLigand:StudiestowarditsSynthesisandAsymmetricFriedel−CraftsAlkylationofIndoleswithNitroalkenes.”Organometallics2012,31(3),835-846. http://pubs.acs.org/doi/abs/10.1021/om200714z?source=chemport Ming-JunYang,Yan-JingLiu,Jun-FangGong*,Mao-PingSong*.“UnsymmetricalChiralPCNPincerPalladium(II)andNickel(II)ComplexeswithAryl-BasedAminophosphine-ImidazolineLigands:SynthesisviaArylC-HActivation,andAsymmetricAdditionofDiarylphosphinestoEnones.”Organometallics2011,30(14),3793-3803. http://pubs.acs.org/doi/abs/10.1021/om200350h?source=chemport InvitedPerspective:Jun-LongNiu,Xin-QiHao,Jun-FangGong*,Mao-PingSong*.“Symmetricalandunsymmetricalpincercomplexeswithgroup10metals:SynthesisviaarylC–Hactivationandsomecatalyticapplications.”DaltonTrans.2011,40(19),5135-5150. http://pubs.rsc.org/en/Content/ArticleLanding/2011/DT/c0dt01439g#!divAbstract TaoWang,Xin-QiHao,Xiao-XueZhang,Jun-FangGong*,Mao-PingSong*.“Synthesis,structureandcatalyticpropertiesofCNNpincerpalladium(II)andruthenium(II)complexeswithN-substituted-2-aminomethyl-6-phenylpyridines.”DaltonTrans.2011,40(35),8964-8976.(封面文章) http://pubs.rsc.org/en/Content/ArticleLanding/2011/DT/c1dt10331h#!divAbstract Dan-DanShao,Jun-LongNiu,Xin-QiHao,Jun-FangGong*,Mao-PingSong*.“NeutralandcationicchiralNCNpincernickel(II)complexeswith1,3-bis(2'-imidazolinyl)benzenes:synthesisandcharacterization.”DaltonTrans.2011,40(35),9012-9019. http://pubs.rsc.org/en/content/articlelanding/2011/DT/c1dt10329f#!divAbstract Ben-ShangZhang,WeiWang,Dan-DanShao,Xin-QiHao,Jun-FangGong*,Mao-PingSong*.“UnsymmetricalChiralPCNPincerPalladium(II)andNickel(II)Complexesof(Imidazolinyl)arylPhosphiniteLigands:SynthesisviaLigandC-HActivation,CrystalStructuresandCatalyticStudies.”Organometallics2010,29(11),2579-2587. http://pubs.acs.org/doi/abs/10.1021/om100232n?source=chemport Jun-LongNiu,Qing-TaoChen,Xin-QiHao,Qing-XiangZhao,Jun-FangGong*,Mao-PingSong*.“Diphenylprolinol-derivedSymmetricalandUnsymmetricalChiralPincerPalladium(II)andNickel(II)Complexes:SynthesisviaOne-PotPhosphorylation/metalationReactionandC-HActivation.”Organometallics2010,29(9),2148-2156. http://pubs.acs.org/doi/abs/10.1021/om100234q?source=chemport Li-YuanWu,Xin-QiHao,Yan-XiaoXu,Min-QiangJia,Ya-NanWang,Jun-FangGong*,Mao-PingSong*.“ChiralNCNPincerPt(II)andPd(II)Complexeswith1,3-Bis(2'-imidazolinyl)benzene:SynthesisviaDirectMetalation,Characterization,andCatalyticActivityintheFriedel-CraftsAlkylationReaction.”Organometallics2009,28(12),3369-3380. http://pubs.acs.org/doi/abs/10.1021/om801005j?source=chemport Jun-FangGong,Yan-HuiZhang,Mao-PingSong*,ChenXu.“NewPCNandPCPPincerPalladium(II)Complexes:ConvenientSynthesisviaFacileOne-potPhosphorylation/PalladationReactionandStructuralCharacterization.”Organometallics2007,26(25),6487-6492. http://pubs.acs.org/doi/abs/10.1021/om7008364?source=chemport An-TingHou,Yan-JingLiu,Xin-QiHao,Jun-FangGong*,Mao-PingSong*.“SynthesisandCharacterizationofnew(pyrazolyl)arylphosphinitePCNpincerpalladium(II)complexes.”J.Organomet.Chem.2011,696(15-16),2857-2862. http://www.sciencedirect.com/science/article/pii/S0022328X11003093 Xin-QiHao,Ya-NanWang,Jun-RuiLiu,Kun-LunWang,Jun-FangGong,*Mao-PingSong*.“Unsymmetrical,oxazolinyl-containingachiralandchiralNCNpincerligandprecursorsandtheircomplexeswithpalladium(II).”J.Organomet.Chem.2010,695(1),82-89. http://www.sciencedirect.com/science/article/pii/S0022328X09006342 Ben-ShangZhang,ChaoWang,Jun-FangGong*,Mao-PingSong*.“FacilesynthesisofachiralandchiralPCNpincerpalladium(II)complexesandtheirapplicationintheSuzukiandcopper-freeSonogashiracross-couplingreactions.”J.Organomet.Chem.2009,694(16),2555-2561. http://www.sciencedirect.com/science/article/pii/S0022328X09002484 Xin-QiHao,Jun-FangGong*,Chen-XiaDu,Li-YuanWu,Yang-JieWu,Mao-PingSong*.“Synthesis,characterizationandphotoluminescentpropertiesofplatinumcomplexeswithnovelbis(imidazoline)pincerligands.”TetrahedronLett.2006,47(29),5033-5036. http://www.sciencedirect.com/science/article/pii/S0040403906010306# ChenXu,Jun-FangGong*,Su-FangYue,YuZhu,Yang-JieWu*.“Tricyclohexylphosphine-cyclopalladatedferrocenyliminecomplexes:synthesis,crystalstructuresandapplicationinSuzukiandHeckreactions.”DaltonTrans.2006,(39),4730-4739. ChenXu,Jun-FangGong*,TaoGuo,Yan-HuiZhang,Yang-JieWu*.“Cyclopalladatedferrocenyliminecomplexeswithdicyclohexylphosphinobiphenylligands:Synthesis,crystalstructuresandtheiruseashighlyefficientcatalystsforSuzukireactionofarylchlorides.”J.Mol.Catal.A:Chem.2008,279(1),69-76. ChenXu,Jun-FangGong*,Yang-JieWu*.“Aminationofarylchloridesinwatercatalyzedbycyclopalladatedferrocenyliminecomplexeswithcommerciallyavailablemonophosphinobiarylligands.”TetrahedronLett.2007,48(9),1619-1623. Jun-FangGong*,Xin-HengFan,ChenXu,Jin-LeiLi,Yang-JieWu*,Mao-PingSong.“Newcycloplatinatedcomplexeswith2-arylimidazolines:synthesis,crystalstructuresandphotophysicalproperties.”J.Organomet.Chem.2007,692(10),2006-1013. JunfangGong,GuangyuLiu,ChenxiaDu,YuZhu,YangjieWu*.“EfficientSuzukicouplingofarylchloridescatalyzedbytricyclohexylphosphineadductsofcyclopalladatedferrocenylimines.”J.Organomet.Chem.2005,690(17),3963-3969. KaiXu,Xin-QiHao,Jun-FangGong*,Mao-PingSong*,andYang-JieWu.“RoomTemperatureSuzukiReactionsinAqueousMediaunderAirbyPalladium(II)ComplexeswithPyrazoleDerivedLigands.”Aust.J.Chem.2010,63(2),315-320. ChenXu,Jun-FangGong*,Yan-HuiZhang,YuZhu,Yang-JieWu*.“Synthesis,CharacterizationandCrystalStructuresofThreecis/transPyridine-CyclopalladatedFerrocenylimineComplexes,andTheirCatalysisinSuzukiReactions.”Aust.J.Chem.2007,60(3),190-195. Xin-QiHao,FangLiu,BiZhang,Mei-LingJiang,Jun-FangGong*,Mao-PingSong*.“Cyclopalladatedcomplexesof2-(m-nitrophenyl)imidazolines:synthesis,characterizationandcatalyticactivityintheSuzukireactionundermildconditions.”TransitionMet.Chem.2010,35(3),271-277. ChenXu,Jun-FangGong*,Mao-PingSong,Yang-JieWu*.“Catalysisofthecouplingreactionofarylchlorideswithbis(pinacolato)diboronbytricyclohexylphosphine-cyclopalladatedferrocenyliminecomplexes.”TransitionMet.Chem.2009,34(2),175-179. Jun-FangGong*,ChenXu,Yan-HuiZhang,YuZhu,Yang-JieWu*.“Synthesis,characterizationandcrystalstructuresoftwocis/transpyridine-cyclopalladatedferrocenyliminecomplexes.”Transit.MetalChem.2007,32(7),1000-1004. Xin-QiHao,Jun-FangGong*,Wen-TaoSong,Yang-JieWu,Mao-PingSong*.“Synthesisandcrystalstructuresofmono-,bis-aswellastris-mercuratedcomplexeswithferrocenylazines.”Inorg.Chem.Commun.2007,10(3),371-375. GONGJun-fang*,ZHANGYan-hui,FANXin-heng,WANGDa-wei,SONGMao-ping,WUYang-jie.“Synthesis,StructuralCharacterizationofFerrocenylIminophosphinesandAmidophosphinesasWellasTheirApplicationintheSuzukiReaction.”Chem.Res.ChineseU.2007,23(6),683-687. Jun-FangGong*,Da-WeiWang,Yan-HuiZhang,YuZhu,Yang-JieWu*.“SynthesisandStructuralCharacterizationofMercury(II)ComplexeswithaNovelFerrocenyliminophosphine.”Inorg.Chim.Acta2006,359(7),2115-2120. ChenXu,Jun-FangGong,Yan-HuiZhang,YuZhu,Chen-XiaDu,Yang-JieWu*.“Synthesis,characterizationandcrystalstructuresofanovel1,1’-bisferrocenylimineanditsmonocyclopalladatedderivative.”Inorg.Chem.Commun.2006,9(5),456-459. Ling-ZhiDu,Jun-FangGong*,ChenXu,YuZhu,Yang-JieWu,Mao-PingSong*.“Synthesisandstructuresofnoveldiastereomericcyclopalladatedferrocenyliminesderivedfromchiralb-aminoalcohols.”Inorg.Chem.Commun.2006,9(4),410-414. Ling-ZhiDu,Jun-FangGong*,YuZhu,Yang-JieWu,Mao-PingSong*.“Synthesis,characterizationandthecrystalstructuresofnovelachiralandchirala-ferrocenyla-aminophosphineoxides.”Inorg.Chem.Commun.2006,9(5),529-532. JunfangGong,GuangyuLiu,YuZhu,ChenxiaDu,MaopingSong,YangjieWu*.“Synthesis,CharacterizationandCatalyticActivityinSuzukiReactionofCyclopalladatedFerrocenylimineTriphenylphosphinecomplexes.”Chem.J.Chin.Univ.2006,27(7),1266-1271. JunfangGong,ChenXu,YangjieWu*.“Transition-MetalCatalyzedα-ArylationofCarbonylDerivativesandCompoundswithAcidicHydrogen.”ProgressinChem.2006,18(6),752-760. JunfangGong,EricBonfand,EricBrown,GillesDujardin*,VéroniqueMichelet*,Jean-PierreGenêt.“Remarkablestereocontrolinthesynthesisof1,2,3,5-tetrasubstitutedtetrahydropyransviaanasymmetricheterocycloadditionofaketone-derivedenolether.”TetrahedronLett.2003,44(10),2141-2144. JunfangGong,QinghuaFanandDazhiJiang*.“Nickel-catalyzedcarbonylationofmethylacetatetoaceticanhydride.”J.Mol.Catal.A:Chem.1999,147(1-2),113-124. 参与翻译、编写的著作 1.宋毛平,毛璞,廖新成,张雁冰,龚军芳.有机立体化学导论(译著,国外名校名著系列),化学工业出版社,2007.1 2.龚军芳.傅瑞德尔-克拉夫兹反应(现代有机反应第5卷金属催化反应胡跃飞林国强主编)，化学工业出版社，2008.12 3.龚军芳,宋毛平.玉尾-熊田-弗莱明立体选择性羟基化反应(现代有机反应第8卷碳-杂原子键参与的反应II胡跃飞林国强主编)，化学工业出版社，2013.1