朱钢国 - 浙江师范大学 - 化学与生命科学学院

个人简介

1996年9月－2000年7月：浙江师范大学化学系，理学学士 2000年9月－2005年7月：中科院上海有机化学研究所，理学博士，导师张兆国教授 2005年9月－2007年10月：师从美国普渡大学诺贝尔化学奖得主Negishi教授博士后研究，完成了spongidepsin、hexamethyldocosane等天然产物的全合成 2007年11月－2008年10月：美国印第安纳大学博士后研究 2008年12月－至今：浙江师范大学化学系任教。现为教授、硕士生导师、化学与生命科学学院副院长、先进催化材料教育重点实验室负责人，2009年入选浙江省“151”人才第三层次培养对象，2013年入选浙江省高校中青年学科带头人，2016年入选浙江省“151”人才工程第二层次培养对象、浙江师范大学“双龙学者”教授。已发表Angew. Chem. Int. Ed.、Chem. Sci.、Org. Lett.、Chem. Commun.、Adv. Synth. Catal.、J. Org. Chem.等SCI论文70余篇，SCI引用1100余次，授权发明专利9件，先后主持国家自然科学基金3项、浙江省自然科学杰出青年基金等省部级项目3项，完成企业横向项目2项，

研究领域

主要从事过渡金属催化的氟化反应、自由基反应和生理活性的天然产物全合成研究。

近期论文

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Visible-light induced three-component alkynyl-difluoroalkylation of unactivated alkenes, Jin, W.; Wu, M.; Xiong, Z. Zhu, G.* Chem. Commun. 2018, 54, DOI: 10.1039/C8CC03105C. Synthesis of Difluoromethylated and Phosphorated Spiro[5.5]trienones via Dearomative Spirocyclization of Biaryl Ynones, Zhang, Y.*; Zhang, J.; Hu, B.; Ji, M.; Ye, S.; Zhu, G.* Org. Lett. 2018, 20, 2988-2992. Photocatalytic acylarylation of unactivated alkenes with diaryliodonium salts toward indanones and related compounds, Chen, Y.; Shu, C.; Luo, F.; Xiao, X.;* Zhu, G.* Chem. Commun. 2018, 54, 5373-5376. Intermolecular Oxidative Radical Addition to Aromatic Aldehydes: Direct Access to 1,4- and 1,5-Diketones via Silver-Catalyzed Ring-Opening Acylation of Cyclopropanols and Cyclobutanols, Che, C.; Qian, Z.; Wu, M.; Zhao, Y.; Zhu, G.* J. Org. Chem. 2018, 83, 5665-5673. Nickel-Catalyzed Remote Arylation of Alkenyl Aldehydes Initiated by Radical Alkylation with Tertiary α-Carbonyl Alkyl Bromides, Jin, W.; Zhou, Y.; Zhao, Y.; Ma, Q.; Kong, L.; Zhu, G.* Org. Lett. 2018, 20, 1435-1438. Palladium-Catalyzed Site-Selective sp3 C-H Bond Thiocyanation of 2-Aminofurans, Chen, Y.; Wang, S.; Jiang, Q.; Cheng, C.; Xiao, X.;* Zhu, G.* J. Org. Chem. 2018, 83, 716-722. Preparation of 2-Amino-5-homoallylfurans via Palladium-Catalyzed Tandem Cycloisomerization/Heck-Type Coupling of Homoallenyl Amides with Allyltrialkylsilanes, Zhang, J.; Wu, M.; Lu, W.; Wang, S.; Zhang, Y.; Cheng, C.;* Zhu, G.* J. Org. Chem. 2017, 82, 11134-11140. Palladium-catalyzed tandem cyclization/sulfonylation of homoallenyl amides with sodium sulfinates, Wan, Y.; Zhang, J.; Chen, Y.; Kong, L.; Luo, F.;* Zhu, G.* Org. Biomol. Chem. 2017, 15, 7204-7211. Copper-Catalyzed Radical Cascade Difluoromethylation/Cyclization of 2-(3-Arylpropioloyl)benzaldehydes: A Route to Difluoromethylated Naphthoquinones, Zhang, Y.*; Ye, S.; Ji, M.; Li, L.; Guo, D.; Zhu, G. J. Org. Chem. 2017, 82, 6811-6818. Visible Light-Induced Tandem Radical Addition-Cyclization of Alkenyl Aldehydes Leading to Indanones and Related Compounds, Lu, D.; Wan, Y.; Kong, L.; Zhu, G.* Org. Lett. 2017, 19, 2929-2932. Copper-catalyzed acyltrifluoromethylation of alkenes: rapid access to trifluoroethyl indanones and related compounds, Liu, Z.; Bai, Y.; Zhang, J.; Yu, Y.; Tan, Z.; Zhu, G.* Chem. Commun. 2017, 53, 6440-6443. Palladium-Catalyzed Remote Aryldifluoroalkylation of Alkenyl Aldehydes, Nie, X.; Cheng, C.; Zhu, G.* Angew. Chem. Int. Ed. 2017, 56, 1898-1902. Synthesis of Trifluoromethylated Naphthoquinones via Copper-Catalyzed Cascade Trifluoromethylation/Cyclization of 2-(3-Arylpropioloyl)benzaldehydes, Zhang, Y.;* Guo, D.(本科生); Ye, S.; Liu, Z.; Zhu, G.* Org. Lett. 2017, 19, 1302-1305. Copper-catalyzed borylative cyclization of 1,n-enynyl phosphates leading to five- to eight-membered cyclic 1,4-dienyl boronates, Zhang, F.; Wang, S.; Liu, Z.; Bai, Y.;* Zhu, G.* Tetrahedron Lett. 2017, 58, 1448-1452. Synthesis of (E)-α,β-Unsaturated Carbonyls via Silver-Catalyzed Tandem Epoxide Rearrangement/Intermolecular Carbonyl-Heteroalkyne Metathesis, Zhu, H.; Jin, W.; He, J.; Zhang, Y.*; Zhu, G.* Adv. Synth. Catal. 2016, 358, 3730-3735. Copper-catalyzed cascade annulation between α-bromocarbonyls and biaryl or (Z)-arylvinylacetylenes enabling a direct synthesis of dibenzocycloheptanes and related compounds, Lu, D.; Wan, Y.; Kong, L.; Zhu, G.* Chem. Commun. 2016, 52, 13971-13974. Copper-Catalyzed Trifluoromethylation of Alkenes with Redox-Neutral Remote Amidation of Aldehydes, Cheng, C.; Liu, S.; Lu, D.; Zhu, G.* Org. Lett. 2016, 18, 2852-2855. Copper-catalyzed cascade annulation of unsaturated α-bromocarbonyls with enynals: a facile access to ketones from aldehydes, Che, C.; Huang, Q.; Zheng, H.; Zhu, G.* Chem. Sci. 2016, 7, 4134-4139. Direct access to 2-amino-5-azidomethylfurans through palladium-catalyzed azidative cycloisomerization of homoallenyl amides, Huang, Q.(本科生); Zheng, H.; Liu, S.; Kong, L.; Luo, F.*; Zhu, G.* Org. Biomol. Chem. 2016, 14, 8557-8563. HOTf-Catalyzed, Solvent-free Oxyarylation of Ynol Ethers and Thioethers, Hu, L.; Cui, Q.; Chen, X.; Tan, Z.*; Zhu, G.* J. Org. Chem. 2016, 81, 4861-4868.