刘占祥 - 浙江大学

研究领域

从事有机合成方法学研究，主要研究领域为组合化学、功能分子合成及其应用。固相有机合成建立具有生物活性的杂环化合物库，合成功能性近红外荧光分子，建立合成方法，研究其在离子或分子识别以及在有机合成中的应用。

近期论文

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Yao, J. Z.; Feng, R. K.; Lin, C.; Liu, Z. X.; Zhang, Y. H. Synthesis of 2,3-dihydro-1 H -indazoles by Rh( III )-catalyzed C – H cleavage of arylhydrazines Org. Biomol. Chem., 2014, 12 , 5469–5476 Feng, R. K.; Yu, W. L.; Wang, K.; Liu, Z. X.; Zhang, Y. H. Ester-Directed Selective Olefination of Acrylates by Rhodium Catalysis Adv. Synth. Catal. 2014, 356, 1501 – 1508 Xie, R. J.; Yi, Y. R.; He, Y.; Liu, X. G.; Liu, Z. X. A simple BODIPY imidazole-based probe for the colorimetric and fluorescent sensing of Cu(II) and Hg(II) Tetrahedron 2013, 69, 8541-8546. Feng, R. K.; Yao, J. Z.; Liang, Z. J.; Liu, Z. X.; Zhang, Y. H. Cu(II)-Promoted Palladium-Catalyzed C−H Ortho-Arylationof N,N‑Dimethylbenzylamines J. Org. Chem. 2013, 78, 3688−3696. Ju L.; Yao, J. Z.; Wu, Z. H.; Liu, Z. X.; Zhang Y. H. Palladium-Catalyzed Oxidative Acetoxylation of Benzylic C−H Bond Using Bidentate Auxiliary J. Org. Chem. 2013, 78, 10821−10831. Chen, Z. K.; Yan, Q. Q.; Liu, Z. X.; Xu, Y. M.; Zhang, Y. H. Copper-Mediated Synthesis of 1,2,3-Triazoles from N-Tosylhydrazones and Anilines Angew. Chem. Int. Ed. 2013, 52, 13324 -13328. Liang, Z. J.; Zhang, J. T.; Liu, Z. X.; Wang, K.; Zhang, Y.H. Pd(II)-catalyzed C(sp2)eH carbonylation of biaryl-2-amine: synthesis of phenanthridinones Tetrahedron 2013, 69, 6519-6526. Yao, J. Z.; Feng, R. K.; Wu, Z. H.; Liu, Z. X.; Zhang, Y. H. Palladium-Catalyzed Decarboxylative Coupling of a-Oxocarboxylic Acids with C(sp2)-H of 2-Aryloxypyridines Adv. Synth. Catal. 2013, 355, 1517–1522. Liu, Z. X.; Yi. Y. R.; Zhao, J. L.; Tang, M. X. Solid-Phase Synthesis of 4,5-Disubstituted-1,2,4-triazole-3-thione Derivatives Based on the Resin-Bound Acylhydrazines Synth. Commun. 2012， 42, 55–61. Liu, Z. X, Burgess K. Continuous flow biocatalytic resolutions of methyl sulfinylacetates Tetrahedron Lett. 2011, 52, 6325-6327. Liu, Z.X.; Song, Z. S.; Zhao, J. L.; Zheng, J. Y. Solid-Phase Synthesis of 2-Arylamino-5-(4-hydroxyphenyl)-1,3,4-thiadiazole Derivatives Based on Resin-Bound Acylhydrazines Phosphorus, Sulfur and Silicon and the Related Elements 2010, 185, 2375-2381. Liu,ZX, Mu, YY.; Lin,J.; Chen YY Traceless Solid-Phase Synthesis of 1,2,3-Thiadiazole Derivatives from Resin-Bound Acylhydrazine Synthetic Communications 2008, 38, 4407–4414. Liu, ZX，Mu YY，Song ZS Solid phase synthesis of 4,5-disubstituted 1,2,4-triazol-3-one derivatives from resin-bound acylhydrazines of Chemical Research, 2008, 216-217. Liu ZX, Zhao JL, Huang, X Solid phase synthesis of 1, 3, 4-oxadiazoline-5-thione derivatives from resin bound acylhydrazines Bioorg. Med. Chem. Lett 2006, 16 (7): 1828-1830. Zhao TY, Liu ZX, Song YB, Xu, W.; Zhang, DQ; Zhu, DB Novel diethynylcarbazole macrocycles: Synthesis and optoelectronic properties J. Org. Chem. 2006, 71 (19): 7422-7432 Liu L, Liu ZX, Xu W, Xu, H., Zhang, DQ， Zhu, DB Special fluorescence enhancement and aggregation in Langmuir-Blodgett films of 4,4 '-dicyano-(3,4-dibutyl-2- thienylethynyl) biphenyl Thin Solid Films 2006, 515 (4): 2596-2601 . Liu L, Liu ZX, Xu W, Zhang, DQ， Zhu, DB Syntheses, optical and electrochemical properties of 4,4 '-bis- [2- (3, 4- dibutyl -2-thienylethynyl) biphenyl and its oligomers Tetrahedron 2005, 61 (15): 3813-3817. Huang X, Liu ZX Solid-phase synthesis of 4(1H)-quinolone and pyrimidine derivatives based on a new scaffold-polymer-bound cyclic malonic acid ester. J. Org . Chem 2002, 67 (19): 6731-6737. Liu ZX, Ruan XX, Huang X A facile solid phase synthesis of tetramic acid. Bioorg. Med. Chem. Lett 2003, 13 (15): 2505-2507. Huang X, Liu ZX Preparation of a resin-bound cyclic malonic ester and a facile solid-phase synthesis of 4(1H)quinolones Tetrahedron Lett. 2001, 42 (43): 7655-7657. Liu Z. X. , Wu, LL, Huang X Solid phase synthesis of 4H-pyrimido[2,1-b] benzothiazol-4-ones from resin-bound cyclic malonic acid. Chinese Chem. Lett. 2003, 14 (3): 247-248