王从敏 - 浙江大学

研究领域

我的研究兴趣是基于离子液体的绿色过程和清洁生产技术研究。主要针对碳捕集、脱硫等酸性气体捕集中普遍遇到的吸收容量低、能耗高、吸收速率慢等关键问题，提出了多位点吸收、碱性调控、双重调控等新的酸性气体捕集策略，实现了酸性气体CO2、SO2等高效、可逆、快速地捕集；并针对离子液体制备复杂、成本高、工业应用难等问题，创制了一类成本低廉、性能优异的简单胺型离子液体，作为溶剂和催化剂应用于万吨级维生素E、烯基醚、肉桂酸等产品的清洁生产中，实现了离子液体的大规模工业应用。这些工作为酸性气体的工业捕集提供了新的思路，为离子液体的大规模工业应用提供了很有前景的方法。

近期论文

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Ding, F.; Zheng, J.; Chen, Y.; Chen, K.; Cui, G.; Li, H.; Wang, C.* "Highly efficient and reversible SO2 capture by surfactant-derived dual functionalized ionic liquids with metal chelate cations", Ind. Eng. Chem. Res., 2014, 53, 18568-19574. Ding, F.; He, X.; Luo, X.; Lin W.; Chen, K.; Li, H.; Wang, C.* "Highly efficient CO2 capture by carbonyl-containing ionic liquids through lewis acid-base and cooperative C-H•••O hydrogen bonding interaction strengthened by the anion", Chem. Commun., 2014, 50, 15041-15044. Luo, X.; Guo, Y.; Ding, F.; Zhao, H.; Cui, G.; Li, H.; Wang, C.* "Significant Improvements in CO2 Capture by Pyridine-containing Anion-functionalized Ionic Liquids through Multiple Site Cooperative Interaction", Angew. Chem. Int. Ed., 2014, 53(27), 7053-7057. Luo, X.; Ding, F.; Lin, W.; Qi, Y.; Li, H.; Wang, C.* "Efficient and Energy-saving CO2 Capture through the Entropic Effect Induced by the Intermolecular Hydrogen Bonding in Anion-functionalized Ionic Liquids", J. Phys. Chem. Lett., 2014, 5, 381-386. Cui, G.; Lin, W.; Ding, F.; Luo, X.; He, X.; Li, H.; Wang, C.* "Highly efficient SO2 capture by phenyl-containing azole-based ionic liquids through multiple-site interactions", Green Chem., 2014, 16, 1211-1216. Cui, G.; Zheng, J.; Luo, X.; Lin, W.; Ding, F.; Li, H.; Wang, C.* "Tuning Anion-Functionaalized Ionic Liquids for Improved SO2 Capture", Angew. Chem. Int. Ed., 2013, 52(40), 10620-10624. onlinelibrary.wiley.com/doi/10.1002/anie.201305234/abstract Wang, C.*; Luo, X.; Zhu, X.; Cui, G.; Jiang, D.; Deng, D.; Li, H.; Dai, S.* "The Strategies fo Improving Carbon Dioxide Chemisorption by Functionalized Ionic Liquids", RSC Adv., 2013, 3, 15518-15527. Wang, C.*; Zheng, J.; Cui, G.; Luo, X.; Guo, Y.; Li, H.* "Highly Efficient SO2 Capture through Tuning the Interaction Between Anion-functionalized Ionic Liquids and SO2", Chem. Commun., 2013, 49(12), 1166-1169 (selected as the back cover). Chen, K.; Jia, L.; Dao, R.; Yao, J.; Wang, C.; Chen, Z.; Li, H.* "Theoretical Studies on Muti-Hydroxyimides as Highly Efficient Catalysts for Aerobic Oxidation", 2013, ChemPhysChem, 14(1), 179-184. Chen, H.; Jia, L.; Xu, X.; Mao, J.; Wang, Y.; Wang, C.; Li, H.* "Electronic effect of ionic-pair substituents", 2013, J. Phys. Org. Chem., 26(6), 460-466. Zhu, X.; Hillesheim, P.C.; Mahurin, S.M.; Wang, C.*; Tian, C.; Brown, S.; Luo, H.; Veith , G.M.; Han, K.; Hagaman, E.W.; Liu, H.*; Dai, S.* "Efficient CO2 Capture by Porous, Nitrogen-Doped Carbonaceous Adsorbents Derived from Task-Specific Ionic Liquids", ChemSusChem, 2012, 5(10), 1912-1917. Zhu, X.; Tian, C.; Mahurin, S.M.; Chai, S.; Wang, C.; Brown, S.; Veith , G.M.; Luo, H.; Liu, H.; Dai, S.* "A Superacid-Catalyzed Synthesis of Porous Membranes Based on Triazine Frameworks for CO2 Separation", J. Am. Chem. Soc., 2012, 134, 10478-10484. Wang, C.;* Guo, Y.; Zhu, X.; Cui, G.; Li, H.; Dai, S.* "Highly Efficient CO2 Capture by Tunable Alkanolamine-Based Ionic Liquids with Multidentate Cation Coordination", Chem. Commun., 2012, 48,6526-6528. Wang, C.;* Luo, H.; Li, H.; Zhu, X.; Yu, B.; Dai, S.* "Tuning the Physicochemicla Properties of Diverse Phenolic Ionic Liquids for Equimolar CO2 Capture by the Substituent on the Anion", Chem. Eur. J., 2012,18(7), 2153-2160. Cui, G.; Wang, C.;* Zheng, J.; Guo, Y.; Luo, X.; Li, H.* "Highly Efficient SO2 Capture by Dual Functionalized Ionic Liquids through a Combination of Chemical and Physical Absorption", Chem. Commun., 2012, 48(20), 2633-2635. Zhang, P.; Gong, Y.; Lv, Y.; Guo, Y.; Wang, Y.; Wang, C.; Li, H.* "Ionic liquids with metal chelate anions", Chem. Commun., 2012, 48(17), 2334-2336. Chen, K.; Sun, Y.; Wang, C.; Yao, J.; Chen Z.; Li, H.* "Aerobic oxidation of beta-isophorone catalyzed by N-hydroxyphthalimide: the key features and mechanism elucidated", 2012, Phys. Chem. Chem. Phys., 14(35), 12141-12146. Xu, Y.; Yao, J.; Wang, C.; Li, H.* "Density, viscosity, and refractive Index properties for the binary mixtures of n-butylammonium acetate ionic liquid plus alkanols at several temperatures", J. Chem. Eng. Data, 2012, 57(2), 298-308. Wang, C.;* Cui, G.; Luo, X.; Xu, Y.; Li, H.;* Dai, S.* "Highly Efficient and Reversible SO2 Capture by Tunable Azole-based Ionic Liquids through Multiple-Site Chemical Absorption", J. Am. Chem. Soc., 2011,133(31), 11916-11919. http://pubs.acs.org/doi/abs/10.1021/ja204808h Wang, C.;* Luo, X.; Luo, H.; Jiang, D.; Li, H.; Dai, S.*"Tuning the Basicity of Ionic Liquids for Equimolar CO2 Capture", Angew. Chem. Int. Ed., 2011, 50(21), 4918-4922. (Selected by the editor as a "Hot Paper") http://onlinelibrary.wiley.com/doi/10.1002/anie.201008151/abstract Zhang, P.; Wang, C.; Chen, Z.; Li H.;* "Acetylacetone-Metal Catalyst Modified by Pyridinium Salt Group Applied to the NHPI-Catalyzed Oxidation of Cholesteryl acetate", Catal. Sci. Technol., 2011, 1, 1133-1137.