黄志真 - 浙江大学

研究领域

主研方向：(1)有机小分子和过渡金属催化的不对称反应; (2)绿色不对称合成 (3)生物活性分子的合成; (4)国家级新药的设计和合成。在研项目：国家自然科学基金面上项目“金属与有机小分子共催化的新型不对称反应的研究”（No.21072091,2011.1-2013.12）、“过渡金属与有机小分子共催化的新型碳-氢官能化反应的研究”（No.21372195,2014.1-2017.12）、国家重点基础研究发展计划(973项目)中的课题“利用手性有机小分子与过渡金属催化不对称合成不饱和化合物的研究”(No.2011CB808601,2011.1-2015.12)、元素有机国家重点实验室课题“过渡金属与有机小分子催化的新型反应的研究”（No.201014,2011.1-2013.12）以及与香港中文大学和美国Georgia医学院联合开展的新药研究。

近期论文

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Copper-catalyzed Dehydrogenative Cross-Coupling Reaction between Allylic C-H Bond and α-C-H Bond of Ketones or Aldehydes, Xin-Feng Huang, Muhammad Salman, Zhi-Zhen Huang*, Chem. Eur. J., 2014, 20, 6618. A Cascade Alkylarylation Reaction of 2-Isocynobiphenyls with Simple Alkanes for 6-Alkyl Phenanthridines via Dual C(sp3)-H/C(sp2)-H Fuctionalizations,Zhi-Qiang Zhu, Tian-Tian Wang, Peng Bai, Zhi-Zhen Huang*,Org. Biomol. Chem., 2014, 12 (31), 5839. Dehydrogenative Cross-Coupling Reaction by Coorperative Transition-Metal and Brønsted Acid Catalysis for the Synthesis of α-Quinolinyl α-Amino Acid Esters, Zhi-Qiang Zhu, Peng Bai, Zhi-Zhen Huang*, Org. Lett. 2014, DOI: 10.1021/ol502402s. A Novel Synthesis of Imides by C-H Functionalization of Aldehydes with Secondary Amides under Palladium Catalysis, Yong-Jun Bian, Chao-Yue Chen, Zhi-Zhen Huang*, Chem. Eur. J., 2013, 19, 1129. Transesterification for Synthesis of Carboxylates Using Aldehydes as Acyl Donors via C-H and C-O Bond Activations, Yong-Sheng Bao, Chao-Yue Chen, Zhi-Zhen Huang*, J. Org. Chem, 2012, 77, 8344. Coupling Reactions of Heteroarenes with Phosphites under Silver Catalysis, Chang-Bing Xiang,Yong-Jun Bian, Xue-Rong Mao, Zhi-Zhen Huang*, J. Org. Chem, 2012, 77, 7706. A Cascade Heck-Aldol-Heck Reaction by A Combination of Transition-Metal and Aminocatalysis, Chang-Shan Guo, Yu-Han Du, Zhi-Zhen Huang*, Chem. Commun., 2011, 47, 3995. Cross Dehydrogenative Coupling Reactions by Transition-Metal and Aminocatalysis for Amino Acid Derivatives, Jin Xie, Zhi-Zhen Huang*, Angew. Chem. Int. Ed. 2010, 49, 10181. The Cascade Carbo-carbonylation of Unactivated Alkenes Catalyzed by An Organocatalyst andA Transition Metal Catalyst: A Facile Approach to γ-Diketones and γ-Carbonyl Aldehydes from Arylalkenes under Air, Jin Xie, Zhi-Zhen Huang*, Chem. Commun., 2010, 46, 1947. Copper-Catalyzed Cross Dehydrogenative Coupling Reactions of Tertiary Amines with Ketones or Indoles, Fei Yang, Jian Li, Jin Xie, Zhi-Zhen Huang*, Org. Lett. 2010, 12, 5214. First Example of Highly Stereoselective Synthesis of 1,2,3-Trisubstituted Cyclopropanes via Chiral Selenonium Ylides, Hai-Yang Wang,Fei Yang,Xin-Liang Li, Xue-Ming Yan,Zhi-Zhen Huang*, Chem. A Eur. J., 2009, 15, 3784. A New Chiral Organosulfur Catalyst for Highly Stereoselective Synthesis of Epoxides, Yuan Gui, Jian Li, Chang-Shan Guo, Xin-Liang Li, Zhi-Feng Lu, Zhi-Zhen Huang*, Adv. Syn. & Cat., 2008, 350(16), 2483. Highly Enantioselective α-Aminoxylation of Aldehydes and Ketones in Ionic Liquids, Kun Huang, Zhi-Zhen Huang*, Xin-Liang Li, J. Org. Chem., 2006, 71, 8320. Synthesis and Isolation of Some Benzo[c]tellurophenes, Zhi-Zhen Huang, M.V. Lakshmikantham, Michael Lyon and Michael P. Cava*, J. Org. Chem., 2000, 65(17), 5413. Palladium-Catalyzed Reaction of Allylic Benzotriazoles with Enamines: A Novel Method for the Stereoselective Synthesis of (E)-α,β-Unsaturated Ketones, Alan R. Katritzky*, Zhi-Zhen Huang, Yunfeng Fang, J. Org. Chem., 1999, 64, 7625. A Novel Synthesis of Alkyl, Aryl, Alkenyl and Alkynyl 1,6-Diketones, Alan R. Katritzky*, Zhi-Zhen Huang, Yunfeng Fan, Indra Prakash, J. Org. Chem., 1999, 64, 2124.