傅春玲 - 浙江大学

研究领域

主要从事联烯化学，多中心反应及选择性(区域和立体)偶联反应及方法学在目标分子有机合成中的应用的研究。重点集中在联烯的亲电加成反应和金属催化下官能团化联烯与芳基卤化物的反应。近几年在世界著名化学期刊上发表研究论文十余篇。申请了中国发明专利3项。其中较典型的工作有：我们利用联烯醇与亲电试剂的加成反应，在反应过程中发生芳基或氢迁移，实现了很有合成价值的β-卤代-β, γ-不饱和醛和酮的选择性合成。这类化合物由于极易发生双键从β, γ-位向α, β-位的移动，传统方法较难合成。通过在联烯中引入亲核性官能团成功地解决了联烯在亲电试剂存在下反应活性及选择性调控，为一系列环状化合物的合成提供了高效合成方法学。首次观测到联烯与芳基卤化物发生Heck型反应，同时也是首例钯催化下联烯双键对分子间碳-钯物种插入生成Csp2-Pd键，而不是形成烯丙基钯中间体的反应。

近期论文

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在饱和硫代硫酸钠作用下1，2-联烯砜与溴的高区域和高立体选择性硫杂三元环化反应研究 Angew.Chem. Int. Ed.46<>, 20070418 Chao Zhou, Chunling Fu, Shengming Ma Studies on electrophilic addition reaction of Br2 with 1，2-allenylic sulfones 1，2-联烯砜与溴的亲电加成反应研究 Tetrahedron63<>, 20070413 Chao Zhou, Chunling Fu, Shengming Ma 1,2-联烯亚砜与苯硒氯的高区域和高立体选择性加成反应研究 Tetrahedron63<>, 20070306 Guangke He, Chao Zhou, Chunling Fu, Shengming Ma Electrophilic Interaction of 2,3-Allenoates with2,3-联烯酸酯与苯硒氯的亲电反应 J.Org.Chem.<>, 20061215 Guofei Chen, Chunling Fu,Shengming Ma Studies on electrophilic addition reaction of 2,3-allenoates with PhSeCl2,3-联烯酸酯与苯硒氯的亲电环化反应 Tetrahedron62<7>, 20060313 Chunling Fu, Shengming Ma Efficient Preparation of 4-Iodofuran-2(5H)-ones by Iodolactonization of 2,3-Allenoates with I2Efficient Preparation of 4-Iodofuran-2(5H)-ones by Iodolactonization of 2,3-Allenoates with I2 <>, 20050901 Stereoselective Z-iodoalkoxylation of 1,2-allenyl sulfides or selenides1，2－联烯硫醚及硒醚的高立体选择性醇碘化反应研究 Tetrahedron61<32>, 20050808 傅春玲 Efficient Preparation of 4-Iodofuran-2（5H）-ones Iodolactionisation 2，3-Allenoates with I22，3－联烯酸酯与碘的碘代内酯环化反应高效合成4－碘呋喃酮类化合物 Eur. J. Org. Chem.<16>, 20050808 傅春玲 Efficient two-step synthesis of 3-halo-3-enals or 2-halo-2-alkenyl ketones from propargylic bromides via a unique cationic 1,2-aryl or proton shift in electrophilic addition reaction of 2,3-allenols w从炔丙基溴出发通过1，2－芳基或1，2－氢迁移高效合成3－卤代－3－烯醛或2－卤代－2烷基烯酮 Chem. Commun.<32>, 20050808 傅春玲 Efficient Two-step Synthesis of 3-Halo-3-enals or 2-Halo-2-alkenyl ketones from Propargylic Bromides via a Unique Cationic 1,2-Aryl Shift in Electrophilic Addition Reaction of 2,3-Allenols with X+(X= Br，I) <>, 20050801 Stereoselective Z-Iodoalkoxylation of 1,2-Allenyl Sulfides or Selenides TetrahedronStereoselective Z-Iodoalkoxylation of 1,2-Allenyl Sulfides or Selenides Tetrahedron 61<32>, 20050801 NaSO2Ph-Induced Isomerization of 1,2-Allenyl Sulfoxides to 2-Acetylenic Phenyl Sulfoxides苯基亚磺酸钠促进的1，2-联烯亚砜的异构化反应 Chin. J. Chem.23<7>, 20050705 Chunling Fu, Shengming Ma PhSO2Na–Induced Isomerization of 1,2-Allenyl Sulfoxides to 2-Acetylenic Phenyl SulfoxidesPhSO2Na–Induced Isomerization of 1,2-Allenyl Sulfoxides to 2-Acetylenic Phenyl Sulfoxides 23<>, 20050601 Highly Stereoselecitive Synthesis of 2(E),4-Alkadienoates via the Pd(0)-Catalyzed Reaction of Aryl Halides with 3,4-AlkadienoatesHighly Stereoselecitive Synthesis of 2(E),4-Alkadienoates via the Pd(0)-Catalyzed Reaction of Aryl Halides with 3,4-Alkadienoates 7<9>, 20050601 The Observation of First Heck-type Substitution Reaction of Allenes with Aryl HalidesThe Observation of First Heck-type Substitution Reaction of Allenes with Aryl Halides 7<8>, 20050501 Highly Stereoselective Synthesis of 2,4-Alkadienoates via the Pd(0)-Catalyzed Reaction of Aryl Halides with 3,4- Alkadienoates钯催化下3，4-联烯酸酯与芳基卤化物反应高区域、高立体选择性合成2，4-共轭二烯酸酯 Org. Lett.7<8>, 20050430 Chunling Fu, Shengming Ma The Observation of First Hech-type Substitution Reaction of Allenes with Aryl Halides. Synthesis of Polysubstituted 1,2-Allenyl Sulfones首例联烯与芳基卤化物的Hech型反应 Org. Lett.7<7>, 20050414 Chunling Fu, Shengming Ma Efficient Preparation of 4-Iodofuran-2(5H)-ones by Iodolactonization of 2,3-Allenoates with I2 Eur. J. Org. Chem.<>, 2005-09-01 Stereoselective Z-Iodoalkoxylation of 1,2-Allenyl Sulfides or Selenides Tetrahedron Tetrahesron61<32>, 2005-08-01 Efficient Two-step Synthesis of 3-Halo-3-enals or 2-Halo-2-alkenyl ketones from Propargylic Bromides via a Unique Cationic 1,2-Aryl Shift in Electrophilic Addition Reaction of 2,3-Allenols with X+(X= Br，I) Chem. Commun.<>, 2005-08-01