陈万芝 - 浙江大学

研究领域

1. 过渡金属有机化学－主要是N－杂环卡宾金属有机化合物合成新方法，结构和反应的研究 2. N－杂环卡宾金属有机化合物在有机合成中的应用。 3. 金属原子簇中金属－金属相互作用及其发光，金银簇合物的抗肿瘤药物。主要研究领域：金属有机化学和均相催化。目前的工作集中在下列三个方面: 1. N-杂环卡宾VIII族金属化合物合成, 结构和性质; 2. 非贵金属有机化合物在有机合成中的应用; 3.杂环化合物合成新方法。

近期论文

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Xiaolong Liu, Wanzhi Chen, A Planar π-Conjugated Naphthyridine-Based N-Heterocyclic Carbene Ligand and Its Derived Transition Metal Complexes, Organometallics, 2013, 32(1), 209-217. DOI: 10.1021/om3009876 Yuansong Jiang, Wanzhi Chen,* and Weimin Lu* N-Heterocyclic carbene Catalyzed Annulation between 2-Chloro-2-arylacetaldehydes and Salicylaldehydes and Synthesis of 3-Arylcoumarins, Tetrahedron，2013, 69, 3669-3676. DOI: 10.1016/j.tet.2013.03.025 Xiaobo Shang and Wanzhi Chen, A simple and efficient synthesis of dibenzothiophene via Lewis acid-promoted intramolecular annulations, Synlett 2013, 24, 851-854. DOI: 10.1055/s-0032-1318391 Gu Shaojin, Wanzhi Chen, Review, 基于N-杂环卡宾的多齿C,N-配体过渡金属化合物的合成与应用, 有机化学, 2013, 33, 715-737. DOI: 10.6023/cjoc201301075 Qinqin Xia and Wanzhi Chen*, Iron-Catalyzed N-Alkylation of Azoles via Cleavage of a sp3 C-H Bond Adjacent to a Nitrogen Atom, J. Org. Chem., 2012，77，9366-9373. DOI: 10.1021/jo301568e Chao Chen, Wanzhi Chen* and Huayu Qiu, Synthesis of [PdL(NH3)2](PF6)2 (L = 1,1′-di(alkyl)-3,3′-methylenediimidazolin-2,2′-diylidene) complexes and their reactivities towards N-donors, Dalton Trans. 2012, 41,13405. DOI: 10.1039/C2DT31739G Xiaolong Liu, Wanzhi Chen, Pyridazine-Based N-Heterocyclic Carbene Complexes and Ruthenium-Catalyzed Oxidation Reaction of Alkenes, Organometallics, 2012, 31(18), 6614-6622. DOI: 10.1021/om300644h Zhang Yin, Bin Liu, and Wanzhi Chen*, Reactivities of Iron N-Heterocyclic Carbenes Towards N, P, O, S-donors, 科学通报, 2012, 57(19), 2368-2376. DOI: 10.1007/s11434-012-5164-5 Yuansong Jiang, Wanzhi Chen*, and Weimin Lu*, N-Heterocyclic Carbene Catalyzed Conjugate Umpolung Reactions Leading to Coumarin Derivatives, RSC advances, 2012, 2, 1540-1546. DOI: 10.1039/C1RA00916H Bo Liu, Congyan Chen, and Wanzhi Chen*, Synthesis of Metal N-Heterocyclic Carbenes Complexes Using Nickel(II)-Carbene Complexes as Carbene Transfer Reagents, Organometallics, 2012, 31, 282-288. DOI: 10.1021/om200881s Hui Xu and Wanzhi Chen*, Jiuxi Chen, Huayue Wu*, Stereoselective Synthesis of (Z)-1,2-Dithio-1-alkenes via Copper-Catalyzed Thiolation of (Z)-2-Bromovinyl sulfides, Synthesis, 2012, 44, 380-388. DOI: 10.1055/s-0031-1290067 Shaojin Gu, Bo Liu, Jiuxi Chen, Huayue Wu*, and Wanzhi Chen*, Synthesis, Structures, Photophysical and Electrochemical Properties of Heterometallic Tetranuclear Ruthenium(II)-Silver(I) Complexes Based N-Heterocyclic Carbene Ligands, Dalton Trans. 2012, 68, 962-970. DOI: 10.1039/c1dt11269d Daichao Xu,Chunxin Lv, Wanzhi Chen, Palladium-Catalyzed Double Arylations of Terminal Olefins in Acetic Acid, Tetrahedron, 2012, 68, 1466-1474.DOI: 10.1016/j.tet.2011.12.017 Xiaolong Liu and Wanzhi Chen*, Synthesis of Ruthenium (II) Complexes of Tetradentate Bis(N-pyridylimidazolylidenyl)methane and Their Reactivities towards N-Donors, Dalton Transactions, 2012, 41, 599-608. DOI: 10.1039/c1dt11356a Chao Chen, Huayu Qiu*, and Wanzhi Chen*, Trinuclear Copper (I) Complexes of 1,3-Bis(2-pyridinylmethyl)imidazolylidene as Carbene Transfer Reagent for the Preparation of Catalytically Active Nickel(II) and Palladium(II) Complexes, J. Organomet. Chem. 2012, 696(26), 4166-4172. DOI: 10.1016/j.jorganchem.2011.09.008