曹发和 - 浙江大学

研究领域

材料电化学，腐蚀与防护 (1) 基于扫描微探针的材料微区电化学行为研究，局部反应活性，溶解机制等； (2) 典型材料模拟大气腐蚀研究，电化学监检测技术在腐蚀失效过程的应用； (3) 新型环保高耐蚀镁合金阳极/微弧氧化、电沉积等表面处理技术。

近期论文

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W.J. Liu, F.H. Cao*, L.R. Chang, Z. Zhang, J.Q. Zhang, Effect of rare earth element Ce and La on corrosion behavior of AM60 magnesium alloy, Corrosion Science, 2009, 51(6): 1334-1343. L.R. Chang, F.H. Cao*, J.S. Cai, W.J. Liu, J.Q. Zhang, C.N. Cao, Formation and transformation of Mg(OH)2 in anodic coating using FTIR mapping, Electrochemistry Communications, 2009, 11(11): 2245-2248. J.L. Cao, H.Y. Zhao, F.H. Cao*, J.Q. Zhang, C.N. Cao, Electrocatalytic degradation of 4-chlorophenol on F-doped PbO2 anodes, Electrochimica Acta, 2009, 54(9): 2595-2602. W.J. Liu, F.H. Cao*, B.L. Jia, L.Y. Zheng, J.Q. Zhang, C.N. Cao, X.G. Li, Corrosion behaviour of AM60 magnesium alloys containing Ce or La under thin electrolyte layers. Part 2: Corrosion product and characterization, Corrosion Science, 2010, 52(2): 639-650. W.J. Liu, F.H. Cao*, A.N. Chen, L.R. Chang, J.Q. Zhang, C.N. Cao, Corrosion behaviour of AM60 magnesium alloys containing Ce or La under thin electrolyte layers. Part 1: Microstructural characterization and electrochemical behaviour, Corrosion Science, 2010, 52(2): 627-638. L.Y. Zheng, F.H. Cao*, W.J. Liu, B.L. Jia, J.Q. Zhang, Corrosion behavior of pure zinc and its alloy under thin electrolyte layer, Acta Metallurgica Sinica (English Letter), 2010, 23(6): 416-430. 蔡景顺, 曹发和*, 常林荣, 张昭, 张鉴清, 曹楚南, Ce改性AZ91的微弧氧化膜制备及其耐蚀性能, 浙江大学学报（工学版）, 2011, 45(11): 2055-2062. S. Zhang, F.H. Cao*, L.R. Chang, J. Zheng, Z. Zhang, J. Zhang, C. Cao, Electrodeposition of high corrosion resistance Cu/Ni–P coating on AZ91D magnesium alloy, Applied Surface Science, 2011, 257(21): 9213-9220. X.N. Liao, F.H. Cao*, L.Y. Zheng, W.J. Liu, A.N. Chen, J.Q. Zhang, C.N. Cao, Corrosion behaviour of copper under chloride-containing thin electrolyte layer, Corrosion Science, 2011, 53(10): 3289-3298. L.R. Chang, F.H. Cao*, J.S. Cai, W.J. Liu, Z. Zhang, J.Q. Zhang, Influence of electric parameters on MAO of AZ91D magnesium alloy using alternative square-wave power source, Transactions of Nonferrous Metals Society of China, 2011, 21(2): 307-316. J.S. Cai, F.H. Cao*, L.R. Chang, J.J. Zheng, J.Q. Zhang, C.N. Cao, The preparation and corrosion behaviors of MAO coating on AZ91D with rare earth conversion precursor film, Applied Surface Science, 2011, 257(8): 3804-3811. L.R. Chang, F.H. Cao*, J.S. Cai, W.J. Liu, J.J. Zheng, J.Q. zhang, C.N. Cao, Polarization behavior of Magneisum alloy AZ91D with Micro-Arc oxidation coating in NaCl solution, Acta Phys. -Chim. Sin., 2012., 28(1): 127-136. A.N. Chen, F.H. Cao*, W.J. Liu, L.Y. Zheng, Z. Zhang, J.Q. Zhang, C.N. Cao, Shot noise analysis on corroison behavior of Zinc alloy (ZnAl4Cu1) under dry-wet cycles, Transactions of Nonferrous Metals Society of China, 2012, 22(1): 228-240. W.J. Liu, F.H. Cao*, A.N. Chen, L.R. Chang, J.Q. Zhang, C.N. Cao, Effect of chloride ion concentration on electrochemical behavior and corrosion product of AM60 magnesium alloy in aqueous solutions, Corrosion, 2012, 68(4): 045001-045014. X.N. Liao, F.H. Cao*, A.N. Chen, W.J. Liu, J.Q. Zhang, C.N. Cao, In-situ investigation of atmospheric corrosion behavior of bronze under thin electrolyte layers using electrochemical technique, Transactions of Nonferrous Metals Society of China, 2012, 22(5): 1239-1249. Y. Xia, F.H. Cao*, W.J. Liu, L.R. Chang, J.Q. Zhang, The formation of passive films of carbon steel in borate buffer and their degradation behavior in NaCl solution by SECM, International Journal of Electrochemical Science, 2013, 8: 3057-3073. W.J. Liu, F. Arjmand, F.H. Cao, A. Adriaens, Quantification of metallica copper and nickel in their binary mixtures by voltammetry of immobilized microparticles, International Journal of Electrochemical Science, 2013, 8: 2576-2585. A.N. Chen, F.H. Cao*, X.N. Liao, W.J. Liu, L.Y. Zheng, J.Q. Zhang, C.N. Cao, Study of pitting corrosion on mild steel during wet-dry cycles by electrochemical noise analysis based on chaos theory, Corrosion Science, 2013, 66: 183-195. 夏妍, 曹发和*, 常林荣, 刘文娟, 张鉴清, 锈层下碳钢和耐候钢的微区和宏观腐蚀电化学行为, 高等学校化学学报, 2013, 34: 1426-1253. W.J. Liu, F.H. Cao*, Y. Xia, L.R. Chang, J.Q. Zhang, Localized Corrosion of Magnesium Alloys in NaCl Solutions Explored by Scanning Electrochemical Microscopy in Feedback Mode, Electrochimica Acta, 2014, 132: 377-388. F.H. Cao, J. Kim, A. Bard, Detection of the short-lived cation radical intermediate in the electrochemical oxidation of N,N-dimethylaniline by scanning electrochemical microscopy, J. Am. Chem. Soc., 2014, 136(52): 18163-18169