研究领域
配合物型功能材料
主要从事功能性配合物的设计、合成及性能的研究。
主要有三个方向：
1． 配合物型分子基磁性材料的设计、合成、结构及性质研究。主要目标为系统研究磁性与结构的关系，为能够定向设计并合成出具有特定功能的配合物型磁性材料打下坚实的基础。
2． 配合物型荧光材料的设计、合成、结构及性质的研究。主要目标为从分子设计的角度设计并合成出具有较好荧光性质的配合物，系统研究这些配合物的荧光性质与结构的关系，为能够定向设计并合成出较好荧光性能配合物型荧光材料打下基础。
3． 配合物型吸附材料的制备。主要目标为从分子设计的角度设计并合成出具有较好吸附性能的框架配位聚合物(MOFs)，通过研究吸附性能与结构的关系，为能定向设计并合成配合物型吸附材料打下基础。
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Y. Xu, J.-Q. Xu, K. -L. Zhang, X. Z. You, Keggin unit supported transition metal complexes: hydrothermal synthesis and characterization of [Ni(2,2’-bipy)3]1.5[PW12O40Ni(2,2’-bipy)2(H2O)]0.5H2O and [Co(1,10’-phen)3]1.5[PMo12O40Co(1,10’-phen)2(H2O)] 0.5H2O Chem. Commum., (2000) 153-154.
K. -L. Zhang*, Y.-J. Shi, S. Gao, Y. -D. Dai, X.-Z. You, Synthesis and characterization of a new iron(III) oxide cluster containing two different discrete [Fe3O] units: [Fe3O(O2CCH=CH---CH3)6(H2O)3][Fe3O(O2CCH=CH---CH3)7(H2O)2] (HO2CCH=CH---CH3)4(OH)(H2O). Inorg. Chem. Commum., 7 (2004) 584-587.
K. -L. Zhang*, Z. Wang, H. Huang, X.-Z. You, Synthesis, crystal structure and magnetic properties of a novel dinuclear cobalt(II) complex based on the mixed N- and O-donor ligands: [Co2(pyrazine)(fumarato)2(H2O)8]•7H2O. J. of Mol. Struct., 693 (2004) 193-197.
K. -L. Zhang *, Y. Xu, J. G. Lin, X.-Z. You, {[Cu(mal)(bipy)]•2H2O}n: a new one-dimensional ladder-like copper(II) complex based on the mixed N- and O-donor ligands with intrachain ferromagnetic interactions. J. of Mol. Struct., 1-3 (2004) 63-67.
K. -L. Zhang*, Y. Xu, X.-Z. You, Synthesis, crystal and molecular structure and magnetic properties of an extended two-dimensional fumarato-bridged polymeric cobalt(II) complex [Co(l-fumarato)(c-methylpyridine)2(H2O)2]. Transition Met. Chem., 30 (2005) 376-379.
K. -L. Zhang*, H.-W. Kuai, G. –W. Diao, Synthesis, characterization and crystal structure of a novel coordination compound based on the mixed N- and O- donor ligands exhibiting the metal ion-bridged ligand–ligand interaction: [Zn(2,2’-bipy)(Phmal)(H2O)].2H2O. J. of Mol. Struct., 779/1-3 (2005) 11-15
K. -L. Zhang*, H.-W. Kuai, W.-L. Liu, G. –W. Diao, Self assembly of a novel mixed-ligand hydrogen bonding three dimensional supramolecular network [Co(Phmal)(Him)4] J. of Mol. Struct., 831 (2007) 114–118
K. -L. Zhang*, N. Qiao, H.-Y. Gao, F. Zhou, M. Zhang, Self assembly of two novel three-dimensional supramolecular networks with blue photoluminescence Polyhedron, 26 (2007) 2461-2469.
K. -L. Zhang*, H.-Y. Gao, Z - C. Pan, W. Liang, G. –W. Diao, Preparation and characterization of two three-dimensionalmetal–organic photoluminescent supramolecular networks Polyhedron, 26 (2007) 5177-5184.
K. -L. Zhang*, H.-Y. Gao, N. Qiao, F. Zhou, G. –W. Diao, Preparation and characterization of two novel three-dimensional supramolecular networks with blue photoluminescence Inorg. Chim. Acta, 361 (2008) 153-160.
K. -L. Zhang*, F. Zhou; H.-Y. Gao; Z.-C. Pan; J.-G. Lin; Preparation and characterization of a metal-organic three-dimensional framework based on isonicotinate [Pb(INA)2] (INA = isonicotinate, NC5H4-4- J. of Coord. Chem., 61(2008) 1494 - 1502.
K. -L. Zhang*, F. Zhou, L.-M. Yuan, G-W Diao, S. W. Ng, Synthesis and characterization of a novel photoluminescent three-dimensional metal–organic framework Inorg. Chim. Acta, 362 (2009) 2510–2514.
K. -L. Zhang*, W. Liang, Y. Chang, L.-M. Yuan, S. W. Ng, Syntheses, characterization and luminescent properties of two lead(II) fumarate metal-organic frameworks Polyhedron, 28 (2009) 647-652.
K. -L. Zhang*, Y. Chang, C. T. Hou, R. Wu, G. W. Diao, S. W. Ng, Effect of N-donor auxiliary ligands on the engineering of crystalline architectures of a series of lead(II) complexes with 5-amino-2,4,6-triiodoisophthalic acid CrystEngComm 12 (2010) 1194–1204.
K. -L. Zhang*, Z. -C. Pan, W. Liang, W. -L Liu, S. W. Ng, Synthesis and characterization of an energetic three-dimensional metal-organic framework with blue photoluminescence Materials Letter 63 (2009) 2136-2138.
K. -L. Zhang*,Y. Chang, J.-B. Zhang, L.-M. Yuan, Y. Deng, G.-W. Diao, S. W. Ng Synthesis, crystal structures and characterization of four coordination polymers based on 5-amino-2,4,6-triiodoisophthalic acid J. Solid. State Chem (2011) 1263-1272.
K. -L. Zhang*, Y. Chang, S. W. Ng Preparation and characterization of two supramolecular complexes with 5-amino-2,4,6-triiodoisophthalic acid under N-donor auxiliary ligand intervention Inorg. Chim. Acta, 368 (2011) 49–57.
K. -L. Zhang*, C. T. Hou, J.-J. Song, Y. Deng, L. Li, S. W. Ng, G.-W. Diao, Temperature and auxiliary ligand-controlled supramolecular assembly in a series of Zn(II)-organic frameworks: syntheses, structures and properties CrystEngComm, 14 (2012) 590-600.
K. -L. Zhang*, Y. Chang, J.-B. Zhang, Y. Deng, T.-T. Qiu, L. Li, S. W. Ng, The cosolvent-dependent assembly of a family of three blue fluorescent lead(II)-coordination polymers with 5-amino- 2,4,6-tribromoisophthalic acid CrystEngComm, 14 (2012) 2926-2935.
Y. Deng, C.-T.Hou, R.I.Walton, J. Tang, P. Zhu, K. -L. Zhang*, S. W. Ng Preparation, structural diversity and characterization of a family of Cd(II)-organic frameworks Dalton Trans., 2013, 42, 12468-12480.
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