张献明 - 山西师范大学 - 化学与材料科学学院

个人简介

张献明教授，博士生导师，“万人计划”首批创新领军人才，国家杰出青年基金获得者，百千万人才工程国家级人选，三晋学者，全国优秀博士论文获得者，洪堡学者。1996年山西师范大学获学士学位，1999年内蒙古大学获理学硕士学位。1999年师从陈小明教授（中国科学院院士）攻读博士，2002年6月获中山大学理学博士学位。2003年4月获德国 “洪堡”奖学金资助，在海德堡大学做博士后研究工作，2004年6月返回山西师范大学工作。同年，博士论文被评为 “全国优秀博士学位论文”，2005年入选教育部“新世纪优秀人才支持计划”，2007年获 “山西省五一奖章”和“山西省333人才”，2008年获“中国化学会青年化学奖”并入选“山西省高等院校拔尖创新人才”。2009年获“国家杰出青年基金资助” 2010年获国务院特殊津贴。2011年，作为团队带头人，带领“分子磁性与磁性材料团队”入选教育部创新团队。2013年入选科技部中“国家中青年科技创新领军人才”，同时被评为“百千万人才工程”国家级人选。2014入选中组部“万人计划”首批创新领军人才。

研究领域

1.金属有机骨架金属-有机框架（Metal-Organic Frameworks），简称MOFs，是由有机配体和金属离子或团簇通过配位键自组装形成的具有分子内孔隙的有机-无机杂化材料。在MOFs 中，有机配体和金属离子或团簇的排列具有明显的方向性，可以形成不同的框架孔隙结构，从而表现出不同的吸附性能、光学性质、电磁学性质和催化性质等。MOFs 在现代材料学方面呈现出巨大的发展潜力和诱人的发展前景。 2.共价-有机框架共价有机框架材料（Covalent-Organic Frameworks），简称COFs，是一类具有周期性和结晶性的有机多孔聚合物。共价有机框架材料由轻质元素通过共价键连接，拥有较低的密度、高的热稳定性以及固有的多孔性，在气体吸附、非均相催化、能量存储等研究领域有着广泛的应用潜力，引起了科学界强烈的研究兴趣。COFs具有以下优点：1）构筑单元为有机小分子，有机小分子来源广泛而且种类繁多，使得构筑单元多样化，便于通过构筑单元来调控目标材料的结构和功能；2）以共价键连接形成空间网络结构，具有较好的热稳定性和化学稳定性；3）由轻质元素构成，具有低密度的特性。 3.非线性光学晶体非线性光学晶体是对于激光强电场显示二次以上非线性光学效应的晶体。非线性光学晶体是一种功能材料，其中的倍频晶体可用来对激光波长进行变频，从而扩展激光器的可调谐范围，在激光技术领域具有重要应用价值。广泛应用的非线性光学晶体有KDP、BBO和LBO等。目前的研究热点主要集中在硼酸和磷酸盐为代表的深紫外和硫族化物为代表近红外波段。 4.团簇和催化化学团簇是由几个乃至上千个原子、分子或离子通过物理或化学结合力组成的相对稳定的微观或亚微观聚集体，物理和化学性质随所含的原子数目而变化，是介于原子、分子与宏观固体物质之间的物质结构的新层次，是各种物质由原子分子向大块物质转变的过渡状态。基本问题是弄清团簇如何由原子、分子一步一步演化而成，以及随着这种演化，团簇的结构和性质如何变化，具体当尺寸多大时，过渡成宏观固体。

近期论文

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Fan, X.; Liu, Y.; Chen, S.; Shi, J.; Wang, J.; Fan, A.; Zan, W.; Li, S.; Goddard, W. A.; Zhang, X.-M. Defect-enriched iron fluoride-oxide nanoporous thin films bifunctional catalyst for water splitting. Nature Comm., 2018, 9, 1809. Wei, Z.; Yang, Y.; Liu, M.; Dong, J.; Fan, X.; Zhang, X. Cobalt nanocrystals embedded into N-doped carbon as highly active bifunctional electrocatalysts from pyrolysis of triazolebenzoate complex. Electrochim. Acta 2018, 284, 733-741. Wei, X.; Li, N.; Zhang, X. Co/CoO/C@B three-phase composite derived from ZIF67 modified with NaBH4 solution as the electrocatalyst for efficient oxygen evolution. Electrochim. Acta 2018, 264, 36-45. Ren, H.-Y.; Zhang, X.-M. Reversible Double Nucleophilic Substitution Reaction inside Single-Crystal MOF Tuned Remarkable Magnetic Behavior. Inorg. Chem. 2018, 57, 6787-6790. Lingjuan, Z.; Juanjuan, Li.; Zhongyan, H.; Jinhuan, D.; Xian‐Ming, Z.; Xianxiu, X. Silver‐Catalyzed Isocyanide Insertion into N−H Bond of Ammonia: [5+1] Annulation to Quinazoline Derivatives. Advanced Synthesis & Catalysis 2018, 360, 1938-1942. Li, S.-L.; Han, M.; Wu, B.; Wang, J.; Zhang, X.-M. Photochromic Porous and Nonporous Viologen-Based Metal–Organic Frameworks for Visually Detecting Oxygen. Cryst. Growth. & Des. 2018. Zhang, F.; Ma, C.; Zhang, Y.; Li, H.; Fu, D.; Du, X.; Zhang, X.-M. N-doped mesoporous carbon embedded Co nanoparticles for highly efficient and stable H2 generation from hydrolysis of ammonia borane. Journal of Power Sources 2018, 399, 89-97. Dang, Q.-Q.; Liu, C.-Y.; Wang, X.-M.; Zhang, X.-M. Novel Covalent Triazine Framework for High-Performance CO2 Capture and Alkyne Carboxylation Reaction. ACS Appl. Mater.& Inter. 2018. Chen, Y.-G.; Yang, N.; Yao, X.-N.; Li, C.-B.; Guo, Y.; Zhang, X.-M. Synergetic Influence of Alkali-Metal and Lone-Pair Cations on Frameworks of Tellurites. Inorg. Chem. 2018, 57, 5406-5412. Qu, M.; Li, H.; Xie, L.-H.; Yan, S.-T.; Li, J.-R.; Wang, J.-H.; Wei, C.-Y.; Wu, Y.-W.; Zhang, X.-M. Bidentate Phosphine–Assisted Synthesis of an All–Alkynyl–Protected Ag74 Nanocluster. J Am Chem Soc 2017, 139, 12346-12349. Zhang, L.-J. Z. J. L. F.-Q. Z. X.-M. Water as a Proton Mediator for Dioxygen-Selective Oxidation of Alcohols by a Planar Dinuclear Butterfly-Like Cu-Cu Bonding Complex: A Combined Experimental and Computational Study. Journal of Catalysis. 2017, 354, 78-83. Zhang, F.; Zhao, C.; Chen, S.; Li, H.; Yang, H.; Zhang, X.-M. In situ mosaic strategy generated Co-based N-doped mesoporous carbon for highly selective hydrogenation of nitroaromatics. Journal of Catalysis 2017, 348, 212-222. Zhao, Y.-W.; Wang, Y.; Zhang, X.-M. Homochiral MOF as Circular Dichroism Sensor for Enantioselective Recognition on Nature and Chirality of Unmodified Amino Acids. ACS Applied Materials & Interfaces 2017, 9, 20991-20999. Wei, T.; Sun, J.; Zhang, F.; Zhang, J.; Chen, J.; Li, H.; Zhang, X.-M. Acetylene mediated synthesis of Au/graphene nanocomposite for selective hydrogenation. Catalysis Communications 2017, 93, 43-46. Wang, J. H.; Zhang, Y.; Li, M.; Yan, S.; Li, D.; Zhang, X. M. Solvent-Assisted Metal Metathesis: A Highly Efficient and Versatile Route towards Synthetically Demanding Chromium Metal-Organic Frameworks. Angew. Chem. Int. Ed. 2017, 56, 6478-6482. Li, S.-L.; Wang, J.; Zhang, F.-Q.; Zhang, X.-M. Light and Heat Dually Responsive Luminescence in Organic Templated CdSO4-type Halogeno(cyano)cuprates with Disorder of Halogenide/Cyanide. Cryst. Growth. & Des. 2017, 17, 746-752. Hou, J.-J.; Li, X.-Q.; Gao, P.; Sun, H.-Q.; Zhang, X.-M. Tunability in Metal Coordination Sphere, Ligand Coordination Mode, Network Topology, and Magnetism via Stepwise Dehydration Induced Single-Crystal to Single-Crystal Transformation. Cryst. Growth. & Des. 2017. Dang, Q.-Q.; Wan, H.-J.; Zhang, X.-M. Carbazolic Porous Framework with Tetrahedral Core for Gas Uptake and Tandem Detection of Iodide and Mercury. ACS Applied Materials & Interfaces 2017, 9, 21438-21446. Zhao, Y.-W.; Zhang, F.-Q.; Zhang, X.-M. Single Component Lanthanide Hybrids Based on Metal–Organic Framework for Near-Ultraviolet White Light LED. ACS Applied Materials & Interfaces 2016, 8, 24123-24130. Zhang, X.-M.; Sarma, D.; Wu, Y.-Q.; Wang, L.; Ning, Z.-X.; Zhang, F.-Q.; Kanatzidis, M. G. Open-Framework Oxysulfide Based on the Supertetrahedral [In4Sn16O10S34]12– Cluster and Efficient Sequestration of Heavy Metals. J. Am. Chem. Soc. 2016, 138, 5543-5546. Wang, J.; Li, S.-L.; Zhang, X.-M. Photochromic and Nonphotochromic Luminescent Supramolecular Isomers Based on Carboxylate-Functionalized Bipyridinium Ligand: (4,4)-Net versus Interpenetrated (6,3)-Net. ACS Applied Materials & Interfaces 2016, 8, 24862-24869. Fan, X.; Liu, Y.; Peng, Z.; Zhang, Z.; Zhou, H.; Zhang, X.; Yakobson, B. I.; Goddard, W. A.; Guo, X.; Hauge, R. H.; Tour, J. M. Atomic H-Induced Mo2C Hybrid as an Active and Stable Bifunctional Electrocatalyst. ACS Nano 2016. Yao, R.-X.; Cui, X.; Wang, J.; Zhang, X.-M. D3 Symmetric [(NaO3)Co3] Clusters Based Homochiral Magnet from Spontaneous Resolution to Absolute Chiral Induction. Chem. Commun. 2015, 51, 5108-5111. Liu, J.; Qu, M.; Clerac, R.; Zhang, X.-M. A two-dimensional honeycomb coordination network based on fused triacontanuclear heterometallic {Co12Mn18} wheels. Chem. Commun. 2015, 51, 7356-7359. Li, S.-L.; Zhang, F.-Q.; Zhang, X.-M. An Organic-Ligand-Free Thermochromic Luminescent Cuprous Iodide Trinuclear Cluster: Evidence for Cluster Centered Emission and Configuration Distortion with Temperature. Chem. Commun. 2015, 51, 8062-8065. Dang, Q.-Q.; Zhan, Y.-F.; Wang, X.-M.; Zhang, X.-M. Heptazine-Based Porous Framework for Selective CO2 Sorption and Organocatalytic Performances. ACS Appl Mater Interfaces 2015, 7, 28452-28458. Yao, R.-X.; Xu, X.; Zhang, X.-M. Magnetic Modulation and Cation-Exchange in a Series of Isostructural (4,8)-Connected Metal–Organic Frameworks with Butterfly-like [M4(OH)2(RCO2)8] Building Units. Chem. Mater. 2012, 24, 303-310. Zhang, X.-M.; Lv, J.; Ji, F.; Wu, H.-S.; Jiao, H.; Schleyer, P. v. R. A Perfectly Square-Planar Tetracoordinated Oxygen in a Tetracopper Cluster-Based Coordination Polymer. J. Am. Chem. Soc. 2011, 133, 4788-4790. Zhang, X.-M.; Li, C.-R.; Zhang, X.-H.; Zhang, W.-X.; Chen, X.-M., Unusual Slow Magnetic Relaxation in Helical Co3(OH)2 Ferrimagnetic Chain Based Cobalt Hydroxysulfates. Chem. Mater. 2008, 20, (6), 2298-2305. Zhang, X.-M.; Hao, Z.-M.; Zhang, W.-X.; Chen, X.-M., Dehydration-Induced Conversion from a Single-Chain Magnet into a Metamagnet in a Homometallic Nanoporous Metal–Organic Framework. Angew. Chem. Int. Ed. 2007, 46, (19), 3456-3459. Zhang, X. M.; Zhao, Y. F.; Zhang, X. W.; Chen, X. M., A Tetrazolate- and Cyano-Bridged Homometallic Mixed-Valence Copper(I,II) Molecular Ferrimagnet. Adv. Mater. 2007, 19, (19), 2843-2846. Zhang, X.-M.; Fang, R.-Q.; Wu, H.-S., A Twelve-Connected Cu6S4 Cluster-Based Coordination Polymer. J. Am. Chem. Soc. 2005, 127, (21), 7670-7671. Zhang, X.-M., Hydro(solvo)thermal in situ ligand syntheses. Coordin. Chem. Rev. 2005, 249, (11-12), 1201-1219. Zhang, X.-M.; Tong, M.-L.; Chen, X.-M., Hydroxylation of N-Heterocycle Ligands Observed in Two Unusual Mixed-Valence CuI/CuII Complexes. Angew. Chem. Int. Ed. 2002, 41, (6), 1029-1031.