个人简介
2014- Professor, Xiamen University
2013-2014 Associate Professor, Xiamen University
2011-2013 Postdoc fellow, Yale University, USA
2006-2010 Ph.D., Washington University in St. Louis, USA
2002-2006 B.S., Xiamen University, China
Hai-Chao was born in 1983 in Hunan, China. He obtained his B.S. in Chemistry in 2006 from Xiamen University and a Ph.D. in Chemistry in 2010 from Washington University in St. Louis (USA) with Prof. Kevin D. Moeller. After postdoctoral work with Prof. Jonathan A. Ellman at Yale University (USA) from 2011 to 2013, he moved backed to Xiamen University to start his independent career. His research focuses on synthetic electrochemistry.
研究领域
Our research goal is to develop sustainable redox reactions for organic synthesis using organic electrochemistry. We are particularly interested in developing methods for the oxidative activation of simple and stable chemical bonds/small molecules for the generation of synthetically useful carbon- and heteroatom-centered radicals and application of these reactive intermediates for new reaction discovery.
I. Molecular electrocatalysis
II. Molecular photoelectrocatalysis
III. Continous flow electrosynthesis
近期论文
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"Cu-electrocatalytic diazidation of alkenes at ppm catalyst loading" Cai, C.-Y.; Zheng, Y.-T.; Li, J.-F. and Xu, H.-C.* J. Am. Chem. Soc. 2022, 144, 11980–11985
"Electrochemical Aromatic C–H Hydroxylation in Continuous Flow" Long, H.; Chen, T.-S.; Song, J.; Zhu, S. and Xu, H.-C.* (LH and CTS contributed equally) Nat. Commun. 2022, 13, 3945
"Electrocatalytic Allylic C–H Alkylation Enabled by a Dual-Function Cobalt Catalyst" Chen, M.; Wu, Z.-J.; Song, J. and Xu, H.-C.* Angew. Chem. Int. Ed. 2022, 61, e202115954
"Organoelectrocatalysis Enables Direct Cyclopropanation of Methylene Compounds" Jie, L.-H.; Guo, B.; Song, J. and Xu, H.-C.* (GB and JLH contributted equally) J. Am. Chem. Soc. 2022, 144, 2343
"Electrochemical C–H phosphorylation of arenes in continuous flow suitable for late-stage functionalization" Long, H.; Huang, C.; Zheng, Y.-T.; Li, Z.-Y.; Jie, L.-H.; Song, J.; Zhu, S. and Xu, H.-C.* Nat. Commun. 2021, 12, 6629
"Electrocatalytic C(sp3)–H/C(sp)–H cross-coupling in continuous flow through TEMPO/copper relay catalysis" Guo, B. and Xu, H.-C.* Beilstein. J. Org. Chem. 2021, 17, 2650
"Discovery of a tetraarylhydrazine catalyst for electrocatalytic synthesis of imidazo-fused N-heteroaromatic compounds" Hou, Z.-W., Mao, Z.-Y. and Xu, H.-C.* (Hou and Mao contributted equally) Org. Biomol. Chem. 2021, 19, 9789
"Electrochemistry in Synthetic Organic Chemistry" Xu, H.-C.* and Moeller, K. D.* J. Org. Chem. 2021, 86, 15845 (editorial)
"Electrocatalytic Dehydrogenative Cyclization of 2-Vinylanilides for the Synthesis of Indoles" Zheng, Y.-T.; Song, J. and Xu, H.-C.* J. Org. Chem. 2021, 86, 16001
"Recent advances in organic electrosynthesis employing transition metal complexes as electrocatalysts" Ma, C.; Fang, P.; Liu, Z.-R.; Xu, S.-S.; Xu, K.*; Cheng, X.*; Lei, A.*; Xu, H.-C.*; Zeng, C.* and Mei, T.-S.* Sci. Bull. 2021, 66, 2412
"Tailored cobalt-salen complexes enable electrocatalytic intramolecular allylic C–H functionalizations" Cai, C.-Y.; Wu, Z.-J.; Liu, J.-Y.; Chen, M.; Song, J. and Xu, H.-C.* (Cai and Wu contributted equally) Nat. Commun. 2021, 12, 3745
"Electrochemically driven radical reactions: from direct electrolysis to molecular catalysis" Chen, N. and Xu, H.-C.* Chem. Rec. 2021, 21, 2306
"Electrophotocatalytic C−H Azolation of Arenes" Hou, Z.-W. and Xu, H.-C.* ChemElectroChem 2021, 8, 1571
"Catalyst- and Reagent-Free Formal Aza-Wacker Cyclizations Enabled by Continuous-Flow Electrochemistry" Huang, C.; Li, Z.-Y.; Song, J. and Xu, H.-C.* Angew. Chem. Int. Ed. 2021, 60, 11237 (Hot Paper)
"Integrating Continuous-Flow Electrochemistry and Photochemistry for the Synthesis of Acridinium Photocatalysts via Site-Selective C–H Alkylation" Yan, H.; Zhu, S. and Xu, H.-C.* Org. Process Res. Dev. 2021 25, 2608
"Electrochemical synthesis of benzimidazoles via dehydrogenative cyclization of amidines" Zhao, H.-B.; Zhuang, J.-L.* and Xu, H.-C.* ChemSusChem 2021, 14, 1692
"Synthesis of Acridinium Photocatalysts via Site-Selective C−H Alkylation" Yan, H.; Song, J.; Zhu, S. and Xu, H.-C.* CCS Chem. 2021, 3, 317
"C-H Alkylation of Heteroarenes with Alkyl Oxalates by Molecular Photoelectrocatalysis" Xu, F.; Lai, X.-L. and Xu, H.-C.* Synlett 2021, 32, 369
"Site-Selective Electrochemical Benzylic C–H Amination" Hou, Z.-W.; Liu, D.-J.; Xiong, P.; Lai, X.-L.; Song, J. and Xu, H.-C.* Angew. Chem. Int. Ed. 2021, 60, 2943 (VIP) Highlight: Synfacts 2021; 17: 0096
"Site-selective electrooxidation of methylarenes to aromatic acetals" Xiong, P.; Zhao, H.-B.; Fan, X.-T.; Jie, L.-H.; Long, H.; Xu, P.; Liu, Z.-J.; Wu, Z.-J.; Cheng, J.*; Xu, H.-C.* (XP and ZHB contributed equally) Nat. Commun. 2020, 11, 2706
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