Norton. Jack R. - Columbia University - Department of Chemistry

个人简介

Education B.A. Chemistry - Harvard University, Cambridge, MA 1967 Ph.D. Chemistry - (J.P. Collman) Stanford University, Stanford, CA 1972 Postdoctoral Chemistry - (J. Lewis) Univ. Chemical Lab., Cambridge, England, 1972 Professional Experience 1973-1979 Assistant Professor of Chemistry, Princeton University 1979-1981 Associate Professor of Chemistry, Colorado State University 1981-1997 Professor of Chemistry, Colorado State University 1997-Present Professor of Chemistry, Columbia University Honors and Lectureships NSF Graduate Fellow, 1967-1971 NSF Postdoctoral Fellow, 1972 Camille and Henry Dreyfus Foundation Teacher - Scholar, 1976 Alfred P. Sloan Fellow, 1977-1981 Innovation Recognition Award, Union Carbide, 1985 Esso Distinguished Lecturer, U. of Toronto, March 1987 Guggenheim Fellow, 1989 Humboldt Research Award for Senior U.S. Scientists, 1993 Japan Society for the Promotion of Science (JSPS) Fellowship for 1997 American Association for the Advancement of Science (AAAS) Fellow, 1999 Lee Lecturer, University of Chicago, 2001 Frontiers Lectures, Texas A&M, 2002 ACS Organometallic Chemistry Award, 2005 Sierra Nevada Distinguished Chemist, Sierra Nevada ACS, 2006 Arthur C. Cope Scholar Award, 2013

研究领域

Mechanisms of organometallic and inorganic reactions; applications of organometallics to organic synthesis and catalysis; organometallic and bioinorganic proton transfer reactions; use of metalloradicals to control free-radical polymerizations; one-electron chemistry of Lewis acids.

近期论文

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On-Demand Photochemical Synthesis of Hydrogen Peroxide from Alkylated Anthraquinones Hunter B. Vibbert Christoph BendelJack R. NortonAaron J. Moment ACS Sustainable Chem. Eng.. 10, 11106-11116. August 2022 The Synthesis of Diverse Terpene Architectures from Phenols Farbod SalahiChengbo YaoJack R. NortonScott A. Snyder Nature Synth.. 1, 313-321. April 2022 Isomerization of Aziridines to Allyl Amines via Titanium and Chromium Cooperative Catalysis Chengbo YaoAlana D. N. WilliamsYiting GuJack R. Norton J. Org. Chem.. 87, 4991-4997. March 2022 Generation of ɑ-Boryl Radicals by H• Transfer and Their Use in Cycloisomerizations Shicheng ShiFarbod SalahiHunter B. VibbertMaleeha RahmanScott A. SnyderJack R. Norton Angew. Chem. Int. Ed.. 60, 22678-22682. August 2021 Highly Selective Hydrogenation of C═C Bonds Catalyzed by a Rhodium Hydride Yiting GuJack R. NortonFarbod SalahiVladislaw L. LisnyakZhiyao ZhouScott A. Snyder J. Am. Chem. Soc.. 143, 9657-9663. June 2021 Synthesis, Characterization, and Catalytic Activity of Bimetallic Ti/Cr Complexes Jiawei ChenHunter B. VibbertAmymarie K. BartholomewAlexander P. AydtSteffen JockuschJack R. NortonMatthew HammondMichael Rauch Organometallics. 39, 4592–4598. November 2020 Hydrogen Atom Transfer Rates from Tp-Containing Metal Hydrides to Trityl Radicals Hunter B. VibbertHagen NeugebauerJack R. NortonAndreas HansenMarcus BurschStefan Grimme Hydrogen Atom Transfer Rates from Tp-Containing Metal-Hydrides to Trityl Radicals. ASAP. October 2020 Catalytic Cycloisomerization onto a Carbonyl Oxygen Shicheng ShiJonathan L. KuoTao ChenJack R. Norton Org. Lett.. 15, 6171-6176. July 2020 Catalyzing the Hydrodefluorination of CF₃-Substituted Alkenes by PhSiH₃. H• Transfer from a Nickel Hydride Chengbo YaoShuai WangJack R. NortonMatthew Hammond J. Am. Chem. Soc. 142, 4793-4799. January 2020 H· Transfer-Initiated Synthesis of γ-Lactams: Interpretation of Cycloisomerization and Hydrogenation Ratios Chris LorencHunter B. VibbertChengbo YaoJack R. NortonMichael Rauch ACS Catal. 9, 10294-10298. October 2019 Thermodynamics of H+/H•/H–/e– Transfer from [CpV(CO)₃H]−: Comparisons to the Isoelectronic CpCr(CO)₃H Jonathan L. KuoThilina GunasekaraAndreas HansenHunter B. VibbertFabian BohleJack R. NortonSteffan GrimmePatrick J. Quinlivan Organometallics. 38, 4319-4328. October 2019 Anti-Markovnikov alcohols via epoxide hydrogenation through cooperative catalysis Chengbo YaoTobias DahmenAndreas GansäuerJack R. Norton Science. 364, 764-767. May 2019 TEMPO-Mediated Catalysis of the Sterically Hindered Hydrogen Atom Transfer Reaction between (C₅Ph₅)Cr(CO)₃H and a Trityl Radical Thilina GunasekaraGraham P. AbramoAndreas HansenHagen NeugebauerMarkus BurschSteffan GrimmeJack R. Norton J. Am. Chem. Soc. 141, 1882-1886. January 2019 Insertion of Isonitriles into the Zr–CH₃ Bond of Cp*₂Zr(CH₃)₂ and Electrophilic Cleavage of the Remaining Methyl Group Jiawei ChenTao ChenJack R. NortonMichael Rauch Organometallics. 37,4424-4430. November 2018 Insertion of Isonitriles into the M–C Bonds of Group 4 Dialkyl Complexes Jiawei ChenNadine YassinThilina GunasekaraJack R. NortonMichael Rauch J. Am. Chem. Soc. 140, 8980-8989. Catalysis of Radical Cyclizations from Alkyl Iodides under H₂: Evidence for Electron Transfer from [CpV(CO)₃H]−Jonathan L. KuoChris LorencJanine M. AbuyanJack R. Norton J. Am. Chem. Soc. 140, 4512-4516. March 20182017 Cationic Copper Hydride Clusters Arising from Oxidation of (Ph₃P)₆Cu₆H₆ Shuo LiuMichael S. EberhardtJack R. NortonXiaodong YinMichelle C. NearyDaniel W. Paley J. Am. Chem. Soc. 139, 7685-7688. May 2017 Reaction of Cp*₂Zr(2,3-dimethylbutadiene) with Isonitriles and CO Travis N. ValadezJack R. NortonMichelle C. NearyPatrick J. Quinlivan Organometallics. 35, 3163-3169. September 2016 Radical Isomerization and Cycloisomerization Initiated by H• Transfer Gang LiJonathan L. KuoArthur HanJanine M. AbuyuanLily C. YoungJack R. NortonJoshua H. Palmer J. Am. Chem. Soc. 138, 7698-7704. May 2016 Transition-Metal Hydride Radical Cations Yue HuAnthony P. ShawDeven P. EstesJack R. Norton Chem. Rev. 116, 8427-8462. February 2016